Abstract
In this chapter the phonon data of all measured perovskitic crystals are collected together with other crystals which belong to the chemical brutto formula ABX3 (X = O,H,F). This, unavoidably, includes so-called molecular crystals like NaNO3 but may be justified from a technical point of view. Since these crystals show many different types of phase transitions together with a complex dielectric and anharmonic behavior it is not surprising that the lattice dynamics of them is very complicated and offers many unsolved problems. An exception are the cubic perovskites where the pioneering work of COWLEY [14.12] and STIRLING [14.11] led to a basic understanding of interatomic forces in these substances. A recent microscopic model [14.7, 8] emphasized the importance of the oxygen polarizability for the ferroelectric phase transition in ABO3 perovskites.
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Bilz, H., Kress, W. (1979). ABO3 and ABX3 Crystals. In: Phonon Dispersion Relations in Insulators. Springer Series in Solid-State Sciences, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81347-4_14
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DOI: https://doi.org/10.1007/978-3-642-81347-4_14
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