Abstract
Heating a substance causes a variety of changes. According to International confederation on thermal analysis (ICTA), a group of techniques are being used to correlate the temperature variation with some physical properties of the substance. Thermal analysis technique shows some curves which is a measure of property as a function of temperature and that is characteristic of a particular substance.
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References
P.L. Arens, A study of differential thermal analysis of clay and clay minerals, Gravenage, Wageningen, Netherland, 1951, Excelsiors Fotd—offset’s. Soc. Sci. 72(5), 406 (1951)
E.F. Aglietti, J.M. Porto-López, E. Pereira, Mechanochemical effects in Kaolinite grinding, part I: Textural and physicochemical aspects. Int. J. Miner. Process. 16, 125–133 (1986)
E.F. Aglietti, J.M. Porto-Lo´pez, E. Pereira. Mechanochemical effects in kaolinite grinding, Part II: Structural aspects. ibid.16, 135–146 (1986)
W.F. Bradley, R.E. Grim, High-temperature thermal effects of clay and related materials. Am. Mineral. 36(3/4), 182–201 (1951)
D.S. Belyankin, in Mullite, Its Structure, Formation and Significance, ed. by J. Grofcsik, F. Tamas and A. Kiado (Publishing House of the Hungarian Academy of Sciences 1961, Budapest 1932), pp. 70
M. Bulens, B. Delmon, The exothermic reaction of metakaolinite in the presence of mineralizers: influence of crystallinity. Clays Clay Miner. 25(4), 271–277 (1977)
M. Bellotto, High temperature phase transformation in kaolinite: the influence of disorder and kinetics on the reaction path. Mater. Sci. Forum, 166–169, 3–20 (1994)
E.B. Colegrave and G.R. Rigby, The Decomposition of kaoliite by heat. Trans. Brit. Ceram. Soc. 51(6), 355–367(1952)
A.K. Chakraborty and D.K. Ghosh, Kaolinite–Mullite Reaction Series. Cent. Glass & Ceram. Res. Instt. Bull. 23(2), 86–88 (1976)
A.K. Chakraborty, Resolution of thermal peaks of Kaolinite by TMA and DTA. J. Am. Ceram. Soc. 75(7), 2013–2047 (1992)
A.K. Chakraborty, Application of TMA and DTA studies on the crystallization behavior of SiO2 in thermal transformation of Kaolinite. J. Therm. Anal. 39, 280–299 (1993)
A.K. Chakraborty, DTA study of preheated Kaolinite in the mullite formation region. Thermochima Acta 398(1–2), 203–209 (2003)
C.Y. Chen, G.S. Lan, W.H. Tuan, Micro structural evolution of Mullite during the sintering of Kaolinite powder compacts. Ceram. Int. 26(7), 715–720 (2000)
R.D. Dragsdorf, H.E. Kissinger, A.T. Perkins, An x-ray study of the decomposition of kaolinite. Soil Sci. Soc. Am. J. 71, 439–448 (1951)
W.L. De Keyser, Silicate Industries, vol. 24. pp. 117 and190 (1959)
W.L. De Keyser, Differential thermo balance. Nature [London] 172, 364 (1953)
W.L. De Keyser, Contribution to the study of Mullite. Ber. Dtsch. Keram. Ges. 40, 304–315 (1963a)
W.L. De Keyser, R. Wollast, L. De Laet, Contribution to the study of OH groups In kaolin minerals. International Clay Conference (Pergamon Press, 1963b), pp. 75–86
W.L. De Keyser, Note concerning the exotherm reaction of kaolinite & formation of spinel phase preceding that of mullite. International Clay Conference (Pergamon Press, 1963c), pp. 91–96
L. Erdey, F. Paulik, J. Paulik, Differential thermogravimetry. Nature 174, 885–886 (1954)
F. Freund, Die Deutungder Exothermen Reaktio Des Kaolinite Als Reaktio Des Aktiven Zustandes, Ber. Deut. Keram. Ges. 37, 209–218 (1960a)
F. Freund, Explanation of exothermal reaction of kaolinite as a ‘Reaction of the Active State’. Ber. Deut. Keram. Ges. 37(51), 209–218 (1960b)
W.H. Flank, Behavior of kaolinite pellets at elevated temperature. Clays Clay Miner. 20(1), 1–18 (1979)
R.E. Grim and R.A. Rowland, Differential thermal analysis of clays & shales, A control of prospecting method. J. Am. Ceram. Soc. 27(3), 65–76 (1944)
