Abstract
The analytical chemist in general employs several procedural steps for the characterization of complex samples. These steps can be classified into three major tasks: sample preparation, analysis, and interpretation of the resultant data. Advances in analytical chemistry have reduced the experimental burden and time required for these task areas; however, to date, sample preparation continues to consume much of the analyst’s time in the entire analysis protocol. Improved methods for sample preparation would be welcomed in the analytical laboratory as well as techniques that minimize the use of chemical reagents and their attendant disposal problems. This is particularly true in analytical protocols that require the use of toxic or carcinogenic organic solvents in the sample preparation schemes. The relatively new technique of supercritical fluid extraction (SFE) offers the analyst an alternative for preparing samples prior to analysis, that is rapid and environmentally less hazardous. This chapter will describe the basic principles involved in applying the technique for sample preparation in analytical chemistry.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Majors RE (1989) LC-GC 7:92
Steinwandter H (1989) In: Zweig G, Sherma J (eds) Analytical methods for pesticides and plant growth regulators, Vol 17. Academic, New York, pp 63–71
Giddings JC, Myers MN, King JW (1969) J Chromatogr Sci 7:276
Sie ST, Rijnders GWA (1967) Separation Sci 2:755
Stahl E, Schilz W, Schutz W, Willing E (1978) Angew Chem Int Ed Engl 17:731
Stahl E, Quirin KW, Gerard D (1988) Dense gases for extraction and refining. Springer-Verlag, Berlin
Hawthorne SB, Miller DJ (1986) J Chromatog Sci 24:258
Schantz MM, Chesler SN (1986) J Chromatog 363:397
Alexandrou N, Pawliszyn J (1989) Anal Chem 61:2770
Hawthorne SB, Krieger MS, Miller DJ (1989) Anal Chem 61:736
Onuska FI, Terry KA (1989) J High Resolut Chromatog 12:357
Dooley KM, Kao CP, Gambreil RP, Knopf FC (1987) Ind Eng Chem Res 26:2058
King JW (1989) J Chromatog Sci 27:355
Nam KS, Kapila S, Pieczonka G, Clevenger TE, Yanders AF, Viswanath DS, Mallu B (1988) In: Perrut M (ed) Proceedings of the international symposium on supercritical fluids. Tome 2 Institute National Polytechnique de Lorraine, France, p 743–750
Wheeler JR, McNally ME (1989) J Chromatog Sci 27:534
Janda V, Steenbeke G, Sandra P (1989) J Chromatog 479:200
Lopez-Avila V, Becker WF, Billets S (1989) In: Proceedings of the 5th annual waste testing and quality assurance. Symposium, Vol 2. US EPA, Washington, DC, p 11 - 73
Schafer K, Baumann W (1989) Z Anal Chem 332:884
Schneiderman MA, Sharma AK, Locke DC (1987) J Chromatog 409:343
Schneiderman MA, Sharma AK, Locke DC (1988) J Chromatog Sci 26:458
Xie QL, Markides KE, Lee ML (1989) J Chromatog Sci 27:365
Hawthorne SB, Miller DJ (1987) J Chromatog 403:63
McHugh MA, Krukonis VJ (1986) Supercritical fluid extraction: principles and practice. Butterworths, Boston, MA
Zosel K (1980) In: Extraction with supercritical gases. Verlag Chemie, Weinheim, Germany, pp 1–23
Eggers R, Tschiersch R (1978) Chem Ing Tech 50:842
King JW, Johnson JH, Friedrich JP (1989) J Agric Food Chem 37:951
