Abstract
Nanotechnology is based on the fact that very small structures usually have new properties and behavior that are not observed in bulk matter of the same composition. Carbon nanotubes are one of the most striking nanometric structures. Their properties depend upon diameter and chirality. Carbon nanotubes have high length to radius ratio, high degree of mechanical strength and flexibility. Carbon nanotubes can behave like metallic, semi-conducting or insulating material. Carbon nanotubes have attracted major attention in latest applications such as nanodevices, field emission, gas adsorption, composite reinforcement, metal composites, and as a catalyst supports because they possess exceptional mechanical properties, unique electrical properties, high chemical and thermal stability and a large specific surface area. The properties of carbon nanotubes can be altered by encapsulating metals to make electrical or magnetic nanocables structures. Carbon nanotubes may therefore be suitable for sorbing hydrogen or separating gases and also can be used as energy storage, membranes for gaseous adsorption and sensors for environmental application. This review discusses the main concepts behind the role of carbon nanotubes for the special application in the field of environmental protection. The major points which are discussed in this review are:
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Introduction to carbon nanotubes: in this section we discuss the main synthesis routes of nanotubes and their properties
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Use of carbon nanotubes for energy storage: hydrogen storage is considered to be an ideal for its clean and abundantly reserved. Storage and transportation of hydrogen is an important challenge which has been focused on the use of carbon nanotubes.
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Use of carbon nanotubes as a sorbents: carbon nanotubes are thought to be very good sorbent for various toxic gases, dioxins, and volatile organic compounds.
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Use of carbon nanotubes as sensors: carbon nanotubes are thought to be promising candidate for nano scale sensing material for the detection of various pollutants in air like volatile organic compounds such as benzene and toluene.
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References
Avouris Ph (2002) Molecular electronics with carbon nanotubes. Acc Chem Res 35:1026–1034
Baughman RH, Cui C, Zakhidov AA, Iqbal Z, Barisci JN, Spink GM, Wallace GG, Mazzoldi A, De Rossi D, Rinzler AG, Jaschinski O, Roth S, Kertesez M (1999) Carbon nanotubes actuators. Science 284:1340–1344
Bekyarova E, Davis M, Burch T, Itkis ME, Zhao B, Sunshine S, Haddon RC (2004) Chemically functionalized single walled carbon nanotubes as ammonia sensors. J Phys Chem B 108(51):19717–19720
Boul PJ, Liu J, Mickelson ET, Huffman CB, Ericson LM, Chiang IW, Smith KA, Colbert DT, Hauge RH, Margrave JL, Smalley RE (1999) Reversible sidewall functionalization of bucky tubes. Chem Phys Lett 310(3–4):367–372
Bower C, Kleinhammes A, Wu Y, Zhou O (1998) Intercalation and partial exfoliation of single walled carbon nanotubes by nitric acid. Chem Phys Lett 288(2–4):481–486
Bower C, Zhou O, Zhu W, Werder DJ, Jin S (2000) Nucleation and growth of carbon nanotubes by microwave plasma chemical vapor deposition. Appl Phys Lett 77:2767–2769
Cai Y, Cai Y, Mou S, Lu Y (2005) Multiwalled carbon nanotubes as a solid phase extraction adsorbent for the determination of chlorophenols in environmental water samples. J Chromatogr A 1081(2):245–247
Cantalini C, Valentini L, Lozzi L, Armentano I, Kenny JM, Santucci S (2003) NO2 gas sensitivity of carbon nanotubes obtained by plasma enhanced chemical vapor deposition. Sens Actuators B 93:333–337
Cao DP, Zhang XR, Chen JF, Wang WC, Yun J (2003) Optimization of single walled carbon nanotubes arrays for methane storage at room temperature. J Phys Chem B 107(48):13286–13292
