Abstract
The application of Differential Scanning Calorimetry (DSC) has been proven useful in characterizing bituminous binders, distillates and crude oils. In this paper, results of the round robin test, organized by the Rilem TC 231 Nanotechnology-based Bituminous Materials (NBM) TG1 group are reported. The purpose is to investigate the repeatability and reproducibility of standard DSC measurements when applied to bituminous binders. In the full test program of the Rilem NBM group, DSC measurements are further compared to observations made in atomic force microscopy (AFM), AFM measurements are reported in a separate paper. Seven laboratories have participated in this round robin test. Four bituminous binders were investigated, containing various amounts of natural or added wax. The test program consisted of a well-defined isothermal annealing procedure, followed by a first heating and cooling scan, and afterwards followed by a second heating scan. At this stage, the data, as they were reported by the different participants, were compared. For the glass transition (Tg), mid temperatures, can be defined with a reasonable reproducibility, which improves if natural wax is not present. Regarding melting and crystallization, the shape of the melting curve is highly dependent on the thermal history of the samples. Peak temperatures of melting and crystallization phenomena were reported with a good reproducibility, while the reproducibility of melting enthalpies (or surface area’s under the melting and crystallization signals) was not satisfactory. Different reasons for this and recommendations for improving the results are discussed in the paper.
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References
Meyer, G.: Thermal Properties of Micro-crystalline Waxes in Dependence on the Degree of Deoiling. SOFW Journal 135(8), 43–50 (2009)
Edwards, Y.: Influence of Waxes on Bitumen and Asphalt Concrete Mixture Performance. Doctoral Thesis in Highway Engineering, KTH, Sweden (2005)
Claudy, P.M., Létoffé, J.-M., Martin, D., Planche, J.-P.: Thermal behavior of asphalt cements. Thermochimica Acta 324, 203–213 (1998)
Michon, L.C., Netzel, D.A., Turner, T.F.: A C13NMR and DSC study of the amorphous and crystalline phases in Asphalts. Energy & Fuels 13, 602–610 (1999)
Harrison, I.R., Wang, G., Hsu, T.C.: SHRP-A/UFR-92-612, A Differential Scanning Calorimetry Study of Asphalt Binders, Strategic Highway Research Program, National Research Council, Washington, DC (1992)
Kok, M.V., Létoffé, J.-M., Claudy, P., Martin, D., Garcin, M., Vollet, J.-L.: Comparison of wax appearance temperatures of crude oils by differential scanning calorimetry, thermomicroscopy and viscometry. Fuel 75(7), 787–790 (1996)
Lesueur, D.: Propriétés mécaniques des liants routiers. Thèse de Doctorat, Institut National Des Sciences appliquées de Lyon, France (1996)
Lesueur, D., Planche, J.-P., Dumas, P.: Détermination de la teneur en paraffines des bitumes. Bulletin des Laboratoires des Ponts et Chausseés 229, 3–11 (2000)
Lu, X., Redelius, P.: Effect of bitumen wax on asphalt mixture performance. Construction and Building Materials 21, 1961–1970 (2006)
Planche, J.P., Claudy, P.M., Létoffé, J.-M., Martin, D.: Using thermal analysis methods to better understand asphalt rheology. Thermochimica Acta 324, 223–227 (1998)
Soenen, H., De Visscher, J., Vanelstraete, A., Redelius, P.: The Influence of Thermal History on Binder Rutting Indicators. IJRMPD 6(2), 217–238 (2005)
Lu, X., Soenen, H., Redelius, P.: Impact of Bitumen Wax on Asphalt Performance – Low Temperature Cracking. In: E&E Conference (2004)
Claudy, P., Letoffe, J.M., Rondelez, F., Germanaud, L., King, G., Planche, J.P.: A new interpretation of time-dependent physical hardening in asphalt based on DSC and optical thermoanalysis. ACS 92, 1408–1426
Evans, M., Hesp, S.A.M.: Physical Hardening Effects on Stress Relaxation in Asphalt Cements and Implications for Pavement Performance transportation research board (2011)
Lu, X., Kalman, B., Redelius, P.: A new test method for determination of wax content in crude oils, residues and bitumens. Fuel 87, 1543–1551 (2008)
Lu, X., Langton, M., Olofsson, P., Redelius, P.: Wax morphology in bitumen. J. Mat. Sci. 40, 1893–1900 (2005)
Masson, J.-F., Polomark, G.M.: Bitumen microstructure by modulated differential scanning calorimetry. Thermochimica Acta 374, 105–114 (2001)
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Soenen, H. et al. (2013). Differential Scanning Calorimetry Applied to Bitumen: Results of the RILEM NBM TG1 Round Robin Test. In: Kringos, N., Birgisson, B., Frost, D., Wang, L. (eds) Multi-Scale Modeling and Characterization of Infrastructure Materials. RILEM Bookseries, vol 8. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6878-9_23
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DOI: https://doi.org/10.1007/978-94-007-6878-9_23
Publisher Name: Springer, Dordrecht
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