Abstract
Optical study of 3d transition metal oxides with perovskite-type structure has revealed the variation of their electronic structure with the 3d element M. The low-energy feature is governed by electronic states in the M-O network. The overall trend of the gap variation agrees well with the Zaanen-Sawatzky-Allen framework. We can also estimate the Hund coupling constant and ligand field effect from the optical spectra.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. Zaanen, G. A. Sawatzky, and J. W. Allen, Phys. Rev. Lett. 55 418 (1985).
J. B. Torrance, P. Lacorre, C. Asavaroengchai, and R. M. Metzger, Physica C 182, 351 (1991).
T. Arima, Y. Tokura, and J. B. Torrance, Phys. Rev. B 48, 17006 (1993).
R. G. Egdell, M. R. Harrison, M. D. Hill, L. Porte, and G. Wall, J. Phys. C: Solid State Phys. 17, 2889 (1984).
S. Kimura, T. Nanba, M. Tomikwa, S. Kunii, and T. Kasuya, Phys. Rev. B 46, 12196 (1992).
S. Uchida, T. Ido, H. Takagi, T. Arima, Y. Tokura, and S. Tajima, Phys. Rev. B 43, 7942 (1991).
Y. Tokura, S. Koshihara, T. Arima, H. Takagi, S. Ishibashi, T. Ido, and S. Uchida, Phys. Rev. B 41, 11657 (1990).
A. Fujimori, I. Hase, H. Namatame, Y. Fujishima, Y. Tokura, H. Eisaki, S. Uchida, K. Takegahara, and F. M. F. de Groot, Phys. Rev. Lett. 69, 1796 (1992).
A. Fujimori, I. Hase, H. Namatame, Y. Fujishima, Y. Tokura, M. Abbate, F. M. F. de Groot, M. T. Czyzyk, J. C. Fuggle, O. Strebel, F. Lopez, M. Domke, and G. Kaindl, Phys. Rev. B 46, 9841 (1992).
T. Saito, A. E. Bocquet, T. Mizokawa, H. Namatame, A. Fujimori, M. Abbate, Y. Takeda, and M. Takano, Jpn. J. Appl. Phys. 32,Suppl. 3, 258 (1993).
A. Chainani, M. Mathew, and D. D. Sarma, Phys. Rev. B 46, 9976 (1992).
V. G. Bhide, D. S. Rajoria, G. R. Rao, and C. N. R. Rao, Phys. Rev. B 6, 1021 (1972).
J. B. Torrance, P. Lacorre, A. I. Nazzal, E. J. Ansaldo, Ch. Niedermayer, Phys. Rev. B 45, 8209 (1992).
D. A. Crandles, T. Timusk, J. D. Garrett, and J. E. Greedan, Physica C 201, 407 (1992).
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Arima, T., Tokura, Y. (1995). Systematics of Optical Gaps in Perovskite-Type 3d Transition Metal Oxides. In: Spectroscopy of Mott Insulators and Correlated Metals. Springer Series in Solid-State Sciences, vol 119. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-57834-2_13
Download citation
DOI: https://doi.org/10.1007/978-3-642-57834-2_13
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-63371-3
Online ISBN: 978-3-642-57834-2
eBook Packages: Springer Book Archive