Abstract
This chapter focuses on the environmental response of carbon fibre-reinforced epoxy composites, where the matrix has been modified with carbon nanotubes. These newly developed hybrid aerospace systems have been recently introduced as alternatives to conventional high performance polymer composites due to their improved mechanical properties, toughness and damage sensing abilities as discussed in detail in previous chapters. First an attempt is made to outline the conditions that lead to environmental degradation specifically in aerospace environments. Next to that the response of typical aerospace composites to these environments is discussed. Following, the benefits and challenges in using hybrid aerospace composites in in-service conditions is presented. The degradation of hybrid composites due to exposure on hydro/hygrothermal loadings and galvanic corrosion is presented based on preliminary results. In this section, the focus is on epoxy based composites reinforced with carbon fibres. Matrix modification of these systems is provided by the addition of carbon nanotubes.
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References
Apicella, A., Nicolais, L.: Role of processing on the durability of epoxy composites in humid environments. Ind. Eng. Chem. Prod. Res. Dev. 23, 288–297 (1984). doi:10.1021/i300014a024
Apicella, A., Nicolais, L.: Network structure and plasticization of epoxy-based resins. Makromol. Chem. Macromol. Symp. 7, 97–113 (1987). doi:10.1002/masy.19870070111
Asp, L.E.: The effects of moisture and temperature on the interlaminar delamination toughness of a carbon/epoxy composite. Compos. Sci. Technol. 58, 967–977 (1998). doi:10.1016/S0266-3538(97)00222-4
Baker, A.A.: Joining and repair of aircraft composite structures. In: Mallick, P.K. (ed.) Composite Engineering Handbook. Marcel Dekker, New York (1997)
Baker, A.A.: Bonded composite repair of fatigue-cracked primary aircraft structure. Compos. Struct. 47, 431–443 (1999). doi:10.1016/S0263-8223(00)00011-8
Bank, L.C., Gentry, T.R., Barkatt, A.: Accelerated test methods to determine the long-term behavior of FRP composite structures: environmental effects. J. Reinf. Plast. Compos. 14, 559–587 (1995). doi:10.1177/073168449501400602
Barkoula, N.M., Paipetis, A., Matikas, T., Vavouliotis, A., Karapappas, P., Kostopoulos, V.: Environmental degradation of carbon nanotube modified carbon fibre reinforced laminates: an electrical resistivity study. Mech. Compos. Mater. 45, 21–32 (2009). doi:10.1007/s11029-009-9059-8
Barkoula, N.M., Gkikas, G., Makri, A., Matikas, T.E., Paipetis, A.: Effect of the environmental degradation on the viscoelastic response of nano modified epoxies and CTRPs. In: Proceedings of the 14th European Conference on Composite Materials (ECCM14), Budapest, Hungary. Paper ID: 045-ECCM14 (2010)
Bellenger, V., Verdu, J.: Photooxidation of amine crosslinked epoxies II. Influence of structure. J. Appl. Polym. Sci. 28, 2677–2688 (1983). doi:10.1002/app. 1983.070280901
Bellenger, V., Verdu, J.: Oxidative skeleton breaking in epoxy–amine networks. J. Appl. Polym. Sci. 30, 363–374 (1985). doi:10.1002/app. 1985.070300132
Bierwagen, G.P., Tallman, D.E.: Choice and measurement of crucial aerospace coating system properties. Prog. Org. Coat. 41, 201–217 (2001). doi:10.1016/S0300-9440(01)00131-X
Bierwagen, G., Battocchi, D., Simoes, A., Stamness, A., Tallman, D.: The use of multiple electrochemical techniques to characterize Mg-rich primers for Al alloys. Prog. Org. Coat. 59, 172–178 (2007). doi:10.1016/j.porgcoat.2007.01.022
Bockenheimer, C., Fata, D., Possart, W.: New aspects of aging in epoxy networks. II. Hydrothermal aging. J. Appl. Polym. Sci. 91, 369–377 (2004). doi:10.1002/app. 13093
Bondzic, S., Hodgkin, J., Krstina, J., Mardel, J.: Chemistry of thermal ageing in aerospace epoxy composites. J. Appl. Polym. Sci. 100, 2210–2219 (2006). doi:10.1002/app. 23692
Botelho, E.C., Pardini, L.C., Rezende, M.C.: Hygrothermal effects on the shear properties of carbon fibre/epoxy composites. J. Mater. Sci. 41, 7111–7118 (2006a). doi:10.1007/s10853-006-0933-7
