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Photochemistry at Adsorbate-Metal Interfaces: Intra-adsorbate Bond Breaking

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Chemistry and Physics of Solid Surfaces VIII

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 22))

Abstract

While photochemistry in gases, liquids and solids has a long and well-documented record [3.1], and photochemistry, including photoelectrochemistry, at semiconductor-adsorbate interfaces is well known [3.2], photochemistry at adsorbate-metal interfaces is a newly emerging and rapidly expanding area of surface chemistry. There are also a number of recent interesting experiments involving photochemistry of molecules adsorbed at insulator surfaces [3.3]. In this paper we focus on bond cleavage within the first monolayer of adsorbate rather than on adsorbate-metal bond cleavage or photochemistry in multilayers. The latter topic has been the subject of a number of investigations and reviews [3.4–6], Table 3.1 lists a number of recent successful photochemical intraadsorbate bond cleavage experiments [3.7–27]. An interesting comparison is given in Table 3.2, which lists experiments where no photochemistry was observed [3.28–31].

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Authors and Affiliations

  1. Department of Chemistry, University of Texas, 78712, Austin, TX, USA

    J. M. White

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  1. J. M. White
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Editors and Affiliations

  1. Department of Chemistry and Laboratory for Surface Studies, The University of Wisconsin-Milwaukee, 53201, Milwaukee, WI, USA

    Ralf Vanselow Ph.D.

  2. Department of Chemistry, Private Bag, University of Auckland, Auckland, New Zealand

    Russell Howe

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© 1990 Springer-Verlag Berlin Heidelberg

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White, J.M. (1990). Photochemistry at Adsorbate-Metal Interfaces: Intra-adsorbate Bond Breaking. In: Vanselow, R., Howe, R. (eds) Chemistry and Physics of Solid Surfaces VIII. Springer Series in Surface Sciences, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75762-4_3

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  • DOI: https://doi.org/10.1007/978-3-642-75762-4_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-75764-8

  • Online ISBN: 978-3-642-75762-4

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