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Synthesis of Functionalized Mesoporous Silicas, Structure of Their Surface Layer and Sorption Properties

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Nanomaterials and Supramolecular Structures

Abstract

The routes of synthesis of polysiloxane xerogels functionalized by nitrogen-, oxygen-, phosphorus- and sulphur content ligand groups were investigated. Applying a number of physical methods (SEM, TEM, AFM, IR and Raman spectroscopy, 1H, 13C, 29Si and 31P CP/MAS NMR spectroscopy, EPR spectroscopy, ERS and thermal analysis) the structure of xerogels and their surface was established. The influence of some factors on the structural-adsorption characteristics of such xerogels and their sorption properties were analysed.

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Acknowledgements

The author would like to acknowledge the partial financial support of NATO (Grant SfP–978006) and the Ministry of Education and Science of Ukraine for this work.

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  1. O.O. Chuiko Institute of Surface Chemistry of the National Academy of Sciences of Ukraine, General Naumov St. 17, 03164, Kyiv, Ukraine

    Yuriy L. Zub

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Correspondence to Yuriy L. Zub .

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  1. G.V. Kurdiumov Inst. Metal Physics, National Academy of Sciences of Ukraine, Blvd. Akademika Vernadskogo 36, Kiev, 03680, Ukraine

    Anatoliy Petrovych Shpak

  2. A. A. Chuiko Inst. Surface Chemistry, National Academy of Sciences of Ukraine, General Naumov St. 17, Kiev, 03164, Ukraine

    Petr Petrovych Gorbyk

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Zub, Y.L. (2009). Synthesis of Functionalized Mesoporous Silicas, Structure of Their Surface Layer and Sorption Properties. In: Shpak, A., Gorbyk, P. (eds) Nanomaterials and Supramolecular Structures. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2309-4_14

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