Abstract
Visible radiation from galaxies is dominated by hot stellar material. However, the existence of cooler, interstellar phases can be inferred from the absorption and scattering of visible radiation as well as from emission at longer wavelengths. In particular, radioastronomical and, to a lesser extent, infrared observations have helped to uncover the existence of vast interstellar clouds of gaseous and particulate matter, with most of the matter (≈ 99%) in the gaseous form and ≈ 1% in the form of dust-like particles [1]. In the denser interstellar clouds, approximately eighty different molecular species and numerous isotopic variants have been discovered in the gas phase. These molecules range in complexity from diatomics to a thirteen-atom species, are mainly organic (carbon-containing) in nature, and comprise a variety of standard and bizarre species [1,2]. Detected by narrow line spectra, the gaseous molecules are exceedingly well characterized and their observation leads to a detailed knowledge of the chemical and physical state of the gas in dense interstellar clouds [2, 3]. For example, gas temperatures are in the range 10 – 70 K and total gas densities are on the order of 104 cm-3. Since dense clouds can range in extent up to ≈ 100 pc, cloud masses can range up to 106 solar masses. The material is slowly collapsing to form stars. Material in star-forming regions is typically denser and warmer than ambient material and can be studied separately from the ambient material either interferometrically or via differences in line profiles [4]. The particulate phase of dense clouds consists of small (0.1 μm) dust particles that contain refractory cores of material such as silicates covered mantles deposited from the gas phase [5].
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References
A recent introduction to the subject can be found in the collection of papers entitled Astrochemistry, eds. M. S. Vardya and S. P. Tarafdar, Proceedings of the 120th Symposium of the I. A. U. (Reidel, Dordrecht 1987). A somewhat older volume is Molecular Astrophysics, eds. G. H. F. Diercksen, W. F. Huebner, and P. W. Langhoff, NATO ISI Series Vol. 157 (Reidel, Dordrecht, 1985). Finally, the physical and chemical processes occurring in clouds are reviewed in the volume Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987).
G. Winnewisser and E. Herbst: Topics in Current Chemistry 139, 119 (1987)
W. M. Irvine, P. F. Goldsmith, and Å Hjalmarson: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987) p. 561.
G. A. Blake, E. C. Sutton, C. R. Masson, T. G. Phillips: Astrophys. J. 315, 621 (1987)
See also N. Z. Scoville, D. B. Sanders, A. I. Sargent, B. T. Soifer, S. L. Scott, K. Y. Lo: Astrophysical J. Letters 311, L47 (1986)
A. G. G. M. Tielens, L. J. Allamandola: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987), p. 397
L. J. Allamandola, A. G. G. M. Tielens, J. R. Barker: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987), p. 471
W. Gordy, R. L. Cook: Microwave Molecular Spectra, Techniques of Chemistry, Vol. XVIII (Wiley, New York, 1984)
A. Betz: In Astrochemistry, eds. M. S. Vardya and S. P. Tarafdar (Reidel, Dordrecht, 1987), p. 327
See, for example, T. Anderson, E. Herbst, and F. C. De Lucia: Astrophysical J. Suppl. Ser. 64, 703 (1987) and references therein.
T. J. Millar, A. Bennett, E. Herbst: submitted to Astrophys. J. U.E. Herbst, C. M. Leung: Monthly Notices Roy. Astron. Soc. 222, 689
