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Dissolved Organic Carbon as an Indicator Parameter for Groundwater Flow and Transport

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Riverbank Filtration for Water Security in Desert Countries

Abstract

The bulk parameter dissolved organic carbon (DOC) is often successfully exploited in the context of investigations into the collective behavior of dissolved organics contained in water. Though being an unspecific parameter, increased DOC concentrations can indicate anthropogenic influences (such as bank filtration or artificial recharge) on groundwater quality. To this end, DOC as an organic surrogate parameter was investigated for its potential to indicate and characterize such influences. The advantages of using DOC as an indicator parameter are the low time and cost investments required for analysis of DOC concentrations but also the fact that DOC reflects the collective behavior of the dissolved organics contained in water. Existing models for DOC characterization are limited to the identification of one or two compound groups with different degradability. Based on first order degradation kinetics, a multi-component approach is mathematically derived. The approach is demonstrated for the example of four compound groups that are (i) easily, (ii) moderately, (iii) poorly and (iv) under the given conditions not degradable as a function of time scale and flow path length. By means of the conceptual model, a decision tool is given for finding the necessary contact time as a function of hydraulic conditions and flow path length, such as in the case of bank filtration or groundwater recharge site design, as well as in finding the required distance between infiltration areas and points of interest. The discussion of contact time and time scales is a step towards a comparable interpretation of laboratory and field conditions in terms of biodegradation rate constants for DOC as well as for single organic compounds.

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References

  • Alexander M (1991) Introduction to soil microbiology. Krieger, Malabar

    Google Scholar 

  • Arnold RG, Quanrud DM, Wilson LG et al (1996) The fate of residual wastewater organics during soil aquifer treatment. Proceedings American Water Works Association Water Reuse ‘96, San Diego, CA:505–530

    Google Scholar 

  • Bockelmann A, Ptak TH, Teutsch G (2001) An analytical quantification of mass fluxes and natural attenuation rate constants at a former gasworks site. J Contam Hydrol 53:429–453

    Article  Google Scholar 

  • Boggs JM, Beard LM, Waldrop WR et al (1993) Transport of tritium and four organic compounds during a natural-gradient experiment (MADE-2). EPRI TR-101998. Research Project 2485-05. TVA Eng. Lab., Norris. Tennessee

    Google Scholar 

  • Brauner JS, Widdowson MA (2001) Numerical simulation of a natural attenuation experiment with a petroleum hydrocarbon NAPL Source. Ground Water 39(6):939–952

    Article  Google Scholar 

  • Drewes JE, Fox P (1999a) Behavior and characterization of residual organic compounds in wastewater used for indirect potable reuse. Water Sci Technol 40(4–5):391–398

    Google Scholar 

  • Drewes JE, Fox P (1999b) Fate of natural organic matter (NOM) during groundwater recharge using reclaimed water. Water Sci Technol 40(9):241–248

    Article  Google Scholar 

  • Drewes JE, Jekel M (1998) Behavior of DOC and AOX using advanced treated wastewater for groundwater re-charge. Water Res 32(10):3125–3133

    Article  Google Scholar 

  • Drewes JE, Summers RS (2002) Natural organic matter removal during riverbank filtration: Current knowledge and research needs. In: Ray C, Melin G, Linsky RB (eds) Riverbank filtration: Improving source-water quality. Kluwer, Dordrecht, The Netherlands:303–309

    Google Scholar 

  • Gimbel R, Mälzer H-J (1987) Testfilter experiments to evaluate drinking water relevance of organic compounds in running waters (in German). Vom Wasser 69:139–153

    Google Scholar 

  • Gimbel R, Gerlach M, Mälzer H-J (1992) A testfilter method for the simulation of pollutant transport in the subsurface (in German). In: Erfassung und Bewertung von Xenobiotika aus der Sicht der Trinkwasserversorgung. Institute for water chemistry and water technology, University Duisburg 6:126–162