Botelho, E.C., Pardini, L.C., Rezende, M.C.: Damping behavior of hygrothermally conditioned carbon fibre/epoxy laminates. J. Appl. Polym. Sci. 106, 3143–3148 (2006b)
Bowles, K.J., Jayne, D., Leonhardt, T.A.: Isothermal aging effects on PMR-15 resin. SAMPE Q. 24, 2–9 (1993)
Bowles, K.J., McCorkle, L., Ingram, L.: Comparison of graphite fabric reinforced PMR-15 and Avimid N composites after long-term isothermal aging at various temperatures. J. Adv. Mater. 30, 27–35 (1998)
Buchheit, R.G.: Compilation of corrosion potentials reported for intermetallicphases in aluminum alloys. J. Electrochem. Soc. 142, 3994–3996 (1995)
Buchheit, R.G., Grant, R.P., Hlava, P.F., McKenzie, B., Zender, G.L.: Local dissolution phenomena associated with S phase (Al2CuMg) particles in aluminum alloy 2024-T3. J. Electrochem. Soc. 144, 2621–2628 (1997)
Buehler, F.U., Seferis, J.C.: Effect of reinforcement and solvent content on moisture absorption in epoxy composite materials. Compos. Part A-Appl. Sci. Manuf. 31, 741–748 (2000). doi:10.1016/S1359-835X(00)00036-1
Chae, H.G., Minus, M.L., Kumar, S.: Oriented and exfoliated single wall carbon nanotubes in polyacrylonitrile. Polymer 47, 3494–3504 (2006). doi:10.1016/j.polymer.2006.03.050
Chen, W., Lu, H., Nutt, S.R.: The influence of functionalized MWCNT reinforcement on the thermomechanical properties and morphology of epoxy nanocomposites. Compos. Sci. Technol. 68, 2535–2542 (2008). doi:10.1016/j.compscitech.2008.05.011
Chin, J.W., Nguyen, T., Aouadi, K.: Effects of environmental exposure on Fibre-Reinforced Plastic (FRP) materials used in construction. JCTR 19, 205–213 (1997)
Chou, P.J.C., Ding, D.J.: Characterization of moisture absorption and its Influence on composite structures. J. Thermoplast. Compos. 13, 207–225 (2000). doi:10.1177/089270570001300303
Chow, W.S.: Water absorption of epoxy/glass fibre/organo-montmorillonite nanocomposites. Express Polym. Lett. 1, 104–108 (2007). doi:10.3144/expresspolymlett.2007.18
Clark, G., Saunders, D.S., van Blaricum, T.J., Richmond, M.: Moisture absorption in graphite/epoxy laminates. Compos. Sci. Technol. 39, 355–375 (1990). doi:10.1016/0266-3538(90)90081-F
Colin, X., Marais, C., Verdu, J.: Thermal oxidation kinetics for a poly(bismaleimide). J. Appl. Polym. Sci. 82, 3418–3430 (2001). doi:10.1002/app. 2203
Collings, T.A., Stone, D.E.W.: Hygrothermal effects in CFC laminates: damaging effects of temperature, moisture and thermal spiking. Compos. Struct. 3, 341–378 (1985). doi:10.1016/0263-8223(85)90061-3
Dao, B., Hodgkin, J., Krstina, J., Mardel, J., Tian, W.: Accelerated aging versus realistic aging in aerospace composite materials. J. Appl. Polym. Sci. 102, 4291–4303 (2006a). doi:10.1002/app. 24862
Dao, B., Hodgkin, J., Krstina, J., Mardel, J., Tian, W.: Accelerated aging versus realistic aging in aerospace composite materials. II. Chemistry of thermal aging in a structural composite. J. Appl. Polym. Sci. 102, 3221–3232 (2006b). doi:10.1002/app. 24573
Dao, B., Hodgkin, J., Krstina, J., Mardel, J., Tian, W.: Accelerated ageing versus realistic ageing in aerospace composite materials. III. The chemistry of thermal ageing in bismaleimide based composites. J. Appl. Polym. Sci. 105, 2062–2072 (2007a). doi:10.1002/app. 26320
Dao, B., Hodgkin, J.H., Krstina, J., Mardel, J., Tian, W.: Accelerated ageing versus realistic ageing in aerospace composite materials. IV. Hot/wet ageing effects in a low temperature cure epoxy composite. J. Appl. Polym. Sci. 106, 4264–4276 (2007b). doi:10.1002/app. 27104
Delozier, D.M., Watson, K.A., Smith, J.G., Connell, J.W.: Preparation and characterization of space durable polymer nanocomposite films. Compos. Sci. Technol. 65, 749–755 (2004). doi:10.1016/j.compscitech.2004.10.026
Dyakonov, T., Mann, P.J., Chen, Y., Stevenson, W.T.K.: Thermal analysis of some aromatic amine cured model epoxy resin systems–II: residues of degradation. Polym. Degrad. Stabil. 54, 67–83 (1996). doi:10.1016/0141-3910(96)00096-1
