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Problems of Development of Hydrogen Power Engineering

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Carbon Nanomaterials in Clean Energy Hydrogen Systems - II

Part of the book series: NATO Science for Peace and Security Series C: Environmental Security ((NAPSC,volume 2))

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Abstract

The kinetics and mechanism of the interaction of aluminium and magnesium of the ternary system Al-Mg-Bi with water have been studied by high-temperature volumetry. The kinetic parameters of the reaction (rate constants, activation energies and degrees of transformation) have been calculated, and a mechanism of corrosion dissolution of bismuth-activated aluminium and magnesium in water with hydrogen evolution at a high rate is proposed. Kinetic parameters in the case of interaction between bismuth- and magnesium-activated aluminium and water, involving transformation of aluminium and magnesium into boehmite (AlOOH) and magnesium into hydroxide (Mg(OH)2) with hydrogen evolution at a rate of 3,196–4,033 l/(m2·min) in the temperature range in question have been determined. Micro- and nanostructured particles of Al-Mg-Bi alloys have been detected with the aid of a JSM 6490 LV electron microscope (Japan).

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Author information

Authors and Affiliations

  1. V.I. Vernadskii Institute of General and Inorganic Chemistry of NAS of Ukraine, Palladin av. 32/34, 03680, Kyiv-142, Ukraine

    L. F. Kozin, S. V. Volkov, S. G. Goncharenko & B. I. Daniltsev

Authors
  1. L. F. Kozin
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  2. S. V. Volkov
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  3. S. G. Goncharenko
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  4. B. I. Daniltsev
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Corresponding author

Correspondence to L. F. Kozin .

Editor information

Editors and Affiliations

  1. , Institute of Hydrogen and Solar Energy, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03150, Ukraine

    Svetlana Yu. Zaginaichenko

  2. , Inst. for Problems of Materials Science, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03150, Ukraine

    Dmitry V. Schur

  3. , Inst. for Problems of Materials Science, Ukrainian Academy of Sciences, Krzhyzhanovsky str. 3, Kiev, 03142, Ukraine

    Valeriy V. Skorokhod

  4. International Association for Hydrogen E, University of Miami, 5794 SW 40 St. # 303, Miami, 33155, Florida, USA

    Ayfer Veziroglu

  5. , Department of Mechanical Engineering, Gazi University, Yukselis Street 5, Ankara, Turkey

    Beycan İbrahimoğlu

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Kozin, L.F., Volkov, S.V., Goncharenko, S.G., Daniltsev, B.I. (2011). Problems of Development of Hydrogen Power Engineering. In: Zaginaichenko, S., Schur, D., Skorokhod, V., Veziroglu, A., İbrahimoğlu, B. (eds) Carbon Nanomaterials in Clean Energy Hydrogen Systems - II. NATO Science for Peace and Security Series C: Environmental Security, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0899-0_1

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