Skip to main content

Interstellar Molecular Formation Processes

  • Conference paper
Cosmic Chemistry

Part of the book series: Reviews in Modern Astronomy ((MOD.ASTRONOMY,volume 1))

Abstract

Visible radiation from galaxies is dominated by hot stellar material. However, the existence of cooler, interstellar phases can be inferred from the absorption and scattering of visible radiation as well as from emission at longer wavelengths. In particular, radioastronomical and, to a lesser extent, infrared observations have helped to uncover the existence of vast interstellar clouds of gaseous and particulate matter, with most of the matter (≈ 99%) in the gaseous form and ≈ 1% in the form of dust-like particles [1]. In the denser interstellar clouds, approximately eighty different molecular species and numerous isotopic variants have been discovered in the gas phase. These molecules range in complexity from diatomics to a thirteen-atom species, are mainly organic (carbon-containing) in nature, and comprise a variety of standard and bizarre species [1,2]. Detected by narrow line spectra, the gaseous molecules are exceedingly well characterized and their observation leads to a detailed knowledge of the chemical and physical state of the gas in dense interstellar clouds [2, 3]. For example, gas temperatures are in the range 10 – 70 K and total gas densities are on the order of 104 cm-3. Since dense clouds can range in extent up to ≈ 100 pc, cloud masses can range up to 106 solar masses. The material is slowly collapsing to form stars. Material in star-forming regions is typically denser and warmer than ambient material and can be studied separately from the ambient material either interferometrically or via differences in line profiles [4]. The particulate phase of dense clouds consists of small (0.1 μm) dust particles that contain refractory cores of material such as silicates covered mantles deposited from the gas phase [5].

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 119.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 159.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. A recent introduction to the subject can be found in the collection of papers entitled Astrochemistry, eds. M. S. Vardya and S. P. Tarafdar, Proceedings of the 120th Symposium of the I. A. U. (Reidel, Dordrecht 1987). A somewhat older volume is Molecular Astrophysics, eds. G. H. F. Diercksen, W. F. Huebner, and P. W. Langhoff, NATO ISI Series Vol. 157 (Reidel, Dordrecht, 1985). Finally, the physical and chemical processes occurring in clouds are reviewed in the volume Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987).

    Google Scholar 

  2. G. Winnewisser and E. Herbst: Topics in Current Chemistry 139, 119 (1987)

    Article  Google Scholar 

  3. W. M. Irvine, P. F. Goldsmith, and Å Hjalmarson: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987) p. 561.

    Google Scholar 

  4. G. A. Blake, E. C. Sutton, C. R. Masson, T. G. Phillips: Astrophys. J. 315, 621 (1987)

    Article  ADS  Google Scholar 

  5. See also N. Z. Scoville, D. B. Sanders, A. I. Sargent, B. T. Soifer, S. L. Scott, K. Y. Lo: Astrophysical J. Letters 311, L47 (1986)

    Article  ADS  Google Scholar 

  6. A. G. G. M. Tielens, L. J. Allamandola: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987), p. 397

    Chapter  Google Scholar 

  7. L. J. Allamandola, A. G. G. M. Tielens, J. R. Barker: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987), p. 471

    Google Scholar 

  8. W. Gordy, R. L. Cook: Microwave Molecular Spectra, Techniques of Chemistry, Vol. XVIII (Wiley, New York, 1984)

    Google Scholar 

  9. A. Betz: In Astrochemistry, eds. M. S. Vardya and S. P. Tarafdar (Reidel, Dordrecht, 1987), p. 327

    Chapter  Google Scholar 

  10. See, for example, T. Anderson, E. Herbst, and F. C. De Lucia: Astrophysical J. Suppl. Ser. 64, 703 (1987) and references therein.