Fidelusa, J.D., Wiesela, E., Gojny, F.H., Schulte, K., Wagnera, H.D.: Thermo-mechanical properties of randomly oriented carbon/epoxy nanocomposites. Compos. Part A 36, 1555–1561 (2005). doi:10.1016/j.compositesa.2005.02.006
Fox, B.L., Lowe, A., Hodgkin, J.H.: Investigation of failure mechanisms in aged aerospace composites. Eng. Fail. Anal. 11, 235–241 (2004). doi:10.1016/j.engfailanal.2003.05.010
Frassine, R., Pavan, A.: The combined effects of curing and environmental exposure on fracture properties of woven carbon/epoxy laminates. Compos. Sci. Technol. 51, 495–503 (1994). doi:10.1016/0266-3538(94)90082-5
Garton, A.: Infrared spectroscopic characterization of epoxy matrix composites. J. Macromol. Sci. Part A-Pure Appl. Chem. 26, 17–41 (1989)
Gkikas, G., Paipetis, A., Barkoula, N.M., Lekatou, A., Sioulas, D.: Enhanced bonded aircraft repair using nano-modified adhesives. In: Proceedings of the 14th European Conference on Composite Materials (ECCM14), Budapest, Hungary. Paper ID: 660-ECCM14 (2010)
Gojny, F.H., Schulte, K.: Functionalisation effect on the thermo-mechanical behavior of multiwall carbon nanotube/epoxy composite. Compos. Sci. Technol. 64, 2303–2308 (2004). doi:10.1016/j.compscitech.2004.01.024
Grenier-Loustalot, M.F., Metras, F., Grenier, P., Chenard, J.Y., Horny, P.: Mecanismes reactionnels, cinetique et structure du reseau de systemes thermodurcissables type TGDDM-DDS. Eur. Polym. J. 26, 83–100 (1990). doi:10.1016/0014-3057(90)90102-A
Hancox, N.L.: Overview of effects of temperature and environment on performance of polymer matrix composite properties. Plast. Rubber Compos. Process Appl. 27, 97–105 (1998)
Harmon, J.P., Muisener, P.A.O., Clayton, L., D’Angelo, J., Sikder, A.K., Kumar, A., et al.: Ionizing radiation effects on interfaces in carbon nanotube-polymer composites. Mater. Res. Soc. Symp. Proc. 697, 425–435 (2002)
Hatakeyama, T., Quinn, F.: Thermal Analysis: Fundamentals and Application to Polymer Science, 2nd edn. Wiley, Chichester (1999)
Hough, J.A., Xiang, Z.D., Jones, F.R.: The effect of thermal spiking and resultant enhanced moisture absorption on the mechanical and viscoelastic properties of carbon fibre reinforced epoxy laminates. Key Eng. Mater. 144, 27–42 (1998). doi:10.4028/www.scientific.net/KEM.144.27
Hwang, T., Pu, L., Kim, S.W., Oh, Y.S., Nam, J.D.: Synthesis and barrier properties of poly(vinylidene chloride-co-acrylonitrile)/SiO2 hybrid composites by sol-gel process. J. Membr. Sci. 345, 90–96 (2009). doi:10.1016/j.memsci.2009.08.029
Ilevbare, G.O., Scully, J.R., Yuan, J., Kelly, R.G.: Inhibition of pitting corrosion on aluminum alloy 2024-T3: effect of soluble chromate additions vs. chromate conversion coating. Corrosion 56, 227–242 (2000)
Ivanova, K.I., Pethrick, R.A., Affrossman, S.: Hygrothermal aging of rubber-modified and mineral-filled dicyandiamide-cured DGEBA epoxy resin. II. Dynamic mechanical thermal analysis. J. Appl. Polym. Sci. 82, 3477–3485 (2001). doi:10.1002/app. 2209
Jedidi, J., Jacquemin, F., Vautrin, A.: Design of accelerated hygrothermal cycles on polymer matrix composites in the case of a supersonic aircraft. Compos. Struct. 68, 429–437 (2005). doi:10.1016/j.compstruct.2004.04.009
Jedidi, J., Jacquemin, F., Vautrin, A.: Accelerated hygrothermal cyclical tests for carbon/epoxy laminates. Compos. Part A-Appl. Sci. Manuf. 37, 636–645 (2006). doi:10.1016/j.compositesa.2005.05.007
Jelinski, L.W., Dumais, J.J., Cholli, A.L., Ellis, T.S., Karasz, F.E.: Nature of the water-epoxy interaction. Macromolecules 18, 1091–1095 (1985). doi:10.1021/ma00148a008
Joshi, K.M.: The effect of moisture on the shear properties of carbon fibre composites. Composites 14, 196–200 (1983). doi:10.1016/0010-4361(83)90005-8
Kenig, S., Moshonov, A., Shucrun, A., Maron, G.: Environmental effects on shear delamination of fabric-reinforced epoxy composites. Int. J. Adhes. Adhes. 9, 38–45 (1989). doi:10.1016/0143-7496(89)90145-0
