Summary
The major chemical pathway for the degradation of hydrocarbons is their photochemical oxidation by hydroxy radicals. The products vary depending on the concentration of nitrogen oxides. At low NOx-levels, the production of organic hydroperoxides is favoured. Until now the determination of these compounds was limited to analysis of the total amount of peroxide and the analysis of hydrogen peroxide. This paper describes a method to separate and determine organic peroxides by means of HPLC and post-column reaction detection. Depending on the kind of peroxide, detection limits of 100ppb or 10pmol have been reached until now. Since hydrogen peroxide elutes within the dead-volume, it does not interfere with the detection of the other peroxides.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. G. Calvert, S. Madronich (1987) “Theoretical study of the initial products of the atmospheric oxidation of hydrocarbons”, Journal of Geophysical Research 92(D2), 2211 – 2220.
W. Schmied, M. Przewosnik and K. B–chmann (1988) –Spurenbestimmung von Aldehyden und Ketonen in der Troposph“re durch Festphasenderivatisierung mit DNSH”, submitted to Zeitschrift für Analytische Chemie (Fresenius)
E. Hellpointer and S. Gab (1989) “Detection of methyl, hydroxymethyl and hydroxyethyl hydroperoxides in air and precipitation”, Nature 337(6208), 631 – 632.
T. Miyazawa, K. Yasudo, K. Fujimoto and T. Kaneda (1988) “Determination of phosphatidylcholine hydroperoxide in human plasma by chemiluminescence high performance liquid chromatography”, Analytical Letters 21(6), 1033 – 1044.
K. Akasaka, H. Ohuri and H. Meguro (1988) “An aromatic phosphine reagent for the high performance liquid chromatography fluorescence determination of hydroperoxides - determination of phosphatidylcholine hydroperoxides in human plasma”, Analytical Letters 21(6), 965 – 975.
R.K. Jensen, M. Zinboand and S. Korcek (1983) “High performance liquid chromatography determination of hydroperoxide product formed in the autooxidation of n-hexadecane at elavated temperatures”, Journal of Chromatographic Science 21, 394 – 397.
M.O. Funk and W.J. Baker (1985) “Determination of organic peroxides by high performance liquid chromatography with electrochemical detection”, Journal of Liquid Chromatography 8(4), 663 – 675.
R.S. Deelder, M.G.F. Kroll and J.H.M. van den Berg (1976)“Determination of trace amount of hydrogen- peroxide by column liquid chromatography and colori- metric detection”, Journal of Chromatography 125, 307–314.
Y. Yamamoto, M.H. Brodsky, J.C. Baker and B.N. Ames (1987) “Detection and characterization of lipid hydroperoxides at picomole levels by high performance liquid chromatography”, Analytical Biochemistry 160(1), 7 – 13.
T. Miyazawa, K. Yasudo and K. fujimoto (1987) “Chemiluminescence - high performance liquid chromatography of phosphatidylcholine hydroperoxide”, Analytical Letters 20(6), 915 – 925.
G.L. Kok, K. Thompson and A.L. Lazrus (1986) “Derivatization technique for the determination of peroxides in precipitation”, Analytical Chemistry 58(6), 1192 – 1194.
K.G. Paul, P.I. Ohlsson and S.Wold (1979) “Formation of horseradish peroxidase compound I with alkyl hydroperoxides”, Acta Chemica Scandinavica B33, 747 – 754.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1990 ECSC, EEC, EAEC, Brussels and Luxembourg
About this chapter
Cite this chapter
Bächmann, K., Hauptmann, J. (1990). Determination of Organic Peroxides. In: Restelli, G., Angeletti, G. (eds) Physico-Chemical Behaviour of Atmospheric Pollutants. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0567-2_15
Download citation
DOI: https://doi.org/10.1007/978-94-009-0567-2_15
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6743-0
Online ISBN: 978-94-009-0567-2
eBook Packages: Springer Book Archive