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Elucidation of the Transfer Mechanism in Ion-Molecule Reactions by ICR

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Ion Cyclotron Resonance Spectrometry II

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 31))

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Abstract

Ion cyclotron double-resonance (ICDR) techniques have been widely used to determine the pathways of ion-molecule reactions [1]. Methods using isotopi-cally labelled reactants, mainly hydrogen isotopes, have also been previously applied to studies of reaction mechanisms [2]. These methods are not always straight-forward. In this work the mechanisms of some positive and negative ion-molecule reactions were studied employing ICDR techniques in combination with isotope labelling.

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References

  1. T.A. Lehman and M.M. Bursey, Ion Cyclotron Resonance Spectrometry, Wiley, New York, 1976.

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  2. See for example, J.M.S. Hem’s and M.K. Tripodi, J. Chem. Phys., 61 (1974) 4863.

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  5. For increased sensitivity care should be taken to avoid overlap of mass/ charge between the chosen product ion and various reactant ions and other fragment ions present.

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Author notes

  1. Ze’ev Karpas

    Present address: Nuclear Research Center Negev, Beer Sheva, P.O. Box 9001, Israel

Authors and Affiliations

  1. Isotope Department, The Weizmann Institute of Science, 76100, Rehovot, Israel

    Itzhak Dotan, Ze’ev Karpas & Fritz S. Klein

Authors
  1. Itzhak Dotan
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  2. Ze’ev Karpas
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  3. Fritz S. Klein
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© 1982 Springer-Verlag Berlin Heidelberg

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Dotan, I., Karpas, Z., Klein, F.S. (1982). Elucidation of the Transfer Mechanism in Ion-Molecule Reactions by ICR. In: Ion Cyclotron Resonance Spectrometry II. Lecture Notes in Chemistry, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50207-1_7

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  • DOI: https://doi.org/10.1007/978-3-642-50207-1_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-11957-9

  • Online ISBN: 978-3-642-50207-1

  • eBook Packages: Springer Book Archive

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