Kerr, J.R., Haskins, J.F.: Time-Temperature-Stress Capabilities of Composite Materials for Advanced Supersonic Technology Application. NASA CR-178272 (1987)
Kim, J.K., Hu, C., Woo, R.S.C., Sham, M.L.: Moisture barrier characteristics of organoclay-epoxy nanocomposites. Compos. Sci. Technol. 65, 805–813 (2005). doi:10.1016/j.compscitech.2004.10.014
Kojima, Y., Usuki, A., Kawasumi, M., Okada, A., Kurauchi, T., Kamigaito, O.: Sorption of water in nylon 6-clay hybrid. J. Appl. Polym. Sci. 49, 1259–1264 (1993). doi:10.1002/app. 1993.070490715
Kostopoulos, V., Tsotra, P., Karapappas, P., Tsantzalis, S., Vavouliotis, A., Loutas, T.H., Paipetis, A., Friedrich, K., Tanimoto, T.: Mode I interlaminar fracture of CNF or/and PZT doped CFRPs via acoustic emission monitoring. Compos. Sci. Technol. 67, 822–828 (2007). doi:10.1016/j.compscitech.2006.02.038
Kumar, B.G., Singh, R.P., Nakamura, T.: Degradation of carbon fibre-reinforced epoxy composites by ultraviolet radiation and condensation. J. Compos. Mater. 36, 2713–2733 (2002). doi:10.1177/002199802761675511
Lai, J.Y., Young, K.F.: Dynamics of graphite/epoxy composite under delamination fracture and environmental effects. Compos. Struct. 30, 25–32 (1995). doi:10.1016/0263-8223(94)00017-4
Li, G., Lee-Sullivan, P., Thring, R.: Determination of activation energy for glass transition of an epoxy adhesive using dynamic mechanical analysis. J. Therm. Anal. Calorim. 60, 377–390 (2000). doi:10.1023/A:1010120921582
Li, Y., Miranda, J., Sue, H.J.: Hygrothermal diffusion behavior in bismaleimide resin. Polymer 42, 7791–7799 (2001). doi:10.1016/S0032-3861(01)00241-5
Li, X., Gao, H., Scrivens, W.A., Fei, D., Xu, X., Sutton, M.A., Reynolds, A.P., Myrick, M.L.: Nanomechanical characterization of single-walled carbon nanotube reinforced epoxy composites. Nanotechnology 15, 1416–1423 (2004). doi:10.1088/0957-4484/15/11/005
Liau, W.B., Tseng, F.P.: The effect of long-term ultraviolet light irradiation on polymer matrix composites. Polym. Compos. 19, 440–445 (1998). doi:10.1002/pc.10118
Lin, Y.C.J.: Investigation of the moisture-desorption characteristics of epoxy resin. Polym. Res. 13, 369–374 (2006). doi:10.1007/s10965-006-9053-y
Liu, M., Wu, P., Ding, Y., Chen, G., Li, S.: Two-dimensional (2D) ATR−FTIR spectroscopic study on water diffusion in cured epoxy resins. Macromolecules 35, 5500–5507 (2002). doi:10.1021/ma011819f
Luoma, G.A., Rowland, R.D.: Environmental degradation of an epoxy resin matrix. J. Appl. Polym. Sci. 32, 5777–5790 (1986). doi:10.1002/app. 1986.070320710
Maggana, C., Pissis, P.: Water sorption and diffusion studies in an epoxy resin system. J. Polym. Sci. Part B-Polym. Phys. 37, 1165–1182 (1999). doi:10.1002/(SICI)1099-0488(19990601)37:11<1165::AID-POLB11>3.0.CO;2-E
Mahieux, C.A.: Environmental Degradation in Industrial Composites. Elsevier, Oxford (2006)
Mangalgiri, P.D.: Composite materials for aerospace applications. Bull. Mater. Sci. 22, 657–664 (1999). doi:10.1007/BF02749982
Matzkanin, G.A., Hansen, G.P.: Heat Damage in Graphite Epoxy Composites: Degradation, Measurement and Detection: A State-of-the-Art Report. NTIAC-SR-98-02 (1998)
McKague, E.L., Halkias, J.E., Reynolds, J.D.: Moisture in composites: the effect of supersonic service on diffusion. J. Compos. Mater. 9, 2–9 (1975). doi:10.1177/002199837500900101
Merdas, I., Thominette, F., Tcharkhtchi, A., Verdu, J.: Factors governing water absorption by composite matrices. J. Compos. Sci. Technol. 62, 487–492 (2002). doi:10.1016/S0266-3538(01)00138-5
Minus, M.L., Chae, H.G., Kumar, S.: Single wall carbon nanotube templated oriented crystallization of poly(vinyl alcohol). Polymer 47, 3705–3710 (2006). doi:10.1016/j.polymer.2006.03.076
Mitchell, C.A., Bahar, J.L., Arepalli, S.: Dispersion of functionalized carbon nanotubes in polystyrene. Macromolecules 35, 8825–8830 (2002). doi:10.1021/ma020890y
Miyagawa, H., Rich, M.J., Drzal, L.T.: Thermo-physical properties of epoxy nanocomposites reinforced by carbon nanotubes and vapor grown carbon fibres. Thermochim. Acta 442, 67–73 (2006). doi:10.1016/j.tca.2006.01.016