Chen P et al (1999) Science 285:91
Chen HW, Wu RJ, Chan KH, Sun YL, Su PG (2005) The application of carbon nanotubes/nafion composite material to low humidity sensing measurement. Sens Actuators B 104:80–84
Chiang IW, Brinson BE, Smalley RE, Margrave JL, Hauge RH (2001) purification and characterization of single walled carbon nanotubes. J Phys Chem B 105(6):1157–1161
Chopra S, Mc Gurie K, Gothard N, Rao AM, Pham A (2003a) Selective gas detection using a carbon nanotubes sensor. Appl Phys Lett 83:2280–2282
Chopra S, McGuire K, Gothard N, Rao AM, Pham A (2003b) Appl Phys Lett 83:2280
Collins PG, Zettl A, Bando H, Thess A, Smalley RE (1997) Nanotube nanodevice. Science 278:100–103
Collins PG, Bradley K, Ishigami M, Zettl A (2000) Extreme oxygen sensitivity of electronic properties of carbon nanotubes. Science 287(5459):1801–1804
Dai H (2002) Carbon nanotubes synthesis, integration and properties. Acc Chem Res 35:1035–1044
Dillion AC, Jones KM, Bekkedahl TA, Kiang CH, Bethune DS, Heben MJ (1997) Storage of hydrogen in single walled carbon nanotubes. Nature 386(6623):377–379
Dionysiou D (2004) Environmental applications and implications of nanotechnology and nanomaterials. J Environ Eng 38(3):723–724
Dresselhaus MS, Dresselhaus G, Avouris Ph (2001) Carbon nanotubes: synthesis, structure, properties and applications topics in applied physics, vol 80. Springer, Berlin
Forster PM, Eckert J, Chang JS, Park SE, Ferey G, Cheetham AK (2003) Hydrogen adsorption in nanoporous nickel (II) phosphates. J Am Chem Soc 125(5):1309–1312
Goldoni A, Larciprete R, Petaccia L, Lizzit S (2003) Single-wall carbon nanotube interaction with gases: sample contaminants and environmental monitoring. J Am Chem Soc 125(37):11329–11333
Gordillo MC, Marti J (2001) Hydrogen bonding in supercritical water confined in carbon nanotubes. Chem Phys Lett 341(3–4):250–254
Hafner JH, Cheung CL, Woolley AT, Lieber CM (2001) Structural and functional imaging with carbon nanotubes AFM probes. Prog Biophys Mol Biol 77(1):73–110
Halicioglu T, Jaffe RL (1999) Solvent effect on functional groups attached to edges of carbon nanotubes. Nano Lett 2(6):367–372
Hernadi K, Siska A, Thien-Nga L, Forro L, Kiricsi I (2001) Reactivity of different kinds of carbon during oxidative purification of catalytically prepared carbon nanotubes. Solid State Ionics 141:203–209
Huang WZ, Zhang XB, Kong FZ, Tu JP, Ma JX, Chen CP, Ning YS, Sun YL (2002) Hydrogen storage capacity of potassium – doped multiwalled carbon nanotubes. Chin J Chem Phys 15(1):51–55
Hynek S, Fuller W, Bentley J (1997) Hydrogen storage by carbon sorption. Int J Hydrog Energy 22(6):601–610
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354(6348):56
Jin YX, Liu ZJ, Chen WX, Xu ZD (2002) Hydrogenation of chlorophyll over carbon nanotubes – supported nickel catalyst at normal temperature and pressure. Acta Phys Chim Sin 18(5):459–462
Kong J, Franklin NR, Zhou C, Chapline MG, Peng S, Cho K, Dai H (2000) Nanotubes molecular wires as chemical sensors. Science 287:622–625
Kuzmany H, Kukovecz A, Simon F, Holzweber A, Kramberger C, Pichler T (2004) Functionalization of carbon nanotubes. Synth Met 141(91–2):113–122
Kuznetsova A, Popova I, Yates JT, Bronikowski MJ, Huffman CB, Liu J, Smalley RE, Hwu HH, Chen JGG (2001) Oxygen – containing functional groups on single walled carbon nanotubes: NEXAFS and vibrational spectroscopic studies. J Am Chem Soc 123(43):10699–10704
Li YH, Wang SG, Wei JQ, Zhang XF, Xu CL, Luan ZK, Wu DH, Wei BQ (2002) Lead adsorption on carbon nanotubes. Chem Phys Lett 357(3–4):263–266
Li YH, Wang SG, Luan ZK, Ding J, Xu CL, Wu DH (2003a) Adsorption of cadmium (II) from aqueous solution by surface oxidized carbon nanotubes. Carbon 41(5):1057–1062
Li J, Lu Y, Ye Q, Cinke M, Han J, Meyyappan M (2003b) Carbon nanotubes sensors for gas and vapor detection. Nano Lett 3(7):929–933
