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Novel π-Conjugated Systems Based on N-Confused Porphyrinoids

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Chemical Science of π-Electron Systems

Abstract

N-confused porphyrin (termed as NCP) is an isomer of porphyrin in which a pyrrole is connected to the neighboring meso-carbon atoms at α,β′-positions. The specific π-conjugated scaffold present in NCPs provides unique photophysical and electrochemical properties as well as abilities of metal complexation and anion binding in many cases. That has inspired us to explore the further synthetic approaches for development of novel class of porphyrin analogues based on “N-confusion concept.” This chapter introduces an overview of recent development in the chemistry of N-confused porphyrin and related macrocycles.

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Acknowledgment

The authors are deeply indebted to all of our colleagues in the Furuta group for their indispensable contributions. We express our sincere thanks to Prof. Hidemitsu Uno and Prof. Shigeki Mori (Ehime University, Japan) for the help of X-ray crystallographic analysis. We acknowledge the financial support for the Grants-in-Aid (no. 21108518, 23108715 for “pi-space”) from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan.

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  1. Department of Chemistry and Biochemistry, Graduate School of Engineering and Education Center for Global Leaders in Molecular Systems for Devices, Kyushu University, Fukuoka, 819-0395, Japan

    Masatoshi Ishida & Hiroyuki Furuta

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  1. Masatoshi Ishida
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  2. Hiroyuki Furuta
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Correspondence to Hiroyuki Furuta .

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Editors and Affiliations

  1. Foundation for Advancement of International Science, Tsukuba, Japan

    Takeshi Akasaka

  2. Kyoto University, Kyoto, Japan

    Atsuhiro Osuka

  3. Department of Chemistry and Nano Science,, Ewha Womans University, Seoul, Korea (Republic of)

    Shunichi Fukuzumi

  4. Nagoya Institute of Technology, Nagoya, Japan

    Hideki Kandori

  5. Osaka University, Suita, Japan

    Yoshio Aso

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Ishida, M., Furuta, H. (2015). Novel π-Conjugated Systems Based on N-Confused Porphyrinoids. In: Akasaka, T., Osuka, A., Fukuzumi, S., Kandori, H., Aso, Y. (eds) Chemical Science of π-Electron Systems. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55357-1_12

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