Mohd Ishak, Z., Ariffin, A., Senawi, R.: Effects of hygrothermal aging and a silane coupling agent on the tensile properties of injection molded short glass fibre reinforced poly(butylene terephthalate) composites. Eur. Polym. J. 37, 1635–1647 (2001). doi:10.1016/S0014-3057(01)00033-7
Montazeri, A., Montazeri, N.: Viscoelastic and mechanical properties of multi walled carbon nanotube/epoxy composites with different nanotube content. Mater. Des. 32, 2301–2307 (2011). doi:10.1016/j.matdes.2010.11.003
Montazeri, A., Khavandi, A., Javadpour, J., Tcharkhtchi, A.: Viscoelastic properties of multi-walled carbon nanotube/epoxy composites using two different curing cycles. J. Nano Res. 13, 33–39 (2011). doi:10.4028/www.scientific.net/JNanoR.13.33
Morgan, R.J., Mones, E.T.: The cure reactions, network structure, and mechanical response of diaminodiphenyl sulfone-cured tetraglycidyl 4,4′ diaminodiphenyl methane epoxies. J. Appl. Polym. Sci. 33, 999–1020 (1987). doi:10.1002/app. 1987.070330401
Morgan, R.J., O’neal, J.E.: The durability of epoxies. Polym. Plast. Tech. Eng. 10, 49–116 (1978). doi:10.1080/03602557808055845
Morgan, R.J., Shin, E.E., Lincoln, J.: Thermal properties of high temperature polymer matrix fibrous composites. In: Cheng, S.Z.D. (ed.) Handbook of Thermal Analysis and Calorimetry, Elsevier Science BV, Amsterdam (2002). doi: 10.1016/S1573-4374(02)80015-2
Muisener, P.A.O., Clayton, L., D’Angelo, J., Harmon, J.P., Sikder, A.K., Kumar, A., et al.: Effects of gamma radiation on poly(methyl methacrylate)/single-wall nanotube composites. J. Mater. Res. 17, 2507–2513 (2002). doi:10.1017/S0884291400061914
Musto, P., Ragosta, G., Mascia, L.: Vibrational spectroscopy evidence for the dual nature of water sorbed into epoxy resins. Chem. Mater. 12, 1331–1341 (2000). doi:10.1021/cm9906809
Musto, P., Ragosta, G., Russo, P., Mascia, L.: Thermal-oxidative degradation of epoxy and epoxy-bismaleimide networks: kinetics and mechanism. Macromol. Chem. Phys. 202, 3445–3458 (2001). doi:10.1002/1521-3935(20011201)202:18<3445::AID-MACP3445>3.0.CO;2-N
Musto, P., Ragosta, G., Scarinzi, G., Mascia, L.: Probing the molecular interactions in the diffusion of water through epoxy and epoxy–bismaleimide networks. Polym. Sci. Part B: Polym. Phys. 40, 922–938 (2002). doi:10.1002/polb.10147
Najafi, E., Shin, K.: Radiation resistant polymer-carbon nanotube nanocomposite thin films. Colloid Surf. A 257, 333–337 (2005). doi:10.1016/j.colsurfa.2004.10.076
Najafi, E., Lee, J.O., Shin, K.: Materials for space applications. Mater. Res. Soc. Symp. Proc. 851, 279–285 (2005)
Nam, J.D., Seferis, J.C.: Anisotropic thermo-oxidative stability of carbon fibre reinforced polymeric composites. J. C. SAMPE. Q. 24, 10–18 (1992)
Ngono, Y., Marechal, Y., Mermilliod, N.: Epoxy–amine reticulates observed by infrared spectrometry. I: hydration process and interaction configurations of embedded H2O molecules. J. Phys. Chem. B 103, 4979–4985 (1999). doi:10.1021/jp984809y
Nielsen, K.L.C., Hill, D.J.T., Watson, K.A., Connell, J.W., Ikeda, S., Kudo, H., Whittaker, A.K.: The radiation degradation of a nanotube-polimide nanocomposite. Polym. Degrad. Stabil. 93, 169–175 (2008). doi:10.1016/j.polymdegradstab.2007.10.010
Nogueira, P., RamÃrez, C., Torres, A., Abad, M.J., Cano, J., López, J., López-Bueno, I., Barral, L.: Effect of water sorption on the structure and mechanical properties of an epoxy resin system. J. Appl. Polym. Sci. 80, 71–80 (2001). doi:10.1002/1097-4628(20010404)80:1<71::AID-APP1077>3.0.CO;2-H
Ogi, K., Takeda, N.: Effect of moisture content on non-linear deformation behaviour of CF/epoxy composites. J. Compos. Mater. 31, 530–551 (1997). doi:10.1177/002199839703100601
Papanicolaou, G.C., Kosmidou, T., Vatalis, A.S., Delides, C.G.: Water absorption mechanism and some anomalous effects on the mechanical and viscoelastic behavior of an epoxy system. J. Appl. Polym. Sci. 99, 1328–1339 (2006). doi:10.1002/app. 22095