C. G. Seab: In Interstellar Processes, eds. D. J. Hollenbach and H. A. Thronson, Jr. (Reidel, Dordrecht, 1987), p. 491
A. Omont: Astron. Astrophys. 164, 159 (1986)
R. J. Gould, E. E. Salpeter: Astrophys. J. 138, 393 (1963)
A. Dalgarno, R. McCray: Astrophys. J. 181, 95 (1973)
W. D. Watson: Rev. Mod. Phys. 48, 513 (1976)
M. Allen, G. W. Robinson: Astrophys. J. 212, 396 (1977)
P. Aannestad: Astrophys. J. Suppl. Ser. 25, 223 (1973)
L. B. d’Hendecourt, L. J. Allamandola, J. M. Greenberg: Astron. Astrophys. 152, 130 (1985)
D. A. Williams, T. W. Hartquist: Monthly Notices Roy. Astron. Soc. 210, 141 (1984)
A. Léger, M. Jura, A. Omont: Astron. Astrophys. 144, 147 (1985)
L. B. d’Hendecourt, L. J. Allamandola, F. Baas, J. M. Greenberg: Astron. Astrophys. 109, L 12 (1982)
A. G. G. M. Tielens, W. Hagen: Astron. Astrophys. 114, 245 (1982).
See, for example, N. G. Adams, D. Smith: Chem. Phys. Letters 79, 563 (1981)
A review of the various techniques used is given by D. R. Bates, E. Herbst: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 17
E. Herbst, D. J. DeFrees, A. D. McLean: Astrophys. J. 321, 898 (1987)
See any book on elementary gas phase reaction kinetics. A useful volume is R. D. Levine, R. B. Bernstein: Molecular Reaction Dynamics (Oxford University Press, 1974)
J. B. Marquette, B. R. Rowe, G. Dupeyrat, G. Poissant: In Astrochemistry, eds. M. S. Vardya and S. P. Tarafdar (Reidel, Dordrecht, 1987), p.19
D. C. Clary: Molec. Phys. 54, 605 (1985)
This theory is similar to one proposed by K. Takayanagi: J. Phys. Soc. Japan 45, 976 (1978)
D. R. Bates: Proc. Roy. Soc. London A 384, 289 (1982)
W. J. Chesnavich, T. Su, M. T. Bowers: J. Chem. Phys. 72, 2641
B. R. Rowe: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 135.
Some higher temperature experiments have been discussed by N. G. Adams, D. Smith, D. C. Clary: Astrophys. J. Letters 296, L31(1985)
E. Herbst, N. G. Adams, D. Smith: Astrophys. J. 269, 329 (1983).
V. G. Anicich, W. T. Huntress: Astrophys. J. Suppl. Ser. 62, 553 (1986)
E. Herbst, W. Klemperer: Astrophys. J. 185, 505 (1973)
D. R. Bates: Phys. Rev. 78, 492 (1950)
See, for example, N. G. Adams, D. Smith, E. Alge: J. Chem. Phys. 81, 1778 (1984) and references therein.
D. Smith, N. G. Adams: Astrophys. J. Letters 284 L13 (1984)
E. Herbst: Astrophys. J. 222, 508 (1978)
S. Green, E. Herbst: Astrophys. J. 229, 121 (1979)
D. R. Bates: In Recent Studies in Atomic and Molecular Processes, ed. A. E. Kingston (Plenum, New York, 1987), p. 1.
A shortened version can be found in D. R. Bates: Astrophys. J. Letters 306, L45 (1986).
D. R. Bates, E. Herbst: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 41
E. Herbst: to appear in the proceedings of a conference on Dissociative Recombination Reactions held in Lake Louise, Canada, June 1988. Preprints available from the author.
D. Smith: presentation at conference mentioned in [43]
S. Lepp, A. Dalgarno: Astrophys. J. 324, 553 (1988)
K. S. De Boer, M. A. Jura, J. M. Shull: In Accomplishments of the IUE, ed. Y. Kondo (Reidel, Dordrecht, 1987), p.485
T. E. Graedel, W. D. Langer, M. A. Frerking: Astrophys. J. Suppl. Ser. 48, 321 (1982)
G. F. Mitchell, J. L. Ginsburg, P. J. Kuntz: Astrophys. J. Suppl. Ser. 38, 39 (1978)
H. Gerola, A. E. Glassgold: Astrophys. J. Suppl. Ser. 37, 1 (1978)
E. R. Iglesias, J. Silk: Astrophys. J. 226, 851 (1978)
T. W. Hartquist, M. Oppenheimer, A. Dalgarno: Astrophys. J. 236, 182 (1980)
S. S. Prasad, W. T. Huntress: Astrophys. J. Suppl. Ser. 43, 1 (1980).
See also S. S. Prasad, W. T. Huntress: Astrophys. J. 239, 151 (1980)
E. Herbst: Astrophys. J. Suppl. Ser. 53, 41 (1983).
An update is provided by E. Herbst, N. G. Adams, D. Smith: Astrophys. J. 285, 618 (1984).
G. F. Mitchell: Monthly Notices Roy. Astron. Soc. 205, 765 (1983)
G. F. Mitchell: Astrophys. J. Suppl. Ser. 54, 81 (1984)
C. M. Leung, E. Herbst, W. F. Huebner: Astrophys. J. Suppl. Ser. 56, 231 (1984)
T. J. Millar, A. Freeman: Monthly Notices Roy. Astron. Soc. 207, 405 (1984).
See also T. J. Millar, A. Freeman: Monthly Notices Roy. Astron. Soc. 207, 425 (1984).
W. D. Langer, T. E. Graedel, M. A. Frerking, P. B. Armentrout: Astrophys. J. 277, 581 (1984)
T. J. Millar, L. A. M. Nejad: Monthly Notices Roy. Astron. Soc. 217, 507 (1985)
S. P. Tarafdar, S. S. Prasad, W. T. Huntress, K. R. Villere, D. C. Black: Astrophys. J. 289, 220 (1985)
E. Herbst, C. M. Leung: Astrophys. J. 310, 378 (1986)
R. D. Brown, E. H. N. Rice: Monthly Notices Roy. Astron. Soc. 223, 429 (1986).
See also R. D. Brown, E. H. N. Rice: Monthly Notices Roy. Astron. Soc. 223, 405 (1986).
T. J. Millar, C. M. Leung, E. Herbst: Astron. Astrophys. 183, 109 (1987)
T. J. Millar, D. J. DeFrees, A. D. McLean, E. Herbst: Astron. Astrophys. 194, 250 (1988).
E. Herbst, C. M. Leung: submitted to Astrophys. J. Suppl. Ser. Preprints available from the authors.
R. Gredel, S. Lepp, A. Dalgarno, E. Herbst: submitted to Astrophys. J. Preprints available from the authors.
S. B. Charnley, J. E. Dyson, T. W. Hartquist, D. A. Williams: submitted to Monthly Notices Roy. Astron. Soc.
P. D. Brown, S. B. Charnley, T. J. Millar: Monthly Notices Roy. Astron. Soc. 231, 409 (1988)
E. Herbst: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), p. 239
R. Gredel, S. Lepp, A. Dalgarno: Astrophys. J. Letters 323, L137 (1987)
S. S. Prasad, S. P. Tarafdar: Astrophys. J. 267, 403 (1983)
D. K. Böhme: In Rate Coefficients in Astrochemistry, eds. T. J. Millar and D. A. Williams (Reidel, Dordrecht, 1988), P. XXX.
A. Dalgarno: In Recent Studies in Atomic and Molecular Processes, ed. A. E. Kingston (Plenum, New York, 1987), p. 51
E. Herbst: Astrophys. J. 252, 810 (1982)
J. H. Black, A. Dalgarno: Astrophys. J. Suppl. Ser. 34, 405 (1977)
M. Elitzur, W. D. Watson: Astrophys. J. 236, 172 (1980)
E. Herbst, D. R. Bates: Astrophys. J. 329, 410 (1988)
N. G. Adams, D. Smith: Astrophys. J. Letters 317, L25 (1987)
G. F. Mitchell, W. T. Huntress: Nature 278, 722 (1979)
D. K. Bohme, S. Wlodek, A. B. Raksit: Can. J. Phys. 65, 2057 (1987)
W. Federer, H. Villinger, W. Lindinger, E. E. Ferguson: Chemical Phys. Letters 123, 12 (1986)
E. Herbst: Astrophys. J. 313, 867 (1987)
F. Combes, M. Gerin, A. Wootten, G. Wlodarczak, F. Clausset, P. J. Encrenaz: Astron. Astrophys. 180, L13 (1987)
J. H. Black, A. Dalgarno: Astrophys. J. Letters 184, L101 (1973)
E. Herbst, N. G. Adams, D. Smith, D. J. DeFrees: Astrophys. J. 312, 351 (1987)
E. Herbst: Astron. Astrophys. 111, 76 (1982)
W. D. Watson: In CNO Processes in Astrophysics, ed. J. Audouze (Reidel, Dordrecht, 1977), p. 105
M. Guélin, W. D. Langer, R. L. Snell, A. Wootten: Astrophys. J. Letters 217, L165 (1977)
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Herbst, E. (1988). Interstellar Molecular Formation Processes. In: Klare, G. (eds) Cosmic Chemistry. Reviews in Modern Astronomy, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74188-3_5
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DOI: https://doi.org/10.1007/978-3-642-74188-3_5
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