    Article  ADS  Google Scholar 

  11. T. J. Millar, A. Bennett, E. Herbst: submitted to Astrophys. J. U.E. Herbst, C. M. Leung: Monthly Notices Roy. Astron. Soc. 222, 689

    Google Scholar 

  12. C. G. Seab: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987), p. 491

    Google Scholar 

  13. A. Omont: Astron. Astrophys. 164, 159 (1986)

    ADS  Google Scholar 

  14. R. J. Gould, E. E. Salpeter: Astrophys. J. 138, 393 (1963)

    Article  ADS  Google Scholar 

  15. A. Dalgarno, R. McCray: Astrophys. J. 181, 95 (1973)

    Article  ADS  Google Scholar 

  16. W. D. Watson: Rev. Mod. Phys. 48, 513 (1976)

    Article  ADS  Google Scholar 

  17. M. Allen, G. W. Robinson: Astrophys. J. 212, 396 (1977)

    Article  ADS  Google Scholar 

  18. P. Aannestad: Astrophys. J. Suppl. Ser. 25, 223 (1973)

    Article  ADS  Google Scholar 

  19. L. B. d’Hendecourt, L. J. Allamandola, J. M. Greenberg: Astron. Astrophys. 152, 130 (1985)

    ADS  Google Scholar 

  20. D. A. Williams, T. W. Hartquist: Monthly Notices Roy. Astron. Soc. 210, 141 (1984)

    ADS  Google Scholar 

  21. A. Léger, M. Jura, A. Omont: Astron. Astrophys. 144, 147 (1985)

    ADS  Google Scholar 

  22. L. B. d’Hendecourt, L. J. Allamandola, F. Baas, J. M. Greenberg: Astron. Astrophys. 109, L 12 (1982)

    ADS  Google Scholar 

  23. A. G. G. M. Tielens, W. Hagen: Astron. Astrophys. 114, 245 (1982).

    ADS  Google Scholar 

  24. See, for example, N. G. Adams, D. Smith: Chem. Phys. Letters 79, 563 (1981)

    Article  ADS  Google Scholar 

  25. A review of the various techniques used is given by D. R. Bates, E. Herbst: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 17

    Chapter  Google Scholar 

  26. E. Herbst, D. J. DeFrees, A. D. McLean: Astrophys. J. 321, 898 (1987)

    Article  ADS  Google Scholar 

  27. See any book on elementary gas phase reaction kinetics. A useful volume is R. D. Levine, R. B. Bernstein: Molecular Reaction Dynamics (Oxford University Press, 1974)

    Google Scholar 

  28. J. B. Marquette, B. R. Rowe, G. Dupeyrat, G. Poissant: In Astrochemistry, eds. M. S. Vardya and S. P. Tarafdar (Reidel, Dordrecht, 1987), p.19

    Chapter  Google Scholar 

  29. D. C. Clary: Molec. Phys. 54, 605 (1985)

    Article  ADS  Google Scholar 

  30. This theory is similar to one proposed by K. Takayanagi: J. Phys. Soc. Japan 45, 976 (1978)

    Article  ADS  Google Scholar 

  31. D. R. Bates: Proc. Roy. Soc. London A 384, 289 (1982)

    Article  ADS  Google Scholar 

  32. W. J. Chesnavich, T. Su, M. T. Bowers: J. Chem. Phys. 72, 2641

    Google Scholar 

  33. B. R. Rowe: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 135.

    Chapter  Google Scholar 

  34. Some higher temperature experiments have been discussed by N. G. Adams, D. Smith, D. C. Clary: Astrophys. J. Letters 296, L31(1985)

    Article  ADS  Google Scholar 

  35. E. Herbst, N. G. Adams, D. Smith: Astrophys. J. 269, 329 (1983).

    Article  ADS  Google Scholar 

  36. V. G. Anicich, W. T. Huntress: Astrophys. J. Suppl. Ser. 62, 553 (1986)

    Article  ADS  Google Scholar 

  37. E. Herbst, W. Klemperer: Astrophys. J. 185, 505 (1973)

    Article  ADS  Google Scholar 

  38. D. R. Bates: Phys. Rev. 78, 492 (1950)

    Article  ADS  Google Scholar 

  39. See, for example, N. G. Adams, D. Smith, E. Alge: J. Chem. Phys. 81, 1778 (1984) and references therein.

    Article  ADS  Google Scholar 

  40. D. Smith, N. G. Adams: Astrophys. J. Letters 284 L13 (1984)

    Article  ADS  Google Scholar 

  41. E. Herbst: Astrophys. J. 222, 508 (1978)

    Article  ADS  Google Scholar 

  42. S. Green, E. Herbst: Astrophys. J. 229, 121 (1979)

    Article  ADS  Google Scholar 

  43. D. R. Bates: In Recent Studies in Atomic and Molecular Processes, ed. A. E. Kingston (Plenum, New York, 1987), p. 1.

    Google Scholar 

  44. A shortened version can be found in D. R. Bates: Astrophys. J. Letters 306, L45 (1986).

    Article  ADS  Google Scholar 

  45. D. R. Bates, E. Herbst: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 41

    Chapter  Google Scholar 

  46. E. Herbst: to appear in the proceedings of a conference on Dissociative Recombination Reactions held in Lake Louise, Canada, June 1988. Preprints available from the author.

