Abstract
A synthesis technique of magnetosensitive nanocomposites was proposed on the basis of nanocrystalline magnetite (Fe3O4) or maghemite (γ-Fe2O3) and highly disperse silica. Thermogravimetry, differential thermal analysis, XRD, and a vibrating magnetometer were used to characterize prepared nanocomposites. It was found that nanosilica prevents growth of Fe3O4 nanocrystallites stabilized at average sizes of 5–8 nm.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Gorbyk PP, Petranovskaya AL, Storozhuk LP et al (2006) Medico-biological nanocomposites based on magnetite: synthesis, modification, surface functionalization for application in vitro. Chem Phys Technol Surf 11–12:374–396
Duguet E, Vasseur S, Mornet S (2006) Magnetic nanoparticles and their applications in medicine. Nanomedicine 1:157–168
Mornet S, Vasseur S, Grasset F (2006) Magnetic nanoparticle design for medical applications. Prog Solid State Chem 34:237–247
Kotov EP, Rudenko MI (1990) Carriers for magnetic records. Radio i svyaz, Moscow
Kirschvink JL, Walker MM, Deibel C (2001) Magnetite-based magnetoreception. Curr Opin Neurobiol 11:462–467
Sun S, Zeng H, Robinson DB (2004) Monodispersed MFe2O4(M=Fe, Co, Mn) Nanoparticles. J Am Chem Soc 126:273–279
Vasilevsky YA (1989) Carriers for magnetic records. Iscusstvo, Moscow
Del Monte F, Morales MP, Levy D (1997) Formation of γ-Fe2O3 isolated nanoparticles in a silica matrix. Langmuir 13:3627–3624
Popovici M, Gich M, Savii C (2006) Ultra-light sol–gel derived magnetic nanostructured materials. Roman Rep Phys 58:369–378
Cannas C, Gatteschi D, Musinu A (1998) Structural and magnetic properties of Fe2O3 nanoparticles dispersed over a silica matrix. J Phys Chem B 102:7721–7726
Xu J, Thompson S, O’Keefe E (2004) Iron oxide-silica nanocomposites via sol–gel processing. J Mater Lett 58:1696–1700
Raileanu M, Crisan M, Petrache C (2005) Sol–gel FexOy nanocomposites. Roman J Phys 50:595–606
Cannas C, Concas G, Gatteschi D (2001) Superparamagnetic behaviour of γ-Fe2O3 nanoparticles dispersed in a silica matrix. Phys Chem Chem Phys 3:832–838
Battishaa IK, Afifya HH, Ibrahimb M (2006) Synthesis of Fe2O3 concentrations and sintering temperature on FTIR and magnetic susceptibility measured from 4 to 300 K of monolith silica gel prepared by sol–gel technique. J Magn Magn Mater 306:211–217
Bogatyrev VM, Gaeva MV, Chuiko AA (2006) IR spectral study of thermooxidation destruction of trimethylsilylated silica modified by acetylacetonate of Fe(III). Chem Phys Technol Surf 11–12:254–260
Sviridov VV (1987) Chemical precipitation of metals from aqueous solutions. Belarus, Minsk
Sviridov VV (1996) Inorganic synthesis. Belarus, Minsk
Oranska EI, Gornikov YI, Fesenko TV (1994) Automated method of determination of average sizes of crystallites of polycrystalline solids. Zavodsk Lab 60(1):28
Spak AP, Kunitsky YA, Zakharchenko MI, Voloschenko AS (2003) Magnetism of amorphous and nanocrystalline systems. Naukova Dumka, Kiev
Yang J, Ferreira JMF (1998) Inhibitory effect of the Al2O3–SiO2 mixed additives on the anatase–rutile phase transformation. Mater Lett 36:320–324
Gun’ko VM, Zarko VI, Turov VV et al (1998) CVD-titania on fumed silica substrate. J Colloid Interface Sci 198:141–156
Cannas C, Concas G, Gatteschi D et al (2002) How to tailor maghemite particle size in γ-Fe2O3–SiO2 nanocomposites. J Mater Chem 12:3141–3146
Gun’ko VM, Zarko VI, Leboda R et al (2001) Aqueous suspensions of fumed oxides: Particle size distribution and zeta potential. Adv Colloid Interface Sci 91:1–112
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2009 Springer Science+Business Media B.V.
About this chapter
Cite this chapter
Bogatyrov, V., Borysenko, M., Dubrovin, I., Abramov, M., Galaburda, M., Gorbyk, P. (2009). Synthesis and Properties of Magnetosensitive Nanocomposites Based on Iron Oxide Deposited on Fumed Silica. In: Shpak, A., Gorbyk, P. (eds) Nanomaterials and Supramolecular Structures. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2309-4_12
Download citation
DOI: https://doi.org/10.1007/978-90-481-2309-4_12
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-2308-7
Online ISBN: 978-90-481-2309-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)