Abstract
The main aim of the paper is to evaluate ferro-precipitate as an immobilization agent for various ions from aqueous solutions. Heavy metals, namely lead, copper and chromium were adsorbed as well as arsenate and phosphate. In addition, the adsorption of surfactants, sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB) was carried out. Linear as well as non-linear regression of adsorption isotherms confirmed the Langmuir model applicability. Adsorption capacities (am) were calculated. The highest adsorption capacity was found for arsenate and phosphate respectively (am = 1.36 mmol g−1 for arsenate and 0.70 mmol g−1 for phosphate). Lower but still enough adsorption capacity was found for heavy metals (am = 0.76 mmol g−1 for lead, 0.58 mmol g−1 for copper, 0.38 mmol g−1 for chromium, and the lowest values were shown for surfactants (a = 0.38 mmol g−1 for CTAB and 0.21 mmol g−1 for SDS).
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Taraba B, Marsalek R (2007) Immobilization of heavy metals and phenol on altered bituminous coals. Energ Source A 29:885–894
Wang YH, Lin SH, Juang RS (2003) Removal of heavy metal ions from aqueous solutions using various low-cost adsorbents. J Hazard Mater B 102:291–302
Klucakova M, Omelka L (2004) Sorption of metal ions on lignite and humic acid. Chem Pap Chem Zvesti 58:170–175
Cox M, El-Shafey E, Pichugin AA, Appleton Q (2000) Removal of mercury(II) from aqueous solution on a carbonaceous sorbent prepared from flax shive. J Chem Technol Biot 75:427–435
Meena AK, Mishra GK, Kumar S, Rajagopal C, Nagal NP (2004) Low-cost adsorbents for the removal of mercury(II) from aqueous solution – a comparative study. Defence Sci J 54:537–548
Chen YH, Li FA (2010) Kinetic study on removal of copper(II) using goethite and hematite nano-photocatalysts. J Colloid Interf Sci 347:277–281
Mustafa S, Khan S, Zaman MI (2010) Effect of Ni2+ ion doping on the physical characteristics and chromate adsorption behavior of goethite. Water Res 44:918–926
Campos V (2009) The sorption of toxic elements onto natural zeolite, synthetic goethite and modified powdered block carbon. Environ Earth Sci 59:737–744
Li W, Zhang SZ, Shan XQ (2006) Effect of phosphate on the adsorption of Cu and Cd on natural hematite. Chemosphere 63:1235–1241
Chowdhury SR, Yanful EK (2010) Arsenic and chromium removal by mixed magnetite-maghemite nanoparticles and the effect of phosphate on removal. J Environ Manage 91:2238–2247
Kolbe F, Weiss H, Morgenstern P, Wennrich R, Lorenz W, Schurk K, Stanjek H, Daus B (2011) Sorption of aqueous antimony and arsenic species onto akaganeite. J Colloid Interf Sci 357:460–465
Deliyanni EA, Peleka EN, Lazaridis NK (2007) Comparative study of phosphates removal from aqueous solutions by nanocrystalline akaganeite and hybrid surfactant-akaganeite. Sep Purif Technol 52:478–486
Peleka EN, Deliyanni EA (2009) Adsorptive removal of phosphates from aqueous solutions. Desalination 245:357–371
Chitrakar R, Tezuka S, Sonoda A, Sakane K, Ooi K, Hirotsu T (2006) Phosphate adsorption on synthetic goethite and akaganeite. J Colloid Interf Sci 298:602–608
Wu HS, Pendleton PJ (2001) Adsorption of anionic surfactant by activated carbon: effect of surface chemistry, ionic strength, and hydrophobicity. J Colloid Interf Sci 243:306–315
Ridaoui H, Jada A, Vidal L, Donnet JB (2006) Effect of cationic surfactant and block copolymer on carbon black particle surface charge and size. Colloid Surf A 278:149–159
Chang MY, Juang RS (2005) Equilibrium and kinetic studies on the adsorption of surfactant, organic acids and dyes from water onto natural biopolymers. Colloid Surf A 269:35–46
Vale HM, McKenna TF (2005) Adsorption of sodium dodecyl sulphate and sodium dodecyl benzene sulphonate on poly(vinyl chloride) latexes. Colloid Surf A 268:68–72
Valentim IB, Joekes I (2006) Adsorption of sodium dodecyl sulphate on chrysotile. Colloid Surf A 290:106–111
Qi L, Liao W, Bi Z (2007) Adsorption of conventional and gemini cationic surfactants in nonswelling and swelling layer silicite. Colloid Surf A 302:568–572
Sineva AV, Parfenova AM, Fedorova AA (2007) Adsorption of micelle forming and non-micelle forming surfactants on the adsorbents of different nature. Colloid Surf A 306:68–74
Kosmulski M, Prochniak P, Rosenholm JB (2009) Electrokinetic studies of adsorption of ionic surfactants on titania from organic solvents. Colloid Surf A 348:298–300
Atia AA, Farag FM, El-Fatah A, Youssef M (2006) Studies on the adsorption of dodecyl benzene sulphonate and cetylpyridinium bromine at liquid/air and bentonite/liquid interfaces. Colloid Surf A 278:74–80
Gao XD, Chorover J (2010) Adsorption of sodium dodecyl sulphate (SDS) at ZnSe and α-Fe2O3 surfaces: Combining infrared spectroscopy and bath uptake studies. J Colloid Interf Sci 348:167–176
Davey PT, Scott TR (1976) Removal of iron from leach liquors by the goethite process. Hydrometallurgy 2:25–33
Ismael MRC, Carvalho JMR (2003) Iron recovery from sulphate leach liquors in zinc hydrometallurgy. Miner Eng 16:31–39
Davey PT, Scott TR (1975) Formation of β-FeOOH and α-Fe2O3 in the goethite process. T I Min Metall C 84:83–86
Jolsterå R, Gunneriusson L, Forsling W (2010) Adsorption and surface complex modeling of silicates on maghemite in aqueous suspensions. J Colloid Interf Sci 342:493–498
Rica RA, Jiménez ML, Delgado AV (2010) Electric permittivity of concentrated suspensions of elongated goethite particles. J Colloid Interf Sci 343:564–573
Kumpulainen S, von der Kammer F, Hofmann T (2008) Humic acid adsorption and surface charge effects on schwertmannite and goethite in acid sulphate waters. Water Res 42:2051–2060
Zhang JS, Stanforth R, Pehkonen SO (2007) Proton–arsenic adsorption ratios and zeta potential measurements: implications for protonation of hydroxyls on the goethite surface. J Colloid Interf Sci 315:13–20
Zhang JS, Stanforth R, Pehkonen SO (2007) Effect of replacing a hydroxyl group with a methyl group on arsenic(V) species adsorption on goethite (α-FeOOH). J Colloid Interf Sci 306:16–21
Madigan C, Leong YK, Ong BC (2009) Surface and rheological properties of as-received colloidal goethite (α-FeOOH) suspensions: pH and polyethylenimine effects. Int J Miner Process 93:41–47
Gallardo-Moreno AM, Gonzáles-Garcia CM, González-Martín M, Bruque JM (2004) Arrangement of SDS adsorbed layer on carbonaceous particles by zeta potential determinations. Colloid Surf A 249:57–62
Basar CA, Karagunduz A, Keskinler B, Cakici A (2003) Effect of presence of ions on surface characteristics of surfactant modified powdered activated carbon (PAC). Appl Surf Sci 214:169–174
Juang RS, Wu WL (2002) Adsorption of sulfate and copper(II) on goethite in relation to the changes of zeta potentials. J Colloid Interf Sci 249:22–29
Marsalek R, Navratilova Z (2011) Comparative study of CTAB adsorption on bituminous coal and clay mineral. Chem Pap Chem Zvesti 65:77–84
Acknowledgements
This article has been done in connection with the Institute of Environmental Technologies project, reg. no. CZ.1.05/2.1.00/03.0100 supported by the Research and Development for Innovations Operational Programme financed by European Union Structural Funds and from the means of the state budget of the Czech Republic. It was also supported by the Ministry of Industry and Trade of the Czech Republic (FR-T11/246).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Marsalek, R. (2014). Adsorption of Selected Ions on Ferro-Precipitates from Aqueous Solutions. In: Gupta Bhowon, M., Jhaumeer-Laulloo, S., Li Kam Wah, H., Ramasami, P. (eds) Chemistry: The Key to our Sustainable Future. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-7389-9_13
Download citation
DOI: https://doi.org/10.1007/978-94-007-7389-9_13
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-7388-2
Online ISBN: 978-94-007-7389-9
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)