    Google Scholar 

  47. D. Smith: presentation at conference mentioned in [43]

    Google Scholar 

  48. S. Lepp, A. Dalgarno: Astrophys. J. 324, 553 (1988)

    Article  ADS  Google Scholar 

  49. K. S. De Boer, M. A. Jura, J. M. Shull: In Accomplishments of the IUE, ed. Y. Kondo (Reidel, Dordrecht, 1987), p.485

    Google Scholar 

  50. T. E. Graedel, W. D. Langer, M. A. Frerking: Astrophys. J. Suppl. Ser. 48, 321 (1982)

    Article  ADS  Google Scholar 

  51. G. F. Mitchell, J. L. Ginsburg, P. J. Kuntz: Astrophys. J. Suppl. Ser. 38, 39 (1978)

    Article  ADS  Google Scholar 

  52. H. Gerola, A. E. Glassgold: Astrophys. J. Suppl. Ser. 37, 1 (1978)

    Article  ADS  Google Scholar 

  53. E. R. Iglesias, J. Silk: Astrophys. J. 226, 851 (1978)

    Article  ADS  Google Scholar 

  54. T. W. Hartquist, M. Oppenheimer, A. Dalgarno: Astrophys. J. 236, 182 (1980)

    Article  ADS  Google Scholar 

  55. S. S. Prasad, W. T. Huntress: Astrophys. J. Suppl. Ser. 43, 1 (1980).

    Article  ADS  Google Scholar 

  56. See also S. S. Prasad, W. T. Huntress: Astrophys. J. 239, 151 (1980)

    Article  ADS  Google Scholar 

  57. E. Herbst: Astrophys. J. Suppl. Ser. 53, 41 (1983).

    Article  ADS  Google Scholar 

  58. An update is provided by E. Herbst, N. G. Adams, D. Smith: Astrophys. J. 285, 618 (1984).

    Article  ADS  Google Scholar 

  59. G. F. Mitchell: Monthly Notices Roy. Astron. Soc. 205, 765 (1983)

    ADS  Google Scholar 

  60. G. F. Mitchell: Astrophys. J. Suppl. Ser. 54, 81 (1984)

    Article  ADS  Google Scholar 

  61. C. M. Leung, E. Herbst, W. F. Huebner: Astrophys. J. Suppl. Ser. 56, 231 (1984)

    Article  ADS  Google Scholar 

  62. T. J. Millar, A. Freeman: Monthly Notices Roy. Astron. Soc. 207, 405 (1984).

    ADS  Google Scholar 

  63. See also T. J. Millar, A. Freeman: Monthly Notices Roy. Astron. Soc. 207, 425 (1984).

    ADS  Google Scholar 

  64. W. D. Langer, T. E. Graedel, M. A. Frerking, P. B. Armentrout: Astrophys. J. 277, 581 (1984)

    Article  ADS  Google Scholar 

  65. T. J. Millar, L. A. M. Nejad: Monthly Notices Roy. Astron. Soc. 217, 507 (1985)

    ADS  Google Scholar 

  66. S. P. Tarafdar, S. S. Prasad, W. T. Huntress, K. R. Villere, D. C. Black: Astrophys. J. 289, 220 (1985)

    Article  ADS  Google Scholar 

  67. E. Herbst, C. M. Leung: Astrophys. J. 310, 378 (1986)

    Article  ADS  Google Scholar 

  68. R. D. Brown, E. H. N. Rice: Monthly Notices Roy. Astron. Soc. 223, 429 (1986).

    ADS  Google Scholar 

  69. See also R. D. Brown, E. H. N. Rice: Monthly Notices Roy. Astron. Soc. 223, 405 (1986).

    ADS  Google Scholar 

  70. T. J. Millar, C. M. Leung, E. Herbst: Astron. Astrophys. 183, 109 (1987)

    ADS  Google Scholar 

  71. T. J. Millar, D. J. DeFrees, A. D. McLean, E. Herbst: Astron. Astrophys. 194, 250 (1988).

    ADS  Google Scholar 

  72. E. Herbst, C. M. Leung: submitted to Astrophys. J. Suppl. Ser. Preprints available from the authors.

    Google Scholar 