R.W. Grimshaw, E. Heaton, R.L. Roberts, Refractory clays 11. Trans. Br. Ceram. Soc. 44, 76–92 (1945)
R.E. Grim, Differential thermal curves of prep. Mixtures of clay minerals. Am. Mineral. 32(9, 10), 493–501 (1947)
R.M. Gruver, E.C. Henry, H. Heysteck, Suppression of thermal reactions in Kaolinite. Am. Min. 34, 869 (1949)
J. Gerad-Hirne, C. Lamy, Identification of clays by differential thermal analysis. Bull. Soc. France Ceram. 26–40 (1951)
H.D. Glass, High-temperature phases from kaolinite and halloysite. Am. Mineral. 39, 193–207 (1954)
R.B. Graf , F.M. Wahl and R.E. Grim, Phase transformations in silica-alumina-magnesia mixtures as examined by continuous X-ray diffraction : 1. Talc-kaolinite composition. Amer. Min. 47, 1273–1283 (1962)
F. González García, M.T. Ruiz Abrio and M.G. Rodríguez, Effects of dry grinding on two kaolins of different degrees of crystallinity. Clay Miner. 26(4) 549–565 (1991)
H.S. Houldsworth and J.W. Cobb, Behavior of fireclays, bauxites etc on heating. I. Trans. Brit Ceram. Soc. 22, 111–137, 344–348 (1923)
J.F. Hyslop, A. McMurdo, The thermal expansion of some clay mineral. Trans. Ceram. Soc. (England) 37, 180–186 (1938)
R.A. Heindl, L.E. Meng, Length changes and endothermic and exothermic effects during heating of flint and aluminous clays. J. Res. Natl. Bureau. Stand. 23(9), 427–441 (1939)
C.G. Harman, F. Fraulini, Properties of Kaolinite as a function of its particle size. J. Am. Ceram. Soc. 23, 252–259 (1940)
T. Haase, K. Winter, Influence of grinding on the ceramic properties of kaolin (in Fr.). Bull. Soc. Fr. Ceram. 44, 13–19 (1959)
I.H. Insley, R.H. Ewell, Thermal behavior of the kaolin minerals. J. Res. Natl. Bur. Stand. 14(S), 615–627 (1935)
A. La Iglesium, A.J. Anzar, Crystallinity variations in Kaolinite induced by grinding and pressure treatments. J. Mater. Sci. 31, 4671–4677 (1996)
S.M. Johnson, J.A. Pask, J.S. Moya, Influence of impurities on high-temperature reactions of Kaolinite. J. Am. Ceram. Soc. 65(1), 31–35 (1982)
W.P. Kelly and H. Jenny, Reaction of crystal structure to base exchange and its bearing on base exchange. soil sci. 41, 367–382 (1936)
G. Kulbicki, R.E. Grim, A new method for thermal dehydration studies of clay minerals. Min. Mag. 32, 53 (1959)
T.A. Korneva, T.S. Yusupov, High-temperature behavior of Kaolinite after super-fine grinding, in Proceedings of the First European Symposium on Thermal Analysis (Heyden, London, 1976), pp. 336–339
S. Kawai, M. Yoshida, G. Hashizume, Preparation of mullite from Kaoline by dry grinding, J. Am. Ceram. Soc. Jpn. 98, 669–674 (1990)
E. Kristóf, A.Z. Juhász, I. Vassányi, The effect of mechanical treatment on the crystal structure and thermal behavior of Kaolinite. Clays Clay Miner. 41(5) 608–612 (1993)
H. Le Chatlier, De 1’Action de la Chaleur sur les Argiles” (“Concerning the Action of Heat on Clays”). Bull. SOC. Fr. Mineral. 10, 204–211 (1887)
W.D. Laws, J.B. Page, Changes produced in Kaolinite by dry grinding. Soil Sci. Soc. Am. J. 62, 319–336 (1946)
J. Lemaitre, M. Bullens, B. Delmon, Influence of mineralizers on the 950 °C exothermic reaction of metakaolinite, in Proceedings of the International Clay Conference (Mexico City, Mexico, July 1975), ed. by S.W. Bailey (Applied Publishing Ltd., Wilmette, 1975), pp. 539–544
M. Lomeli, L.M. Flores-Velez, I. Esparza, R. Torres, O. Domínguez, Catalytic effect of CaF2 nanoparticles on sintering behavior of kaolin-based materials. J. Am. Ceram. Soc. 92(7) 1526–1533 (2009)
J. Meneret, Bul. Cer. Fr. 35, 3 (1957)
R.C. Mackenzic, Thermal Methods, Differential Thermal. Investigation of Clays (The Mineralogical Society, London, 1957), p. 22
J.G. Miller, T.D. Oulton, Prototropy in Kaolinite during percussive grinding. Clays Clay Miner. 18(6), 313–323 (1970)
F.H. Norton, Critical study of differentia thermal method for Identification clay minerals. J. Am. Ceram. Soc. 22, 54–63 (1939)
