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Satellite Transition Spectroscopy of Quadrupolar Nuclei

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Solid-State NMR II

Part of the book series: NMR Basic Principles and Progress ((NMR,volume 31))

Abstract

Magic-angle sample spinning (MAS) has had a major impact on several aspects of the development of NMR and its application to solid state physics and chemistry. MAS was first used to average out dipolar broadening in 23Na NMR of monocrystalline sodium chloride, as published in 1958 by Andrew, Bradbury and Eades [1]. After that many more examples were published in the early days including applications to other nuclei such as 1H [2] and 31P [3]. However, successful applications of MAS required either a substantial motional narrowing in the case of strong homonuclear dipole broadening, or a dominant inhomogeneous line broadening interaction such as the chemical shift anisotropy.

During the last five years the availability of fast MAS probes lead to a major progress in high resolution NMR of quadrupolar nuclei. It is now possible to measure the quadrupole interaction of polycrystalline solids precisely using the satellite transitions. But furthermore, a considerable gain in spectral resolution especially for I = 5/2 and I = 9/2 nuclei is now available just by employing the ordinary MAS technique with single pulse excitation when observing the MAS lineshape of certain satellite transitions rather than the central transition MAS pattern. This gain in spectral resolution enables a tremendous progress for improved quantitative studies of disordered solids such as glasses and ceramics exhibiting distributions of the interaction parameters.

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  1. Max-Planck-Institut für Polymerforschung, Ackermannweg 10, D-55128, Mainz, Germany

    Christian Jäger

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  1. Christian Jäger
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  1. Makromolekulare Chemie, RTWH Aachen, Worringer Weg 1, D-52056, Aachen, Germany

    Bernhard Blümich (Lehrstuhl) (Lehrstuhl)

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Jäger, C. (1994). Satellite Transition Spectroscopy of Quadrupolar Nuclei. In: Blümich, B. (eds) Solid-State NMR II. NMR Basic Principles and Progress, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50049-7_4

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  • DOI: https://doi.org/10.1007/978-3-642-50049-7_4

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