Abstract
Rechargeable lithium-ion batteries have been continually developed since their introduction by Sony in 1991. Energy density is one of the key parameters for lithium-ion batteries. It was steadily increased by optimizing battery components such as electrode materials or electrolyte as well as by improving the cell construction technologies. The cell level progress during recent years is shown in Fig. 16.1. Both gravimetric (specific) and volumetric energy density were more than doubled.
The original version of this chapter was revised. The updated online version can be found at https://doi.org/10.1007/978-3-662-53071-9_33
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Change history
03 June 2019
No Header
Notes
- 1.
The theoretical (gravimetric) energy density is the stored chemical energy based on the pure electrode materials’ mass.
- 2.
Initially, the terms “cell” and “battery” had strictly different definitions. An electrochemical cell is the smallest battery unit and consists of anode, cathode, electrolyte, separator, current collector, and housing. As opposed to that, a battery consists of at least two cells connected in series or in parallel. A 12-V lead battery for instance is made of six 2-V cells. Nowadays however, a cell is often called battery also. The electrochemical processes do not differ from cell to battery and this is why the present Chapter does not differentiate between those two terms. Specifying the practical energy densities however calls for a differentiation. All practical energy density values (with the exception of lead batteries) in this Chapter refer to cells.
- 3.
The polysulfide species Sn 2– that form at the cathode during discharging dissolve in the electrolyte there. A concentration gradient versus the anode develops, which causes the polysulfides to diffuse toward the anode. Step by step, the polysulfides are distributed in the electrolyte.
Bibliography
Gesamt-Roadmap Energiespeicher für die Elektromobilität 2030, Fraunhofer-Institut für System und Innovationsforschung ISI, Karlsruhe, Dezember 2015
Herbert D, Ulam J (1962) Inventors; electric dry cells and storage batteries
Nole DA, Moss V, Cordova R (1970) Inventors; battery employing lithium-sulphur electrodes with nonaqueous electrolyte
Abraham KM (1981) Status of rechargeable positive electrodes for ambient-temperature lithium batteries. J Power Sources 7(1):1 − 43
Yamin H, Penciner J, Gorenshtain A, Elam M, Peled E (1985) The electrochemical-behavior of polysulfides in tetrahydrofuran. J Power Sources 14(1−3):129 − 134
Akridge JR, Mikhaylik YV, White N (2004) Li/S fundamental chemistry and application to hig-performance rechargeable batteries. Solid State Ionics 175(1 – 4):243 – 245
Mikhaylik YV, Akridge JR (2004) Polysulfide shuttle study in the Li/S battery system. J Electrochem Soc 151(11):A76 − A1969
Nelson J, Misra S, Yang Y, Jackson A, Liu Y, Wang H et al (2012) In operando x-ray diffraction and transmission x-ray microscopy of lithium sulfur batteries. J Am Chem Soc 134(14):6337 – 6343
Dominko R, Demir-Cakan R, Morcrette M, Tarascon J-M (2011) Analytical detection of soluble polysulphides in a modified Swagelok cell. Electrochem Commun 13(2):117 – 120
Kumaresan K, Mikhaylik Y, White RE (2008) A mathematical model for a lithium-sulfur cell. J Electrochem Soc 155(8):A576 − A582
Ji X, Lee KT, Nazar LF (2009) A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries. Nat Mater 8(6):500 – 506
Schneider H, Garsuch A, Panchenko A, Gronwald O, Janssen N, Novak P (2012) Influence of different electrode compositions and binder materials on the performance of lithium-sulfur batteries. J Power Sources 205:420 – 425
Cheon SE, Ko KS, Cho JH, Kim SW, Chin EY, Kim HT (2003) Rechargeable lithium sulfur battery – II. Rate capability and cycle characteristics. J Electrochem Soc 150(6):A800 – A805
Kang SH, Zhao X, Manuel J, Ahn HJ, Kim KW, Cho KK, Ahn JH (2014) Effect of sulfur loading on energy density of lithium sulfur batteries. PSSA 211(8):1895–1899