    Google Scholar 

  • Grischek T, Schoenheinz D, Worch E, Hiscock K (2002) Bank filtration in Europe – an overview of aquifer conditions and hydraulic controls. In: Dillon PJ (ed) Management of aquifer recharge for sustainability. A.A. Balkema Publ., Sweets & Zeitlinger, Lisse:485–488

    Google Scholar 

  • Grischek T (2003) Management of bank filtration sites along the Elbe River. PhD thesis, Faculty of Forestry, Geo and Hydro Sciences, Dresden University of Technology

    Google Scholar 

  • Grischek T, Nestler W (1998) Behaviour of DOC during bank filtration (in German). University of Applied Sciences, Research report 6, 02WT9454/0

    Google Scholar 

  • Hazen TC, Jiménez L, de Victoria GL, Fliermans CB (1991) Comparison of bacteria from deep subsurface sediment and adjacent groundwater. Microb Ecol 22:293–304

    Article  Google Scholar 

  • Helmisaari H-S, Derome J, Hatva T et al (2006) Artificial recharge in Finland through basin and sprinkling infiltration: Soil processes, retention time and water quality. UNESCO IHP-VI, Series on Groundwater 13:280–285

    Google Scholar 

  • Hobby R, Gimbel R (1988) Results from testfilter experiments with sewage water of municipalities and pulp and paper mills (in German). DVGW-Schriftenreihe Wasser 60:117–151

    Google Scholar 

  • Jurado-Exposito M, Walker A (1989) Degradation of isoproturon, propyzamide and alachlor in soil with constant and variable incubation conditions. Weed Res 38:309–318

    Article  Google Scholar 

  • Kaplan LA, Newbold JD (2000) Surface and subsurface dissolved organic carbon. In: Jones JB, Mulholland PJ (eds) Streams and ground waters. Academic Press,San Diego:237–248

    Chapter  Google Scholar 

  • Kolehmainen RE, Langwaldt JH, Puhakka JA (2007) Natural organic matter (NOM) removal and structural changes in the bacterial community during artificial groundwater recharge with humic lake water. Water Res 41:2715–2725

    Article  Google Scholar 

  • Kölle W (2003) Water analyses – correct evaluation (in German). Wiley, VCH Weinheim

    Google Scholar 

  • Krüger CJ, Radakovich KM, Sawyer TE et al (1998) Biodegradation of the surfactant linear Alkylbenzenesulfonate in sewage-contaminated groundwater: A comparison of column experiments and field tracer tests. Environ Sci Technol 32(24):3954–3961

    Article  Google Scholar 

  • Lehtola M, Miettinen I, Vartiainen T et al (1996) Changes in microbiology and water chemistry during slow sand filtration. Proceedings of International Symposium on “Artificial Recharge of Groundwater,” NHP Report 38:197–202

    Google Scholar 

  • Lindroos A-J, Kitunen V, Derome J, Helmisaari H-S (2002) Changes in dissolved organic carbon during artificial recharge of groundwater in a forested esker in Southern Finland. Water Res 36:4951–4958

    Article  Google Scholar 

  • Mälzer H-J (1993) Investigation into transport and degradation processes during bank filtration considering effects of shock loads (in German). PhD thesis, Faculty of Engineering, University Duisburg

    Google Scholar 

  • Mälzer H-J, Gerlach M, Gimbel R (1992) Development of testfilters to simulate shock loads for bank filtration (in German). Vom Wasser 78:343–353

    Google Scholar 

  • Maeng SK, Sharma SK, Magic-Knezev A, Amy G (2008) Fate of effluent organic matter (EfOM) and natural organic matter (NOM) through riverbank filtration. Water Sci Technol 75(12):1999–2007

    Google Scholar 

  • Matthess G (1994) The quality of groundwater (in German). Gebr. Borntraeger, Berlin, Stuttgart