Giddings JC, Myers MN, McLaren L, Keller RA (1968) Science 162:67
King JW (1984) Preprints-Polymeric Materials Science & Engineering Division, Vol 51. American Chemical Society, Washington, DC, pp 707–712
Stahl E, Willing E (1980) Pharm Ind 42:1136
Hemmaplardh B, King Jr AD (1972) J Phys Chem 76:2170
Brogle H (1982) Chem Ind (12):385
Francis AW (1954) J Phys Chem 58:1099
Lira CT (1988) In: Charpentier BA, Sevenants MR (eds) Supercritical fluid extraction and chromatography. American Chemical Society, Washington DC, pp 1–25
Chimowitz EH, Pennisi KJ (1986) AIChE J 32:1665
Johnston KP, Barry SE, Read NK, Holcomb TR (1987) Ind Eng Chem Res 26:2372
Peter S, Brunner G, Riha R (1976) Fette Seifen Anstrichmittel 76:45
Dobbs JM, Wong JM, Lahiere RJ, Johnston KP (1987) Ind Eng Chem Res 26:56
Wong JM, Johnston KP (1986) Biotech Progress 2:29
Dobbs JM, Johnston KP (1987) Ind Eng Chem Res 26:1476
Hedrick J, Taylor LT (1989) Anal Chem 61:1986
Johnston KP (1989) In: Johnston KP, Penninger JML (eds) Supercritical fluid science and technology. American Chemical Society, Washington, DC, pp 1–12
Rizvi SSH, Benado AL, Zollweg JA, Daniels JA (1986) Food Tech 40 (6):55
Friedrich JP, List GR, Spencer GF (1988) In: Baldwin AR (ed) Proceedings of the 7th international conference on jojoba and its uses. American Oil Chemists’ Society, Champaign, IL, 165–172
Hawthorne SB, Miller DJ, Krieger MS (1988) Fresenius Z Anal Chem 330:211
King JW (1984) J Am Oil Chemists’ Soc 61:689
List GR, Friedrich JP, King JW (1989) Oil Mill Gazetteer 95 (6):28–34
Bowman Jr LM (1976) Dense gas chromatographic studies. Ph D Thesis, University of Utah, Salt Lake City, UT
Prausnitz JM (1969) Molecular thermodynamics of fluid-phase equilibria. Prentice-Hall, Englewood Cliffs, NJ, p 36–39
Kurnik RT, Reid RC (1981) AIChE J 27:861
Allada SR (1984) Ind Eng Chem Process Des Dev 23:344
Fedors RF (1974) Polym Eng Sci 14:147
Jayasri A, Yaseen M (1980) J Coatings Tech 52 (667):41–45
Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, Ithaca, NY
Sugiyama K, Saito M, Hondo T, Senda M (1985) J Chromatogr 332:107
Jackson WP, Markides KE, Lee ML (1986) HRC & CC 9:213
Skelton Jr RJ, Johnson CC, Taylor LT (1986) Chromatographia 21:4
Gmuer W, Bosset JO, Plattner E (1987) J Chromatogr 388:335
Engelhardt H, Gross A (1988) HRC & CC 11:38
Raynor MW, Davies IL, Bartle KD, Clifford AA, Williams A, Chalmers JM, Cook BW (1988) HRC & CC 11:766
McNally ME, Wheeler JR (1988) J Chromatog 435:63
Saito M, Yamaguchi Y, Inomata K, Kottkamp W (1989) J Chromatog Sci 27:79
Ramsey ED, Perkins JR, Games DE, Startin JR (1989) J Chromatogr 464:353
Thiebault D, Chervet JP, Vannoort RW, DeJong GJ, Brinkman UA, Frei RW (1989) J Chromatogr 477:151
Sieber R (1988) In: Perrut M (ed) Proceedings of the international symposium on supercritical fluids, Vol 2. Institute National Polytechnique de Lorraine, France, p 619
van Wasen U, Swaid I, Schneider GM (1980) Angew Chem Int Ed Engl 19:575
Smith RD, Udseth HR, Wright BW, Yonker CR (1987) Sep Sci Tech 22:1065
Feist R, Schneider GM (1982) Sep Sci 17:261
Sie ST, Van Beersum W, Rijnders GWA (1966) Sep Sci 1:459
