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Phase Behavior in Systems of Large Molecules

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Clusters and Nanomaterials

Part of the book series: Springer Series in CLUSTER PHYSICS ((CLUSTER))

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Summary

In this article we present recent developments concerning the relation between the nature of the intermolecular potential and phase behavior. The interest is twofold. The first issue concerns the disappearance of a thermodynamically stable liquid phase expected for C60. The second concerns the isostructural solid—solid transition, counterpart to the liquid—vapor transition in the fluid phase. This is expected but not actually observed in systems of mesoscopic particles such as colloids. The results of these investigations are surveyed with particular emphasis on our own work. The relevant theoretical and simulation methods used to determine the phase diagram are also discussed in some detail.

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Authors
  1. Masayuki Hasegawa
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Editor information

Editors and Affiliations

  1. Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, 980-8577, Sendai, Japan

    Yoshiyuki Kawazoe

  2. Cluster Research Laboratory, Toyota Technological Institute in East Tokyo Laboratory, Genesis Research Institute Inc., 717-86 Futamata, Ichikawa, 272-0001, Chiba, Japan

    Tamotsu Kondow

  3. Department of Physics, Faculty of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, 240-8501, Yokohama, Japan

    Kaoru Ohno

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© 2002 Springer-Verlag Berlin Heidelberg

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Hasegawa, M. (2002). Phase Behavior in Systems of Large Molecules. In: Kawazoe, Y., Kondow, T., Ohno, K. (eds) Clusters and Nanomaterials. Springer Series in CLUSTER PHYSICS. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04812-2_10

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  • DOI: https://doi.org/10.1007/978-3-662-04812-2_10

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-07522-3

  • Online ISBN: 978-3-662-04812-2

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