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Spherical Symmetry and Spins

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Group Theory Applied to Chemistry

Part of the book series: Theoretical Chemistry and Computational Modelling ((TCCM))

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Abstract

A brief excursion is made into the concept of continuous groups, with an example of the rotation groups. The purpose is to familiarize the reader with the concept of electron spin. The coupling of spins is discussed. Applications are taken from Crystal-Field Theory and Electron Spin Resonance.

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Notes

  1. 1.

    See, e.g., [3, 4].

  2. 2.

    Note that not all elements in the same class will be oriented in the positive hemisphere, as is clear from Tables 7.4 and 7.6.

  3. 3.

    Adapted from [10].

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Ceulemans, A.J. (2013). Spherical Symmetry and Spins. In: Group Theory Applied to Chemistry. Theoretical Chemistry and Computational Modelling. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6863-5_7

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