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Special Features and Regularities of Interaction Between Fullerene Molecules and Aromatic Solvents

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Carbon Nanomaterials in Clean Energy Hydrogen Systems - II

Part of the book series: NATO Science for Peace and Security Series C: Environmental Security ((NAPSC,volume 2))

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Abstract

The reaction of C60 fullerene dissolution in monosubstituted benzenes has been studied. The correlation method of physical properties of solvent molecules with reaction characteristics has been applied under the assumption of their donor-acceptor mechanism. The effect of electron-donor substituents of aromatic ring has been found.

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Abbreviations

QSPR:

quantitative structure-property relationship

QSAR:

quantitative structure activity relationship

HOMO:

high occupied molecular orbital

LFMO:

lower free molecular orbital

LCM:

liquid-crystal media

DAC:

donor-acceptor complex

DAI:

donor-acceptor interaction

CCT:

complex with charge transfer

HB:

hydrogen bond

Cs :

concentration of solvent

CCCT :

concentration of CCT

\( {S_{{{C_{{60}}}}}} \) :

solubility of C60

μHB :

dipole moment of halogen benzene

MHB :

mesomeric effect of halogen benzene

μFB :

dipole moment of fluorine benzene

HC:

hyperconjugation

ϕAB :

ionization potential of alkyl benzene

χ:

electronegativity

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Authors and Affiliations

  1. Institute for Problems of Materials Science of NAS of Ukraine, Krzhyzhanovsky str. 3, 03142, Kiev, Ukraine

    N. S. Anikina, O. Ya. Krivuschenko, D. V. Schur, S. Yu. Zaginaichenko & E. A. Kamenetskaia

Authors
  1. N. S. Anikina
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  2. O. Ya. Krivuschenko
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  3. D. V. Schur
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  4. S. Yu. Zaginaichenko
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  5. E. A. Kamenetskaia
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Corresponding author

Correspondence to N. S. Anikina .

Editor information

Editors and Affiliations

  1. , Institute of Hydrogen and Solar Energy, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03150, Ukraine

    Svetlana Yu. Zaginaichenko

  2. , Inst. for Problems of Materials Science, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03150, Ukraine

    Dmitry V. Schur

  3. , Inst. for Problems of Materials Science, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03142, Ukraine

    Valeriy V. Skorokhod

  4. International Association for Hydrogen E, University of Miami, 5794 SW 40 St. # 303, Miami, 33155, Florida, USA

    Ayfer Veziroglu

  5. , Department of Mechanical Engineering, Gazi University, Yukselis Street 5, Ankara, Turkey

    Beycan İbrahimoğlu

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Anikina, N.S., Krivuschenko, O.Y., Schur, D.V., Zaginaichenko, S.Y., Kamenetskaia, E.A. (2011). Special Features and Regularities of Interaction Between Fullerene Molecules and Aromatic Solvents. In: Zaginaichenko, S., Schur, D., Skorokhod, V., Veziroglu, A., İbrahimoğlu, B. (eds) Carbon Nanomaterials in Clean Energy Hydrogen Systems - II. NATO Science for Peace and Security Series C: Environmental Security, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0899-0_4

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