Patel, S.R., Case, S.W.: Durability of hygrothermally aged graphite/epoxy woven composite under combined hygrothermal conditions. Int. J. Fatig. 24, 1295–1301 (2002). doi:10.1016/S0142-1123(02)00044-0
Pearce, P.J., Davidson, R.G., Morris, C.E.M.: Hydrolytic stability of some uncured epoxy resins. J. Appl. Polym. Sci. 26, 2363–2372 (1981). doi:10.1002/app. 1981.070260722
Prolongo, S.G., Gude, M.R., Urena, A.: Improving the flexural and thermomechanical properties of amino-functionalized carbon nanotube/epoxy composites by using a pre-curing treatment. Compos. Sci. Technol. 71, 765–771 (2011). doi:10.1016/j.compscitech.2011.01.028
Pulikkathara, M.X., Shofner, M.L., Wilkins, R., Vera, J.G., Barrera, E.V., Rodriguez-Macias, F.J., Vaidyanathan, R.K., Green, C.E., Condon, C.G.: Fluorinated single wall nanotube/polyethylene composites for multifunctional radiation protection. Nanomater. Struct. Appl. 740, 365–370 (2003)
Pulikkathara, M.X., Pena-Paras, L., McIntosh, D., Chipara, M., Wilkins, R., Barrera, E.V., Dye, D., Zaleski, J.M.: Proton beam induced modifications in multi-functional polyethylene-based carbon nanotube composites. Mater. Res. Soc. Symp. Proc. 851, 261–266 (2005)
Qu, L.W., Lin, Y., Hill, D.E., Zhou, B., Wang, W., Sun, X.F., et al.: Polyimide-functionalized carbon nanotubes: synthesis and dispersion in nanocomposite films. Macromolecules 376055–6060 (2004). doi:10.1021/ma0491006
Ramanathan, T., Liu, H., Brinson, L.C.: Functionalized SWNT/polymer nanocomposites for dramatic property improvement. J. Polym. Sci. Part B: Polym. Phys. 43, 2269–2279 (2005). doi:10.1002/polb.20510
Ranby, B., Rabek, J.: Photodegradation, Photo-Oxidation and Photostabilization of Polymers. Wiley, London (1975)
Ray, B.C.: Temperature effect during humid ageing on interfaces of glass and carbon fibres reinforced epoxy composites. J. Colloid Interface Sci. 298, 111–117 (2006). doi:10.1016/j.jcis.2005.12.023
Reynolds, T.G., Mc Manus, H.L.: Accelerated tests of environmental degradation in composite materials. In: Grant, P., Rousseau, C.Q. (eds.) Composite Structures: Theory and Practice, ASTM STP 1383:513–525. American Society for Testing and Materials, West Conshohocken (2000)
Reynolds, L.B., Twite, R., Donley, M.S., Bierwagen, G.P., Khobaib, M.: Preliminary evaluation of the anticorrosive properties for aircraft coatings by electrochemical methods. Prog. Org. Coat. 32, 31–34 (1997). doi:10.1016/S0300-9440(97)00098-2
Schoeppner, G., Tandon, G., Pochiraju, K.: Predicting thermooxidative degradation and performance of high-temperature polymer matrix composites. In: Talreja, R. (ed.) Multiscale Modeling and Simulation of Composite Materials and Structures, Springer, New York (2008). doi: 10.1007/978-0-387-68556-4_9
Selzer, R., Friedrich, K.: Influence of water up-take on interlaminar fracture properties of carbon fibre-reinforced polymer composites. J. Mater. Sci. 30, 334–338 (1995). doi:10.1007/BF00354392
Seyhan, A.T., Gojny, F.H., Tanoglu, M., Schulte, K.: Rheological and dynamic-mechanical behavior of carbon nanotube/vinyl ester–polyester suspensions and their nanocomposites. Eur. Polym. J. 43, 2836–2847 (2007). doi:10.1016/j.eurpolymj.2007.04.022
Shen, C., Springer, G.S.: Moisture absorption and desorption of composite materials. J. Compos. Mater. 10, 2–20 (1976). doi:10.1177/002199837601000101
Shen, J.F., Huang, W.S., Wu, L.P., Hu, Y.Z., Ye, M.X.: The reinforcement role of different amino-functionalized multi-walled carbon nanotubes in epoxy nanocomposites. Compos. Sci. Technol. 67, 3041–3050 (2007a). doi:10.1016/j.compscitech.2007.04.025
Shen, J.F., Huang, W.S., Wu, L.P., Hu, Y.Z., Ye, M.X.: Thermo-physical properties of epoxy nanocomposites reinforced with amino-fucntionalized multi-walled carbon nanotubes. Compos. Part A 38, 1331–1336 (2007b). doi:10.1016/j.compositesa.2006.10.012
Shin, K.B., Kim, C.G., Hong, C.S., Lee, H.H.: Prediction of failure thermal cycles in graphite/epoxy composite materials under simulated low earth orbit environments. Compos. Part B-Eng. 31, 223–235 (2000a). doi:10.1016/S1359-8368(99)00073-6