Parcher J, Strubinger JR (1989) J Chromatogr 479:251
King JW, Eissler RL, Friedrich JP (1988) In: Charpentier BA, Sevenants MR (eds) Supercritical fluid extraction and chromatography. American Chemical Society, Washington, DC, p 63–88
Markides KE, Lee ML (1989) SFC applications. Brigham Young University Press, Provo, UT
Smith RD, Udseth HR, Wright BW (1985) In: Penninger JML, Radosz M, McHugh MA, Krukonis VJ (eds) Supercritical fluid technology. Elsevier, Amsterdam, pp 191–223
McMahon D, Cohen KA, Taylor LT (eds) (1988) Chromatography illustrated. Preston Publications, Niles, IL, pp 73–90
Fields SM, Grolimund K (1988) HRC & CC 11:727
McNally ME, Wheeler JR (1988) J Chromatogr 447:53
Klesper E, Leyendecker D, Schmitz FP (1986) J Chromatogr 366:235
Levy JM, Ritchey WM (1986) J Chromatogr Sci 24:242
Hawthorne SB, Miller DJ (1987) Anal Chem 59:1705
Engelhart WG, Gargus AG (1988) 20 (2):30
Swanson JT, Andersen MR, Richter BE (1990) Theory of mass transfer applied to micro-SFE. Paper presented at the symposium/workshop on supercritical fluid chromatography, Part City, UT
Hawthorne SB (1990) Anal Chem 62:633A
Andersen MR, Swanson JT, Porter NL, Richter BE (1989) J Chromatogr Sci 27:371
Levy JM, Cavalier RA, Bosch TN, Rynaski AF, Huhak WE (1989) J Chromatogr Sci 27:341
King JW, France JE, Taylor SL (1990) In: Sandra P, Redant G (eds) Proceedings - 11th international symposium on capillary chromatography. Hüthig, Heidelberg, pp 595–601
Synder JM, Friedrich JP, Christianson DD (1984) J Am Oil Chemists’ Soc 61:5475
Roselius W, Vitzhum OG, Hubert P (1976) DBP 2142205
Yamaguchi K, Murakami M, Nakano H, Konosu S, Kokura T, Yamamoto H, Kosaka M, Hata K (1986) J Agric Food Chem 34:904
King JW (1989) Abstracts of the Pittsburgh conference, Atlanta, GA, #397
Chiou JS, Barlow JW, Paul DR (1985) J Apply Polym Sci 30:3911
Nicholas J, Bartle KD, Clifford AA (1990) In: Sandra P, Redant G (eds) Proceedings - 11th international symposium on capillary chromatography. Hüthig, Heidelberg, pp 665–672
Modell M, deFilippi RP, Krukonis V (1980) In: Suffet IH, McGuire MJ (eds) Activated carbon adsorption of organics from the aqueous phase, Vol 1. Ann Arbor Science Publishers Inc, Ann Arbor, MI, pp 447–462
Picht RD, Dillman TR, Burke DJ, deFilippi RP (1982) In: Ma YH (ed) Recent advances in adsorption and ion exchange, Vol 78. AIChE, New York, NY, pp 136–149
King JW (1987) In: Squires TG, Paulaitis ME (eds) Supercritical fluids: Chemical and engineering principles and applications. American Chemical Society, Washington, DC, pp 150–171
Randolph TW (1990) Trends in Biotech 8:78
Fisher RJ (1989) Food Tech 43(3):90
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1992 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
King, J.W., France, J.E. (1992). Basic Principles of Analytical Supercritical Fluid Extraction. In: Wenclawiak, B. (eds) Analysis with Supercritical Fluids: Extraction and Chromatography. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-77474-4_3
Download citation
DOI: https://doi.org/10.1007/978-3-642-77474-4_3
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-77476-8
Online ISBN: 978-3-642-77474-4
eBook Packages: Springer Book Archive