Hagen M, Fanz P, Tübke J (2014) Cell energy density and electrolyte/sulfur ratio in Li-S cells. J Power Sources 264:30–34
Brückner J, Thieme S, Grossmann HT, Dörfler S, Althues H, Kaskel S (2014) Lithium-sulfur batteries: influence of C-rate, amount of electrolyte and sulfur loading on cycle performance. J Power Sources 268:82–87
Cleaver T, Kovacik P, Marinescu M, Zhang T, Offer G (2018) Perspective—commercializing lithium sulfur batteries: are we doing the right research? J Electrochem Soc 165(1):A6029–A6033
Adelhelm P, Hartmann P, Bender CL, Busche M, Eufinger C, Janek J, Beilstein J (2015) From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries. J Nanotechnol 6:1016–1055
Hassoun J, Scrosati B (2010) A high-performance polymer tin sulfur lithium ion battery. Angewandte Chemie Int Edition 49(13):2371 – 2374
Aurbach D, Pollak E, Elazari R, Salitra G, Kelley CS, Affinito J (2009) On the surface chemical aspects of very high energy density, rechargeable li–sulfur batteries. J Electrochem Soc 156(8):A694 – A702
Jozwiuk A, Sommer H, Janek J, Brezesinski T (2015) Fair performance comparison of different carbon blacks in lithium-sulfur batteries with practical mass loadings – simple design competes with complex cathode architecture. J Power Sources 296:454–461
Medenbach L, Adelhelm P (2017) Cell concepts of metal-sulfur batteries (Metal = Li, Na, K, Mg): strategies for using sulfur in energy storage applications. Top Curr Chem 375(5):81
Lin Z, Liu Z, Fu W, Dudney NJ, Liang C (2013) Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries. Angewandte Chemie. 125(29):7608 – 11
Yang Y, Zheng G, Cui Y (2013) A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage. Energy & Environmental Science 6(5):1552 – 8
Rauh RD, Abraham KM, Pearson GF, Surprenant JK, Brummer SB (1979) A lithium/dissolved sulfur battery with an organic electrolyte. J Electrochem Soc 126(4):523–527
Zhang SS, Read JA (2012) A new direction for the performance improvement of rechargeable lithium/sulfur batteries. J Power Sources 200:77–82
Zheng G, Cui Y (2013) A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage. Energy Environ Sci 6:1552–1558
Fu Y, Su YS, Manthiram A (2013) Highly reversible lithium/dissolved polysulfide batteries with carbon nanotube electrodes. Angew Chem Int Edit 52(27):6930–6935
Hassoun J, Scrosati B (2010) Moving to a solid‐state configuration: a valid approach to making lithium‐sulfur batteries viable for practical applications. Adv Mater 22(45):5198–5201
Nagata H, Chikusa Y (2014) A lithium sulfur battery with high power density. J Power Sources 264:206–210
Adelhelm P, Hartmann P, Bender CL, Busche M, Eufinger C, Janek J (2015) From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries. Beilstein J Nanotechnol 6:1016–1055
Abraham KM, Jiang Z (1996) A polymer electrolyte-based rechargeable lithium/oxygen battery. J Electrochem Soc 143(1):1 – 5
Read J (2002) Characterization of the lithium/oxygen organic electrolyte battery. J Electrochem Soc 149(9):A1190 – A1195
Sawyer DT, Valentine JS (1981) How super is superoxide. Acc Chem Res 14(12):393 − 400
Aurbach D, Daroux M, Faguy P, Yeager E (1991) The electrochemistry of noble-metal electrodes in aprotic organic-solvents containing lithium-salts. J Electroanal Chem 297(1):225 – 244
Mizuno F, Nakanishi S, Kotani Y, Yokoishi S, Iba H (2010) Rechargeable Li-air batteries with carbonate-based liquid electrolytes. Electrochem 78(5):403 – 405
Freunberger SA, Chen Y, Peng Z, Griffin JM, Hardwick LJ, Barde F et al (2011) Reactions in the rechargeable Li-O2 battery with alkyl carbonate electrolytes. J Am Chem Soc 133(20):8040 – 8047
McCloskey BD, Scheffler R, Speidel A, Bethune DS, Shelby RM, Luntz AC (2011) On the efficacy of electrocatalysis in nonaqueous Li-O2 batteries. J Am Chem Soc 133(45):18038 – 18041
Peng ZQ, Freunberger SA, Chen YH, Bruce PG (2012) A Reversible and Higher-Rate Li-O2 Battery. Science. 337(6094):563 – 6.
