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Nanoporous Silica Matrices and Their Application in Synthesis of Nanostructures

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Nanomaterials and Supramolecular Structures

Abstract

The effect of the presence of I-4 Me-Ph ionene in the supramolecular template (cetyltrimethylammonium bromide) on formation of porous structure of silicas was studied. We also studied the peculiarities of template synthesis of mesoporous silicas inside of large pores of silica gel. Mesoporous silicas with chemically modified surface were applied in synthesis of metallic nanostructures. Porous silicas with grafted layer of hydridepolysiloxane were used for in situ preparation of supported nanoparticles of gold and silver by reduction of metal ions from chloroauric acid and silver nitrate solutions, respectively. Nitrogen adsorption–desorption, X-ray powder diffraction analysis, scanning and transmission electron microscopies, IR-, UV–visible, and laser correlation spectroscopies were applied for characterization of adsorbents and nanostructures obtained.

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References

  1. Ciesla U, Schuth F (1999) Ordered mesoporous materials. Microporous Mesoporous Mater 27:131–149

    Article  CAS  Google Scholar 

  2. Corma A (1997) From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem Rev 97:2373–2419

    Article  CAS  Google Scholar 

  3. Grun M, Unger KK, Matsumoto A, Tsutsumi K (1999) Novel pathways for the preparation of mesoporous MCM-41 materials: control of porosity and morphology. Microporous Mesoporous Mater 27:207–216

    Article  CAS  Google Scholar 

  4. Zhu W, Han Y, An L (2005) Silver nanoparticles synthesized from mesoporous Ag/SBA-15 composites. Microporous Mesoporous Mater 80:221–226

    Article  CAS  Google Scholar 

  5. Katok KV, Tertykh VA, Brichka SYa, Prikhod’ko GP (2006) Catalytic synthesis of carbon nanotubes over ordered mesoporous matrices. J Therm Anal Calorim 86:109–114

    Article  CAS  Google Scholar 

  6. Muller R (1950) Uber Silicone (I). Zur angewadten Chemie der Silicone (Synthese). Chemische Technik 2:7–13

    CAS  Google Scholar 

  7. Wagner GH, Pines AN (1952) Silicon oxyhydride. Ind Eng Chem 44:321–326

    Article  CAS  Google Scholar 

  8. Budkevich GB, Slinyakova IB, Neimark IE (1966) Reductive properties of xerogel of hydridepolysiloxane. Kolloid Zh 28:21–25

    CAS  Google Scholar 

  9. Adeogun MJ, Hay JN (2001) Structure control in sol–gel silica synthesis using ionene polymers. 2. Evidence from spectroscopic analysis. J Sol–Gel Sci Technol 20: 119–128

    Article  CAS  Google Scholar 

  10. Adeogun MJ, Fairclough JPA., Hay JN, Ryan AJ (1998) Structure control in sol–gel silica synthesis using ionene polymers – evidence from X-ray scattering. J Sol–Gel Sci Technol 13:27–30

    Article  CAS  Google Scholar 

  11. Berezovska IS, Yanishpolskii VV, Tertykh VA, Lobunets TF, Ragulya AV  (2006) Template synthesis of porous silica adsorbents with spherical morphology of particles. Ads Sci Technol 24:403–410

    Article  CAS  Google Scholar 

  12. Berezovskaya IS, Yanishpolskii VV, Tertykh VA (2008) Morphology control of mesoporous silica and their template synthesis in silica gel. Russ J Phys Chem 82:1442–1446

    Article  CAS  Google Scholar 

  13. Tatsumi T, Koyano K, Tanaka Y, Nakata S (1999) Mechanical stability of mesoporous materials MCM-48 and MCM-41. J Porous Mater 6:13–17

    Article  CAS  Google Scholar 

  14. Williford RE, Li XS, Addeman RS, Fryxell GE, BAskaren S, Birnbaun JC, Coyle C, Zemanian TS, Wang G, Courtney AR (2005) Mechanical stability of templated mesoporous silica films. J Microporous Mesoporous Mater 85:260–266

    Article  CAS  Google Scholar 

  15. Wang X, Li W, Zhu G, Qiu S, Zhao D, Zhong B (2004) Effects of ammonia/silica molar ratio on the synthesis and structure of bimodal mesopore silica xerogel. Microporous Mesoporous Mater 71:87–97

    Article  CAS  Google Scholar 

  16. Gun’ko VM, Turov VV, Turov AV, Zarko VI, Gerda VI, Yanishpolskii VV, Berezovska IS, Tertykh VA (2007) Behavior of pure water and water mixture with benzene or chloroform adsorbed onto ordered mesoporous silicas. Cent Eur J Chem 5:420–454

    Article  Google Scholar 

  17. Tertykh VA (2004) Functionalization of silica surfaces. In: Schwarz JA., Contesku C, Putyera K (eds) Dekker Encyclopedia of Nanoscience and Nanotechnology, Marcel Dekker, New York

    Google Scholar 

  18. Cai H, Wang Y, He P, Fang Y (2002) Electrochemical detection of DNA hybridization based on silver-enhanced gold nanoparticle label. Anal Chim Acta 469:165–172

    Article  CAS  Google Scholar 

  19. Gong JL, Jiang JH, Liang Y, Shen GL, Yu RQ (2006) Synthesis and characterization of surface-enhanced Raman scattering tags with Ag/SiO2 core–shell nanostructures using reverse micelle technology. J Colloid Interface Sci 298:752–756

    Article  CAS  Google Scholar 

  20. Cao YC, Jin R, Thaxton CS, Mirkin CA (2005) A two-color-change, nanoparticle-based method for DNA detection. Talanta 67:449–455

    Article  CAS  Google Scholar 

  21. Tertykh VA, Katok KV, Yanishpolskii VV (2008) Reduction nanoparticles of gold in surface layer of modified silica. Russ J Phys Chem 82:1438–1441

    Article  CAS  Google Scholar 

  22. Genie A (1961) Radiographic Imaging of Crystals, State publisher of physico-mathematical literature, Moscow (in Russian)

    Google Scholar 

  23. Katok KV, Tertykh VA, Yanishpolskii VV (2008) Synthesis and application of metal-containing silicas. In: Vaseashta A, Mihailescu IN (eds) NATO Science for Peace and Security Series – B: Physics and Biophysics “Functionalized Nanoscale Materials, Devices, and Systems”, Springer, Heidelberg

    Google Scholar 

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Correspondence to V.A. Tertykh .

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Tertykh, V., Yanishpolskii, V., Katok, K., Berezovska, I. (2009). Nanoporous Silica Matrices and Their Application in Synthesis of Nanostructures. In: Shpak, A., Gorbyk, P. (eds) Nanomaterials and Supramolecular Structures. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2309-4_11

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