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Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions

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Highly Luminescent Lanthanide Complexes with Specific Coordination Structures

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Abstract

The novel thermostable organo-phosphors composed of coordination polymers with phosphine oxides, 1,4-bis(diphenylphosphoryl)benzene (dpb), 4,4′-bis(diphenylphosphoryl)biphenyl (dpbp), 4,4′-bis(diphenylphosphoryl)bithiophe- ne) (dpbt), 3,6-bis(diphenylphosphoryl)-9-phenylcarbazole (dppcz), and low-vibrational frequency hexafluoroacetylacetonato (hfa) ligands are reported. Tight-binding structures with weak intermolecular interactions of the coordination polymer induce both high thermostability (decomposition point >300 °C) and emission quantum yield (Φ Ln = 83 %). The characteristic structures, thermogravimetric analyses and remarkable photophysical properties are presented for the first time.

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Authors and Affiliations

  1. ADEKA Corporation, Tokyo, Japan

    Kohei Miyata

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  1. Kohei Miyata
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Correspondence to Kohei Miyata .

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Miyata, K. (2014). Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions. In: Highly Luminescent Lanthanide Complexes with Specific Coordination Structures. Springer Theses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54944-4_2

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