Chase GV, Zecevic S, Walker W, Uddin J, Sasaki KA, Giordani V, Bryantsev V, Blanco M, Addison D (2011) US Patent Application No 20120028137 A1 2011
Hase Y, Shiga T, Nakano M, Takechi K, Setoyama N (2009) US Patent Application No US 2009/0239113 A1 2009
Chen Y, Freunberger SA, Peng Z, Fontaine O, Bruce PG (2013) Charging a Li–O2 battery using a redox mediator. Nat Chem 5:489–494
Lim HD, Song H, Kim J, Gwon H, Bae Y, Park KY, Hong J, Kim H, Kim T, Kim YH, Lepró X, Ovalle-Robles R, Baughman R, Kang K (2014) Superior rechargeability and efficiency of lithium–oxygen batteries: hierarchical air electrode architecture combined with a soluble catalyst. Angew Chem Int Ed Engl 53(15):3926–3931
Bergner BJ, Schürmann A, Peppler K, Garsuch A, Janek J (2014) TEMPO: a mobile catalyst for rechargeable Li-O2 batteries. J Am Chem Soc 136(42):15054–15064
Feng N, Mu X, Zhang X, He P, Zhou H (2017) Intensive study on the catalytical behavior of N-methylphenothiazine as a coluble mediator to oxidize the Li2O2 cathode of the Li–O2 battery. ACS Appl Mater Interfaces 9(4):3733–3739
Liang Z, Lu YC (2016) Critical role of redox mediator in suppressing charging instabilities of lithium–oxygen batteries. J Am Chem Soc 138(24):7574–7583
Aetukuri NB, McCloskey BD, Garcia JM, Krupp LE, Viswanathan V, Luntz AC (2015) Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li–O2 batteries. Nat Chem 7:50–56
Meini S, Piana M, Tsiouvaras N, Garsuch A, Gasteiger HA (2012) The effect of water on the discharge capacity of a non-catalyzed carbon cathode for Li-O2 batteries. Electrochem Solid-State Lett 15(4):A45–A48
Schwenke KU, Metzger M, Restle T, Piana M, Gasteiger HA (2015) The influence of water and protons on Li2O2 crystal growth in aprotic Li-O2 cells. J Electrochem Soc 162(4):A573–A584
Li F, Wu S, Li D, Zhang T, He P, Yamada A, Zhou H (2015) The water catalysis at oxygen cathodes of lithium–oxygen cells. Nat Commun 6:7843
Xia C, Black R, Fernandes R, Adams B, Nazar LF (2015) The critical role of phase-transfer catalysis in aprotic sodium oxygen batteries. Nat Chem 7:496–501
Hartmann P, Bender CL, Vracar M, Dürr AK, Garsuch A, Janek J, Adelhelm P (2013) A rechargeable room-temperature sodium superoxide (NaO2) battery. Nat Mater 12:228 – 232
http://www.ibm.com/smarterplanet/us/en/smart_grid/article/battery500.html
de Jonghe LC et al (2007) inventors; protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
Peled E, Menkin S (2017) Review—SEI: past, present and future. J Electrochem Soc 164(7):A1703–A1719
Aurbach D et al (2009) On the surface chemical aspects of very high energy density, rechargeable Li-sulfur batteries. J Electrochem Soc 156(8):A694 − A702
Brandt K (1994) Historical development of secondary lithium batteries. Solid State Ionics.69(3 – 4):173 – 183
Monroe C, Newman J (2005) The impact of elastic deformation on deposition kinetics at lithium/polymer interfaces. J Electrochem Soc 152(2):A396 – A404
Li W, Yao H, Yan K, Zheng G, Liang Z, Chiang Y-M, Cui Y (2015) The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth. Nat Commun 6:7436.