Li QL, Yuan DX, Lin QM (2004) Evaluation of multiwalled carbon nanotubes as an adsorbent for trapping volatile organic compounds from environmental samples. J Chromatogr A 1026(1–2):283–288
Liu CG, Liu M, Wang MZ, Cheng HM (2002) Research and development of carbon materials for electrochemical capacitors – II – the carbon electrode. New Carbon Mater 17(2):64–72
Long RQ, Yang RT (2001) carbon nanotubes as superior sorbent for dioxin removal. J Am Chem Soc 123(9):2058–2059
Masciangioli T, Zhang WX (2003) Environmental technologies at the nanoscale. Environ Sci Technol 37(5):102A–108A
Nguyen CV, Dezeit L, Cassell AM, Li J, Han J, Meyyappan M (2002) Preparation of nucleic acid functionalized carbon nanotubes arrays. Nano Lett 2(10):1079–1081
Nikolaev P, Bronikowski MJ, Bradley RK, Fohmund F, Colbert DT, Smith KA, Smalley RE (1999) Gas phase catalytic growth of single walled carbon nanotubes from carbon monoxide. Chem Phys Lett 313:91–97
Novak JP, Snow ES, Houser EJ, Park D, Stepnowski JL, McGill RA (2003) Nerve agent detection using networks of single-walled carbon nanotubes. Appl Phys Lett 83:4026
Odom TW, Huang JL, Kim P, Lieber CM (2000) Structure and electronic properties of carbon nanotubes. J Phys Chem B 104(13):2794–2809
Ong KG, Zeng K, Grimes CA (2002) A wireless passive carbon nanotubes based gas sensors. IEEE Sens J 2:82–88
Peng XJ, Li YH, Luan ZK, Di ZC, Wang HY, Tian BH, Jia ZP (2003) Adsorption of 1,2-dichlorobenzene from water to carbon nanotubes. Chem Phys Lett 376(1–2):154–158
Penza M, Cassano G, Aversa P, Antolini F, Cusano A, Cutolo A, Giordano M, Nicolais L (2004a) Alcohol detection using carbon nanotubes acoustic and optical sensors. Appl Phys Lett 85(12):2379–2381
Penza M, Antolini F, Vittori-Antisari M (2004b) Carbon nanotubes as SAW chemical sensors materials. Sens Actuators B 100(1–2):47–59
Penza M, Antolini F, Antisari MV (2004c) Sens Actuators B 100:47
Penza M, Cassano G, Aversa P, Cusano A, Cutolo A, Giordano M, Nicolais L (2005a) Carbon nanotubes acoustic and optical sensors for volatile organic compounds detection. Nanotechnology 16:2536–2547
Penza M, Cassano G, Aversa P, Antolini F, Cusano A, Cutolo A, Giordano M, Nicolais L (2005b) Carbon nanotubes-coated multi-transducing sensors for VOCs detection. Sens Actuators B 111–112:171–180
Qi P, Vermesh O, Grecu M, Javey A, Wang Q, Dai H, Peng S, Cho KJ (2003) Toward large arrays of multiplex functionalized carbon nanotubes sensors for highly sensitive and selective molecular detection. Nano Lett 3(3):347–351
Rodriguez-Mozaz S, Marco MP, Lopez de Alda MJ, Barcelo D (2004) Biosensors for environmental applications: Future development trends. Pure Appl Chem 76:723
Saito R, Dresselhaus G, Dresselhaus MS (1998) Properties of carbon nanotubes. Imperial Collage Press, Singapore
Shi Z, Lian Y, Liao FH, Zhou X, Gu Z, Zhang Y et al (2000) Large scale synthesis of single wall carbon nanotubes by arc discharge method. J Phys Chem Solids 61:1031–1036
Simonyan VV, Johnson JK (2002) Hydrogen storage in carbon nanotubes and graphitic nano fibers. J Alloys Compd 330:659–665
Someya T, Small J, Kim P, Nuckolls C, Yardley JT (2003) Alcohol vapor sensors based on single walled carbon nanotubes field effect transistors. Nano Lett 3(7):877–881
Suehiro J, Zhou GB, Hara M (2003) Fabrication of a carbon nanotube- based gas sensor using dielectrophoresis and its application for ammonia detection by impedance spectroscopy. J Phys D Appl Phys 36(21):L109–L114
Sumanasekera GU, Pradhan BK, Adu CKW, Romero HE, Foley HC, Eklund PC (2002) Thermoelectric chemical sensor based on single wall carbon nanotubes. Mol Cryst Liq Cryst Sci Technol Sect A 387:31
Sun YP, Huang WJ, Lin Y, Fu KF, Kitaygorodskiy A, Riddle LA, Yu YJ, Carroll DL (2001) Soluble dendron – functionalized carbon nanotubes: preparation, characterization and properties. Chem Mater 13(9):2864–2869
