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Abstract

The kraft process accounts for 85% of the total pulp production in the United States. Bleached kraft pulp is a relatively high-value component of the total production of kraft paper. Kraft pulping removes most of the lignin and dissolves and degrades hemicelluloses without severely damaging cellulose. The kraft process results in excellent pulp from a wide variety of wood species. Unfortunately, kraft pulping also generates large quantities of chromophores. Chromophores are composed of residual lignin and carbohydrate degradation products. They are hard to extract because they are physically entrapped in and covalently bound to the carbohydrate moieties in the pulp matrix. Manufacturers use elemental chlorine and chlorine dioxide to bleach the chromophores and then they extract them, along with the residual lignin to make white pulp. Because of consumer resistance and environmental regulation of chlorine in bleaching, pulp makers are turning to oxygen, ozone, and peroxide bleaching, even though these may be more expensive and less effective than chlorine. One new technology has evolved to decrease the use of chlorine for bleaching, and that is the treatment of the pulp with xylanase enzyme. The use of xylanase enzymes to enhance the bleaching of the pulp was first reported in 1986.1 The Finnish forest companies were the first in the world to start millscale trials in 1988.

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References

  1. Viikari L, Ranua M, Kantelinen A, Sundquist J, Linko M: Bleaching with enzymes. In: Proc. 3rd Int. Conference on Biotechnology in the Pulp and Paper Industry* Stockholm, Sweden, 1986; 67–69.

    Google Scholar 

  2. Tolan JS, Olson D, Dines RE: Survey of mill usage of xylanase. In: Enzymes for pulp and paper processing. Jeffries TW and Viikari L(eds.). ACS Symp Ser 1996; 655: 25–35.

    Google Scholar 

  3. Turner JC, Skerker PS, Burns BJ, Howard JC, Alonso MA, Andres JL: Bleaching with enzymes instead of chlorine: Mill trials. Tappi J. 1992; 75(12) 83–89.

    CAS  Google Scholar 

  4. Jean P, Hamilton J, Senior DJ: Mill trial experiences with xylanase: AOX and chemical reductions. Preprints 80th Annual Meeting Technical Section, Montreal, Canada, Feb. 1-2, 1994; A229–233.

    Google Scholar 

  5. Scott BP, Young F, Paice MG: Mill scale enzyme treatment of a softwood kraft pulp prior to bleaching. Pulp Pap Can 1993; 94(3): 57–61.

    CAS  Google Scholar 

  6. Yee Y, Tolan JS: Three years experience running enzymes continuously to enhance bleaching at Weyerhaeuser Prince Albert. Pulp Pap Can 1997; 98(10): T370–T375.

    Google Scholar 

  7. Bajpai P, Bajpai PK: Realities and trends in enzymatic prebleaching of kraft pulp. Adv Biochem Eng / Biotechnol. edited by T. Scheper, Springer, Berlin Heidelberg New York, 1997; 56: 1–31.

    Google Scholar 

  8. Farrell RL, Viikari L, Senior DJ: Enzyme treatment of pulp. In: Pulp bleaching (Dence CW, Reeve DW. eds.) Tappi Press, Atlanta, 1996; 363–383.

    Google Scholar 

  9. Viikari L, Kantelinen A, Sundquist J, Linko M: Xylanases in bleaching: from an idea to industry. FEMS Microbiol Rev 1994; 13: 335–350.

    Article  CAS  Google Scholar 

  10. Suurnakki A, Tenkanen M, Buchert J, Viikari L: Hemicellulases in the bleaching of chemical pulps. Adv Biochem Eng / Biotechnol. edited byT. Scheper, Springer, Berlin Heidelberg New York, 1997; 57: 261–287.

    Google Scholar 

  11. Tolan JS, Guenette M: Using enzymes in pulp bleaching: mill applications. Adv Biochem Eng / Biotechnol. Springer, Berlin Heidelberg New York, 1997; 57: 288–310.

    Google Scholar 

  12. Bajpai P, Bajpai PK: Biobleaching of kraft pulp. Process Biochem 1992; 27: 319–325.

    Article  CAS  Google Scholar 

  13. Senior DJ, Hamilton J: Reduction in chlorine use during bleaching of kraft pulp following xylanase treatment. Tappi J 1992; 75(11) 125–130.

    CAS  Google Scholar 

  14. Senior DJ, Hamilton J: Bleaching with xylanases brings biotechnology to reality. Pulp Pap 1992; 66(9) 111–114.

    CAS  Google Scholar 

  15. Tolan JS, Canovas RV: The use of enzymes to decrease the chlorine requirements in pulp bleaching. Pulp Pap Can 1992; 93(5) 39–42.

    CAS  Google Scholar 

  16. Senior DJ, Hamilton J: Xylanase treatment for the bleaching of softwood kraft pulps: the effect of chlorine dioxide substitution. Tappi J 1993; 76(8) 200–206.

    CAS  Google Scholar 

  17. Enso-Gutzeit OY: Procedure for the bleaching of pulp. EP 0383>999,1990.

    Google Scholar 

  18. Werthemann D: Prebleaching of Pinus radiatapulp using enzymes - technology to reduce AOX. Jpn J Pap Technol 1993; 10: 15–17.

    Google Scholar 

  19. Skerker PS, Labbauf MM, Farrell RL, Beerwan N, McCarthy P: Practical bleaching using xylanases: laboratory and mill experience with Cartazyme HS-10 in reduced and chlorinefree bleach sequences. Presented in Tappi Pulping Conference Boston, MA, 1992.

    Google Scholar 

  20. Yang JL, Lou G, Eriksson KE: The impact of xylanases on bleaching of kraft pulps.Tappi J 1992; 75(12) 95–101.

    CAS  Google Scholar 

  21. Allison RW, Clark TA, Wrathall SH: Pretreatment of radiata pine kraft pulp with a thermophillic enzyme. Part I. Effect on conventional bleaching. Appita 1993; 46(4) 269–273.

    Google Scholar 

  22. Allison RW, Clark TA, Wrathall SH: Pretreatment of radiata pine kraft pulp with a thermophillic enzyme. Part II. Effect on oxygen, ozone and chlorine dioxide bleaching. Appita 1993; 46(5) 349–353.

    Google Scholar 

  23. Bajpai P, Bhardwaj NK, Bajpai PK, Jauhari MB: The impact of xylanases in bleaching of eucalyptus kraft pulp. J Biotechnol 1994; 36(1) 1–6.

    Article  Google Scholar 

  24. Bajpai P, Bhardwaj NK, Maheshwari S, Bajpai PK: Use of xylanase in bleaching of eucalypt kraft pulp. Appita 1993; 46(4) 274–276.

    Google Scholar 

  25. Senior DJ, Hamilton J: Use of xylanase to decrease the formation of AOX in kraft pulp bleaching. Proc of the Environmental Conference 1991 of the Technical Section, Canadian Pulp and Paper Association, Quebec, Canada, October 8–10,1991; pp 63–67.

    Google Scholar 

  26. Senior DJ, Hamilton J: Use of xylanase to decrease the formation of AOX in kraft pulp bleaching. J Pulp Pap Sci 1992; 18(5): J165–168.

    Google Scholar 

  27. Dunlop N, Gronberg V: Recent developments in the application of xylanase enzymes in ECF and TCF bleaching. Preprints 80th Annual Meeting Technical Section, Montreal, Canada, Feb 1–2,1994; A191–A196.

    Google Scholar 

  28. Sandstrom AS: Total chlorine-free bleaching using enzymes. Sven Papperstidn 1993; 7:40–42.

    Google Scholar 

  29. Anonymous: No matter what you call it, chlorine-free bleaching is here to stay. Pulp Paper Can 1992; 93(5): 22–27.

    Google Scholar 

  30. Young J: Enzone bleaching, enzynk deinking advance to pilot plant trial. Pulp Pap., Nov 1994; 81–82.

    Google Scholar 

  31. Lavielle P: Three large-scale uses of xylanases in kraft pulp bleaching. Proceedings of Pan- Pacific Pulp and Paper Technology, Tokyo, Japan, Sept 8-10,1992, Part A, pp 59–64.

    Google Scholar 

  32. Anonymous: Breakthrough in Finland - chlorine-free bleaching of sulphate pulp. Skogindustri 1991; 45(10) 10.

    Google Scholar 

  33. Worster H: Canadian mills begin chlorine-free bleaching as TCF pulp market grows.Pulp Paper 1993; 67(1) 117.

    Google Scholar 

  34. Anonymous: Development of bleaching technology in Finland. Paper Puu 1992; 74(2) 102–106.

    Google Scholar 

  35. Berry RM, Fleming BI, Voss RH, Luthe CE, Wrist PE: Towards preventing formation of dioxins during chemical pulp bleaching. Pulp Pap Can 1989; 90(8): T279–289.

    Google Scholar 

  36. Pake MG, Bernier R Jr, Jurasek L: Viscosity enhancing bleaching of hardwood kraft pulp with xylanase from a cloned gene. Biotechnol Bioeng 1988; 32: 235–239.

    Article  Google Scholar 

  37. Kantelinen A, Hortling B, Sundquist J, Linko M, Viikari L: Proposed mechanism of the enzymatic bleaching of kraft pulp with xylanases. Holzforschung 1993; 47: 318–324.

    Article  CAS  Google Scholar 

  38. Yllner S, Ostberg K, Stockmann L: A study of the removal of the constituents of pine wood in the sulphate process using a continuous liquor flow method. Sven Papperstidn 1957; 60: 795–802.

    CAS  Google Scholar 

  39. Paice MG, Gurnagul N, Page DH, Jurasek L: Mechanism of hemicellulose directed prebleaching of kraft pulp. Enzyme Microb Technol 1992; 14: 272–276.

    Article  CAS  Google Scholar 

  40. Skjold-Jorgensen S, Munk N, Pederson LS: Recent progress withIn the application of xylanases for boosting the bleachability of kraft pulp. Inr Kuwahara M, Shimada M (eds) Biotechnology in the pulp and paper industry. Uni Publishers, Tokyo, Japan, 1992; pp 93–99.

    Google Scholar 

  41. Tolan JS: Mill implementation of enzyme treatment to enhance bleaching. Proc 78th CPPA Annual Meeting, Montreal Canada, Jan 28–29,1992; pp A163–168.

    Google Scholar 

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© 1999 Springer-Verlag Berlin Heidelberg

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Bajpai, P., Bajpai, P.K., Kondo, R. (1999). Pulp Bleaching with Xylanases. In: Biotechnology for Environmental Protection in the Pulp and Paper Industry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-60136-1_4

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  • DOI: https://doi.org/10.1007/978-3-642-60136-1_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64271-5

  • Online ISBN: 978-3-642-60136-1

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