P.G. Nutting, Some standard thermal dehydratiom curves of minerals. U.S. Geol. Surv. Profess. Paper. 197E, 197–216 (1943)
I. Rhode, Keram. Rundschau 35, 414–415 (1927)
C.S. Ross and P.F. Kerr, The Kaolin Mineral. U.S. Geol. Surv. Profess. Paper. 165E, (1930)
A.N. Sokoloff, Molekulares Zerfall Vo Kaolinites Anfang Du Gluhens, Tonind. Ztg. 36, 1107–1110 (1912)
Y.A. Samoilov, Thermal curves of minerals. Bull. Acad. Sci. Petrograde 1759, 1768 (1915)
S. Spiel, L.H. Berkelheimer, J.A. Pask, B. Davis, Differential thermal analysis—its applications to behavior clays and other aluminous minerals. U.S. Bur. Mines. Tech. 664 (1945)
Sedletski, in Mullite, Its Structure, Formation and Significance, ed. by J. Grofcsik, F. Tamas and A. Kiado (Publishing House of the Hungarian Academy of Sciences 1961, Budapest 1949), pp. 70, X-ray characteristic of Monothermite, pp 70
W.J. Smothers, Y. Chiang, and A. Wilson, Bibliography of differential thermal analysis. Univ.Ark. Inst. Sci. Technol. Res. Ser. 31 (1951)
T. Sudo, K. Nagasawa, M. Amafuji, M. Kimura, S. Honda, T. Muto, Studies of Japans clay minerals. J. Geol. Soc. Jpn 58, 115–130 (1952)
P. Spinedi, O. Franciosi, Thermo Diff. Precis. Anal. React. Sci. 22, 2323–2339 (1952)
R.L. Stone, Differential thermal analysis of kaolin group mineral under controlled partial pressure of H2O. J. Am. Ceram. Soc. 35(1), 90 (1952)
R.L. Stone and R.A. Rowland, in: Thermoanalytical Methods of Investigation, ed. by P.D. Garn, 1965. (Academic Press, New York, 1955), p. 297
K.H. Schuller and H. Kromer, Primary mullite as a pseudomorph after kaolinite.in Proceedings of the International Clay Conference (Mexico City, 1975), ed. by S.W. Bailey. (Applied Publishing, Wilmette, IL, 1976) p. 533–38
G. Suraj, C.S.P. Iyer, S. Rugmini, and M. Lalithambika, The effect of micronization on kaolinites and their sorption behavior. Appl. Clay Sci. 12(2) 111–30 (1997)
P.J. Sánchez-Soto, M.C.J. de Haro, L.A. Pérez-Maqueda, I. Varona, J.L. Pérez-Rodríguez, Effects of dry grinding on the structural changes of Kaolinite powders. J. Am. Ceram. Soc. 83(7) 1649–1657 (2000)
G. Tamman, W. Pape, Ilber Den Wasserverlust Des Kaolines and Seinverhat-en In Festen Zuden Carbonatem Und Oxyden Der Erdalkalien. Z. Anorg. Allg. Chem. 127, 43–68 (1923)
Y. Tsuzuki, K. Nagasawa, A transitional stage to 980 °C exotherm of kaolin minerals. Clay Sci. 3(5), 87–102 (1969)
S. Udagawa, T. Nakada, M. Nakahira, Molecular structure of allophane as revealed by its thermal transformation, in Proceedings of International Clay Conference, vol. 1, ed. by L. Heller, B Heller (Israil University Press, Gerusalem, 1969), p. 151
C.J. Van Nieuwenberg, H.A.J. Pieters, Rehydration of Metakaolin and the synthesis of Kaolin. Ber. Beut. Keram.Ges. 10, 260–263 (1929)
F. Vaughn, Energy changes when kaolin minerals are heated. Clay Mineral Bull. 2(13), 265–274 (1955)
F. Vaughn, Trans. Brit Ceram. Soc. 57, 38 (1958)
R. Wohlin, Thermische analyse Von Tonen and Bauxiten. Silikatz 1, 225 (1913)
F.M. Wahl, R.E. Grim, High temperature DTA and XRD studies of reactions, in Twelfth National Conference on Clays and Clay Minerals, pp. 69–81 (1964)
R.R. West, in Ceramics, ed. by R.C. Mackenzie. Differential Thermal Analysis, Fundamental Aspects, vol. 1 (Academic Press, London, 1970), pp. 149–179
T. Watanabe, H. Shimizu, K. Nagasawa, A. Masuda, and H. Saito, 29Siand 27Al- MAS/NMR study of the thermal transformations of kaolinite. ClayMiner. 22, 37–48 (1987)
T. Yamauchi, S. Kato, Thermal analysis of raw clays. J. Jpn. Ceram. Assn. 50, 303 (1943)
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Chakraborty, A.K. (2014). Thermal Methods. In: Phase Transformation of Kaolinite Clay. Springer, New Delhi. https://doi.org/10.1007/978-81-322-1154-9_3
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