Tanaka H, EI-Merraoui M, Steele WA, Kaneko K (2002) Methane adsorption on single walled carbon nanotubes: a density functional theory model. Chem Phys Lett 352(5–6):334–341
Thostenson ET, Ren Z, Chou TS (2001) Advances in the science and technology of carbon nanotubes and their composites: a review. Compos Sci Technol 61:1899–1912
Valentini L, Armentano I, Kenny JM, Cantalini C, Lozzi L, Santucci S (2003) Sensors for sub ppm NO2 gas detection based on carbon nanotubes thin films. Appl Phys Lett 82:961–963
Valentini L, Armentano I, Lozzi L, Santucci S, Kenny JM (2004) Interaction of methane with carbon nanotubes thin films: role of defects and oxygen adsorption. Mater Sci Eng C Biomim Supramol Syst 24(4):527–533
Varghese OK, Kichambre PD, Gong D, Ong KG, Dickey EC, Grime CA (2001a) Gas sensing characteristics of multiwalled carbon nanotubes. Sens Actuators B 81:32–41
Varghese OK, Kichambre PD, Gong D, Ong KG, Dickey EC, Grimes CA (2001b) Gas sensing characteristics of multiwalled carbon nanotubes. Sens Actuators B 81:32–41
Villalpando-Paez F, Romero AH, Munoz-Sandoval E, Martinez LM, Terrones H, Terrones M (2004) Fabrication of vapor and gas sensors using films of aligned CNx nanotubes. Chem Phys Lett 386(1–3):137–143
Wei BY, Hsu MC, Yang YS, Chien SH, Lin HM (2003) Gas adsorption on single walled carbon nanotubes measured by piezoelectric quartz crystal microbalance. Mater Chem Phys 81:126–133
Wong SS, Joselevich E, Woolley AT, Cheung CL, Lieber CM (1998) Covalently functionalized nanotubes as nanometer – sized probes in chemistry and biology. Nature 394(6688):52–55
Wong YM, Kang WP, Davidson JL, Wisitsora A, Soh KL (2003) A novel microelectronic gas sensor utilizing carbon nanotubes for hydrogen gas detection. Sens Actuators B 93:327–332
www.pa.msu.edu/cmp/csc/ntproperties/equilibriumstructure.html, 2004
Yang Y, Huang S, He H, Mau AWH, Dai L (1999) Patterned growth of well – aligned carbon nanotubes: a photolithographic approach. J Am Chem Soc 121:10832–10833
Yang CM, Kanoh H, Kaneko K, Yudasaka M, Iijima S (2002a) Adsorption behaviors of HiPco single walled carbon nanotubes aggregates for alcohol vapors. J Phys Chem B 106:8994–8999
Yang YL, Zhang J, Nan XL, Liu ZF (2002b) Studies on the dissociation behaviour of carboxylic groups at the open end of single – walled carbon nanotubes by tip chemistry. Chem J Chin Univ Chin 23(3):469–471
Yang CM, Kaneko K, Yudasaka M, Iijima S (2002c) Effect of purification on pore structure of HiPco single – walled carbon nanotubes aggregates. Nano Lett 2(4):385–388
Zhang Y, Iijima S (1999) Formation of single wall carbon nanotubes by laser ablation of fullerenes at low temperatures. Appl Phys Lett 75:3087–3089
Zhang J, Zou HL, Qing Q, Yang YL, Li QW, Liu ZF, Guo XY, Du ZL (2003) Effect of chemical oxidation on the structure of single – walled carbon nanotubes. J Phys Chem B 107(16):3712–3718
Zhao JJ, Park HK, Han J, Lu JP (2004) Electronic properties of carbon nanotubes with covalent sidewall functionalization. J Phys Chem B 108(14):4227–4230
Zhu HW, Li XS, Chi LJ, Xu CL, Wu DH, Mao ZQ (2003) Hydrogen storage in heat treated carbon nanofibers prepared by the vertical floating catalyst method. Mater Chem Phys 78(3):670–675
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Authors are thankful to Dr Vikram Kumar Director CRRI/NPL, New Delhi for giving the permission for the publication of this article. Authors are also thankful to Dr Pawan Kapoor, Director, CSIO, Chandigarh for his constant encouragement and suggestions for this manuscript.
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Chauhan, S.K., Shukla, A., Dutta, S., Gangopadhyay, S., Bharadwaj, L.M. (2012). Carbon Nanotubes for Environmental Protection. In: Lichtfouse, E., Schwarzbauer, J., Robert, D. (eds) Environmental Chemistry for a Sustainable World. Environmental Chemistry for a Sustainable World. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-2442-6_3
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