Shin, E.E., Morgan, R.J., Zhou, J., Lincoln, J., Jurek, R., Curliss, D.B.: Hygrothermal durability and thermal aging behavior prediction of high-temperature polymer-matrix composites and their resins. J. Thermoplast. Compos. 1340–57 (2000b). doi:10.1177/089270570001300104
Signor, A.W., VanLandingham, M.R., Chin, J.W.: Effects of ultraviolet radiation exposure on vinyl ester resins: characterization of chemical, physical and mechanical damage. Polym. Degrad. Stabil. 79, 359–368 (2003). doi:10.1016/S0141-3910(02)00300-2
Singh, R.P., Khait, M., Zunjarrao, S.C., Korach, C.S., Pandey, G.: Environmental degradation and durability of epoxy-clay nanocomposites. J. Nanomater. 352746 (2010). doi:10.1155/2010/352746
Smith, J.G., Connell, J.W., Delozier, D.M., Lillehei, P.T., Watson, K.A., Lin, Y., et al.: Space durable polymer/carbon nanotube films for electrostatic charge mitigation. Polymer 45, 825–836 (2004a). doi:10.1016/j.polymer.2003.11.024
Smith, J.G., Delozier, D.M., Connell, J.W., Watson, K.A.: Carbon nanotube-conductive additive-space durable polymer nanocomposite films for electrostatic charge dissipation. Polymer 45, 6133–6142 (2004b). doi:10.1016/j.polymer.2004.07.004
Smith, J.G., Connell, J.W., Watson, K.A., Danehy, P.M.: Optical and thermo-optical properties of space durable polymer/carbon nanotube films: experimental results and empirical equations. Polymer 46, 2276–2284 (2005). doi:10.1016/j.polymer.2005.01.022
Springer, G.S.: Chapter 3: Moisture absorption in fibre-resin composites. In: Pritchard, G. (ed.) Developments in Reinforced Plastics. Applied Science, London (1982)
St John, N.A., George, G.A.: Diglycidyl amine – epoxy resin networks: kinetics and mechanisms of cure. Prog. Polym. Sci. 19, 755–795 (1994). doi:10.1016/0079-6700(94)90032-9
Tatro, S.R., Clayton, L.M., Muisener, P.A.O., Rao, A.M., Harmon, J.P.: Probing multi-walled nanotube/poly(methyl methacrylate) composites with ionizing radiation. Polymer 45, 1971–1979 (2004). doi:10.1016/j.polymer.2004.01.012
Tian, W., Hodgkin, J.: Long-term aging in a commercial aerospace composite sample: chemical and physical changes. J. Appl. Polym. Sci. 115, 2981–2985 (2010). doi:10.1002/app. 31394
Tsotsis, T.K., Lee, S.M.: Long-term thermo-oxidative aging in composite materials: failure mechanisms. Compos. Sci. Technol. 58, 355–368 (1998). doi:10.1016/S0266-3538(97)00123-1
Tsotsis, T.K., Keller, S., Bardis, J., Bish, J.: Preliminary evaluation of the use of elevated pressure to accelerate thermo-oxidative aging in composites. Polym. Degrad. Stabil. 64, 207–212 (1999). doi:10.1016/S0141-3910(98)00190-6
Valentini, L., Biagiotti, J., Kenny, J.M., Manchado, M.A.L.: Physical and mechanical behavior of single-walled carbon nanotube/polypropylene/ethylene–propylene–diene rubber nanocomposites. J. Appl. Polym. Sci. 89, 2657–2663 (2003). doi:10.1002/app. 12319
Wang, S., Chung, D.D.L.: Effect of moisture on the interlaminar interface of a carbon fibre polymer-matrix composites, studied by contact electrical resistivity measurement. Compos. Interface. 9(5), 453–458 (2002). doi:10.1163/15685540260256546
Wang, S., Kowalik, D.P., Chung, D.D.L.: Effects of the temperature, humidity, and stress on the interlaminar interface of carbon fibre polymer-matrix composites, studied by contact electrical resistivity measurements. J. Adhes. 78, 189–200 (2002). doi:10.1080/00218460210384
Wang, J.G., Fang, Z.P., Gu, A.J., Xu, L.H., Liu, F.: Effect of amino-fucntionalization of multi-walled carbon nanotubes on the dispersion with epoxy resin matrix. J. Appl. Polym. Sci. 100, 97–104 (2006). doi:10.1002/app. 22647
Watson, K.A., Ghose, S., Delozier, D.M., Smith, J.G., Connell, J.W.: Transparent, flexible, conductive carbon nanotube coatings for electrostatic charge mitigation. Polymer 46, 2076–2085 (2005). doi:10.1016/j.polymer.2004.12.057
Weitsman, Y.: Moisture in composites: sorption and damage. In: Reifsnider, K.L. (ed.) Fatigue of Composite Materials, pp. 385–429. Elsevier Science Publishers, Amsterdam (1991)