    Google Scholar 

  • Momba MNB, Kfir R, Venter SN, Cloete TE (2000) An overview on biofilm formation in distribution systems and its impact on the deterioration of water quality. Water SA 26(1):59–66

    Google Scholar 

  • Nestler W, Walther W, Jacobs F, Trettin R, Freyer K (1998) Water production in alluvial aquifers in the Elbe river catchment (in German). UFZ Research report 7, Leipzig

    Google Scholar 

  • Palmisano AC, Schwab BS, Maruscik DA (1991) Seasonal changes in mineralization of xenobiotics by stream microbial communities. Can J Microbiol 37(12):939–948

    Article  Google Scholar 

  • Preuß G, Nehrkorn A (1996) Succession of microbial communities during bank filtration and artificial groundwater recharge. Proceedings of International Symposium on “Artificial Recharge of Groundwater,” NHP Report 38:215–221

    Google Scholar 

  • Quanrud DM, Arnold RG, Wilson LG et al (1996) Fate of organics during column studies of soil aquifer treatment. J Environ Eng 122(4):314–321

    Article  Google Scholar 

  • Rauch T, Drewes JE (2005) Quantifying biological organic carbon removal in groundwater recharge systems. J Environ Eng 131(6)909–923

    Google Scholar 

  • Sacher F, Brauch HJ, Kühn W (2000) Fate studies of hydrophilic organic micro-pollutants in riverbank filtration. In: Jülich W, Schubert J (eds) Proceedings of the International Riverbank Filtration Conference. IAWR:139–148

    Google Scholar 

  • Schoenheinz D, Grischek T, Worch E et al (2002) Groundwater pollution near the pulp and paper mill Sjasstroj at Lake Ladoga, Russia. In: Hiscock KM, Davison RM, Rivett MO (eds) Sustainable groundwater development. Geological Society Special Publ 193, London:277–291

    Google Scholar 

  • Schoenheinz D (2004) DOC as control parameter for the evaluation and management of aquifers with anthropogenic influenced infiltration. PhD thesis, Faculty of Forestry, Geo and Hydro Sciences, Dresden University of Technology

    Google Scholar 

  • Schoenheinz D, Grischek T (2010) Behavior of dissolved organic carbon (DOC) during bank filtration under extreme climate conditions. In: Ray C, Shamrukh M (eds) Riverbank filtration for water security in desert countries. Springer, Dordrecht, The Netherlands

    Google Scholar 

  • Sontheimer H (1991) Drinking water from river Rhine? (in German) Academia Verlag Sankt Augustin

    Google Scholar 

  • Sontheimer H, Völker E (1987) Characterisation of waste water discharges considering drinking water supply (in German). University of Technology Karlsruhe 31

    Google Scholar 

  • Suarez MP, Rifai, HS (1999) Biodegradation rates for fuel hydrocarbons and chlorinated solvents in groundwater. Biorem J 3(4):337–362

    Article  Google Scholar 

  • Veeh RH, Inskeep WP, Camper AK (1996) Soil depth and temperature effects on microbial degradation of 2,4-D. J Environ Qual 25(1):5–12

    Article  Google Scholar 

  • Wesnigk JB, Keskin M, Jonas W, Figge K, Rheinheimer G (2001) Predictability of biodegradation on the environment: Limits of prediction from experimental data. In: Beek B (ed) Biodegradation and persistence. Springer Verlag, Berlin

    Google Scholar 

Download references

Acknowledgments

The author thanks Wolfgang Nestler, Jörg E. Drewes, Thomas Grischek, Hilmar Börnick, and Eckhard Worch for their continuous discussions, significant comments and ongoing support in developing the demonstrated concept.

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Correspondence to Dagmar Schoenheinz .

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Schoenheinz, D. (2011). Dissolved Organic Carbon as an Indicator Parameter for Groundwater Flow and Transport. In: Shamrukh, M. (eds) Riverbank Filtration for Water Security in Desert Countries. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0026-0_10

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