Ding F, Xu W, Graff GL, Zhang J, Sushko ML, Chen X, Shao Y, Engelhard MH, Nie Z, Xiao J, Liu X, Sushko PV, Liu J, Zhang J-G (2013) Dendrite-free lithium deposition via self-healing electrostatic shield mechanism. J Am Chem Soc 135(11):4450–4456.
Suo L, Hu Y-S, Li H, Armand M, Chen L (2013) A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries. Nat Commun 4.
Qian J, Henderson WA, Xu W, Bhattacharya P, Engelhard M, Borodin O, Zhang J-G (2015) High rate and stable cycling of lithium metal anode. Nat Commun 6.
Khurana R, Schaefer JL, Archer LA, Coates GW (2014) Suppression of lithium dendrite growth using cross-linked polyethylene/poly(ethylene oxide) electrolytes: a new approach for practical lithium-metal polymer batteries. J Am Chem Soc 136(20):7395–7402.
Yang Y, McDowell MT, Jackson A, Cha JJ, Hong SS, Cui Y (2010) New nanostructured Li2S/Silicon rechargeable battery with high specific energy. Nano Lett 10(4):1486 – 1491
Elazari R, Salitra G, Gershinsky G, Garsuch A, Panchenko A, Aurbach D (2012) Rechargeable lithiated silicon–sulfur (SLS) battery prototypes. Electrochem Commun 14(1):21 – 24
Handbook of Solid State Batteries, 2nd ed., Dudney N J, West W C, Nanda J (Eds.), World Scientific 2015
Janek J, Zeier W (2016) A solid future for battery development. Nat Energy 1(9):16141
Luntz A C, Voss J, Reuter K (2015) Interfacial challenges in solid-state Li ion batteries. J Phys Chem Lett 6:4599–4604
Robinson A L, Janek J (2014) Solid-state batteries enter EV fray. MRS Bulletin 39:1046
Kato, Y. et al. (2016) High-power all-solid-state batteries using sulfide superionic conductors. Nat Energy 1:16030
Oh G, Hirayama M, Kwon O, Suzuki K, Kanno R (2016) Bulk-type all solid-state batteries with 5 V class LiNi0.5Mn1.5O4 cathode and Li10GeP2S12 solid electrolyte. Chem Mater 28:2634–2640
Bachman JC, Muy S, Grimaud A, Chang HH, Pour N, Lux SF, Paschos O, Maglia F, Lupart S, Lamp P, Giordano L, Shao-Horn Y (2016) Inorganic solid-state electrolytes for lithium batteries: mechanisms and properties governing ion conduction. Chem Rev 116(1):140–162
Minami T, Hayashi A, Tatsumisago M (2006) Recent progress of glass and glass-ceramics as solid electrolytes for lithium secondary batteries. Solid State Ionics 177:2715–2720
Wenzel S, Weber D, Leichtweiss T, Sann J, Janek J (2016) Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte. Solid State Ionics 286:24–33
Zhu Y, He X, Mo Y (2015) Origin of outstanding stability in the lithium solid electrolyte materials: insights from thermodynamic analyses based on first-principles calculations. ACS Appl Mater Interface 7:23685–23693
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer-Verlag GmbH Germany, part of Springer Nature
About this chapter
Cite this chapter
Janek, J., Adelhelm, P. (2018). Next generation technologies. In: Korthauer, R. (eds) Lithium-Ion Batteries: Basics and Applications. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-53071-9_16
Download citation
DOI: https://doi.org/10.1007/978-3-662-53071-9_16
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-53069-6
Online ISBN: 978-3-662-53071-9
eBook Packages: EnergyEnergy (R0)