  73. R. Gredel, S. Lepp, A. Dalgarno, E. Herbst: submitted to Astrophys. J. Preprints available from the authors.

    Google Scholar 

  74. S. B. Charnley, J. E. Dyson, T. W. Hartquist, D. A. Williams: submitted to Monthly Notices Roy. Astron. Soc.

    Google Scholar 

  75. P. D. Brown, S. B. Charnley, T. J. Millar: Monthly Notices Roy. Astron. Soc. 231, 409 (1988)

    ADS  Google Scholar 

  76. E. Herbst: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 239

    Chapter  Google Scholar 

  77. R. Gredel, S. Lepp, A. Dalgarno: Astrophys. J. Letters 323, L137 (1987)

    Article  ADS  Google Scholar 

  78. S. S. Prasad, S. P. Tarafdar: Astrophys. J. 267, 403 (1983)

    Article  ADS  Google Scholar 

  79. D. K. Böhme: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), P. XXX.

    Google Scholar 

  80. A. Dalgarno: In Recent Studies in Atomic and Molecular Processes, ed. A. E. Kingston (Plenum, New York, 1987), p. 51

    Google Scholar 

  81. E. Herbst: Astrophys. J. 252, 810 (1982)

    Article  ADS  Google Scholar 

  82. J. H. Black, A. Dalgarno: Astrophys. J. Suppl. Ser. 34, 405 (1977)

    Article  ADS  Google Scholar 

  83. M. Elitzur, W. D. Watson: Astrophys. J. 236, 172 (1980)

    Article  ADS  Google Scholar 

  84. E. Herbst, D. R. Bates: Astrophys. J. 329, 410 (1988)

    Article  ADS  Google Scholar 

  85. N. G. Adams, D. Smith: Astrophys. J. Letters 317, L25 (1987)

    Article  ADS  Google Scholar 

  86. G. F. Mitchell, W. T. Huntress: Nature 278, 722 (1979)

    Article  ADS  Google Scholar 

  87. D. K. Bohme, S. Wlodek, A. B. Raksit: Can. J. Phys. 65, 2057 (1987)

    Google Scholar 

  88. W. Federer, H. Villinger, W. Lindinger, E. E. Ferguson: Chemical Phys. Letters 123, 12 (1986)

    Article  ADS  Google Scholar 

  89. E. Herbst: Astrophys. J. 313, 867 (1987)

    Article  ADS  Google Scholar 

  90. F. Combes, M. Gerin, A. Wootten, G. Wlodarczak, F. Clausset, P. J. Encrenaz: Astron. Astrophys. 180, L13 (1987)

    ADS  Google Scholar 

  91. J. H. Black, A. Dalgarno: Astrophys. J. Letters 184, L101 (1973)

    Article  ADS  Google Scholar 

  92. E. Herbst, N. G. Adams, D. Smith, D. J. DeFrees: Astrophys. J. 312, 351 (1987)

    Article  ADS  Google Scholar 

  93. E. Herbst: Astron. Astrophys. 111, 76 (1982)

    ADS  Google Scholar 

  94. W. D. Watson: In CNO Processes in Astrophysics, ed. J. Audouze (Reidel, Dordrecht, 1977), p. 105

    Chapter  Google Scholar 

  95. M. Guélin, W. D. Langer, R. L. Snell, A. Wootten: Astrophys. J. Letters 217, L165 (1977)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1988 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Herbst, E. (1988). Interstellar Molecular Formation Processes. In: Klare, G. (eds) Cosmic Chemistry. Reviews in Modern Astronomy, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74188-3_5

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-74188-3_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-74190-6

  • Online ISBN: 978-3-642-74188-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics