Abstract
A high flux of positively and negatively charged metal cluster ions was produced in a sputtering arrangement, energy-analyzed and mass-filtered. The resulting mono- dispersed cluster ion beam was introduced into a quadrupole drift tube, where it interacted with a laser beam or reacted with an introduced gas. All inelastic scattering events were recorded with a subsequent quadrupole mass filter. The results exhibited a high sensitivity of positively and negatively charged silver clusters Ag ± n (n≤16) with respect to photofragmentation. Ion-molecule reactions of nickel clusters with carbon monoxide allowed to synthesize very interesting organometallic and carbonyl compounds, and the maximum number of ligands provided interesting structural indications.
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© 1986 Springer-Verlag Berlin Heidelberg
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Fayet, P., Wöste, L. (1986). Experiments on Size-Selected Metal Cluster Ions in a Triple Quadrupole Arrangement. In: Träger, F., zu Putlitz, G. (eds) Metal Clusters. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71571-6_12
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DOI: https://doi.org/10.1007/978-3-642-71571-6_12
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