Wilkins, R., Pulikkathara, M.X., Khabashesku, V.N., Barrera, E.V., Vaidyanathan, R.K., Thibeault, S.A.: Materials for space applications. Mater. Res. Soc. Symp. Proc. 851, 267–278 (2005)
Windle, A.: Two defining moments: a personal view. Compos. Sci. Technol. 67, 929–930 (2007). doi:10.1016/j.compscitech.2006.07.037
Won, Y.G., Galy, J., Ge’rard, J.F., Pascault, J.P., Vellenger, V., Verdu, J.: Influence of sequence of chemical reactions on kinetics and solid state behavior for bisphenol A diglycidyl ether–bisphenol A–sulfanilamide ternary blends. Polymer 31, 179–186 (1990). doi:10.1007/PL00010783
Woo, R.S.C., Chen, Y., Zhu, H., Li, J., Kim, J.K., Leung, C.K.Y.: Environmental degradation of epoxy-organoclay nanocomposites due to UV exposure. Part I: photo-degradation. Compos. Sci. Technol. 67, 3448–3456 (2007). doi:10.1016/j.compscitech.2007.03.004
Woo, R.S.C., Zhu, H., Leung, C.K.Y., Kim, J.K.: Environmental degradation of epoxy-organoclay nanocomposites due to UV exposure. Part II: residual mechanical properties. Compos. Sci. Technol. 68, 2149–2155 (2008). doi:10.1016/j.compscitech.2008.03.020
Wood, C.A., Bradley, W.L.: Determination of the effect of seawater on the interfacial strength of an interlay E-glass/graphite/epoxy composite by In-Situ Observation of Transverse Cracking in an Environmental SEM. Compos. Sci. Technol. 57(8), 1033–1043 (1997). doi:10.1016/S0266-3538(96)00170-4
Xiao, G.Z., Shanahan, M.E.R.: Water absorption and desorption in an epoxy resin with degradation. J. Polym. Sci. Part B: Polym. Phys. 35, 2659–2670 (1997). doi:10.1002/(SICI)1099-0488(19971130)35:16<2659::AID-POLB9>3.0.CO;2-K
Xiao, G.Z., Delamar, M., Shanahan, M.: Irreversible interactions between water and DGEBA/DDA epoxy resin during hygrothermal aging. J. Appl. Polym. Sci. 65, 449–458 (1997). doi:10.1002/(SICI)1097-4628(19970718)65:3<449::AID-APP4>3.0.CO;2-H
Yip, M.C., Wu, H.Y.: Fatigue and electrical properties of CNT/phenolic composites under moisture-temperature effects. Key Eng. Mater. 334–335, 769–772 (2007). doi:10.4028/www.scientific.net/KEM.334-335.769
Youssef, Z., Jacquemin, F., Gloaguen, D., Guillen, R.: A multi-scale analysis of composite structures: application to the design of accelerated hygrothermal cycles. Compos. Struct. 82, 302–309 (2008). doi:10.1016/j.compstruct.2007.01.008
Zhang, Y.C., Wang, X.: Hygrothermal effects on interfacial stress transfer characteristics of carbon nanotubes-reinforced composites system. J. Reinf. Plast. Compos. 25, 71–88 (2006a). doi:10.1177/0731684406055456
Zhang, Y.C., Wang, X.: Hygrothermal effects on initial frictional pull-out force of CNTs-reinforced composites. J. Therm. Stress. 29, 67–92 (2006b). doi:10.1080/01495730500257425
Zhou, J., Lucas, J.P.: Hygrothermal effects of epoxy resin. Part I: the nature of water in epoxy. Polymer 40, 5505–5512 (1999a). doi:10.1016/S0032-3861(98)00790-3
Zhou, J., Lucas, J.P.: Hygrothermal effects of epoxy resin. Part II: variations of glass transition temperature. Polymer 40, 5513–5522 (1999b). doi:10.1016/S0032-3861(98)00791-5
Zunjarrao, S.C., Sriraman, R., Singh, R.P.: Effect of processing parameters and clay volume fraction on the mechanical properties of epoxy-clay nanocomposites. J. Mater. Sci. 41, 2219–2228 (2006). doi:10.1007/s10853-006-7179-2
Acknowledgements
The author would like to acknowledge the EU (IAPETUS PROJECT, Grant Agreement Number: ACP8-GA-2009-234333) for financial support. Part of the presented experimental work is performed within the framework of the PhD study of PhD candidate Giorgos Gkikas, supervised by Prof. A. Paipetis.
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Barkoula, NM. (2013). Environmental Degradation of Carbon Nanotube Hybrid Aerospace Composites. In: Paipetis, A., Kostopoulos, V. (eds) Carbon Nanotube Enhanced Aerospace Composite Materials. Solid Mechanics and Its Applications, vol 188. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4246-8_9
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