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Polyolefin Analysis by Multidimensional Liquid Chromatography

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Multidimensional HPLC of Polymers

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Abstract

The synthesis and characterization of polyolefins continues to be one of the most important areas for academic and industrial research considering the fact that polyolefins make about 60 % of the total polymer market. One consequence of the development of new “tailor-made” polyolefins is the need for new and improved analytical techniques for the analysis of polyolefins with respect to molar mass, molecular topology and chemical composition distribution. Very frequently, polyolefins exhibit multiple distributions, e.g. long chain branching and molar mass distribution in low-density polyethylene (LDPE) or chemical composition distribution and molar mass distribution in linear low-density polyethylene (LLDPE), copolymers and polymer blends.

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References

  1. Wild L, Ryle T, Knobeloch D, Peat IR (1982) J Polym Sci Polym Phys 20:441

    Article  CAS  Google Scholar 

  2. Wild L (1991) Adv Polym Sci 98:1

    Article  CAS  Google Scholar 

  3. Monrabal B (1994) J Appl Polym Sci 52:491

    Article  CAS  Google Scholar 

  4. Monrabal B (1996) Macromol Symp 110:81

    Article  CAS  Google Scholar 

  5. Monrabal B, Blanco J, Nieto J, Soares JBP (1999) J Polym Sci Polym Chem 37:89

    Article  CAS  Google Scholar 

  6. Monrabal B, Mayo N, Cong R (2012) Macromol Symp 312:115

    Article  CAS  Google Scholar 

  7. Li Pi Shan C, Miller M, Lee D, Zhou Z (2012) Macromol Symp 312:1

    Article  Google Scholar 

  8. Pasch H, Malik I, Macko T (2012) Adv Polym Sci. doi: 10.1007/12_2012_167

  9. Housaki T, Satoh K, Nishikida K, Morimoto M (1988) Makromol Chem Rapid Commun 9:525

    Article  CAS  Google Scholar 

  10. Nishikida K, Housaki T, Morimoto M, Kinoshita T (1990) J Chromatogr A 517:209

    Article  CAS  Google Scholar 

  11. Markovich RP, Hazlitt LG, Smith-Courtney L (1993) In: Provder T (ed) Chromatography of polymers. Characterization by SEC and FFF, ACS Symp Ser 521. American Chemical Society, Washington, DC

    Google Scholar 

  12. Dhenin V, Rose LJ (2000) Polym Prepr 41:285

    Article  CAS  Google Scholar 

  13. DesLauriers PJ, Battiste DR (1995) ANTEC-SPE 53:3639

    Google Scholar 

  14. DesLauriers PJ, Rohlfing DC, Hsieh ET (2002) Polymer 43:159

    Article  CAS  Google Scholar 

  15. DesLauriers PJ (2004) Measuring compositional heterogeneity in polyolefins using SEC/FTIR spectroscopy. In: Striegel A (ed) Multiple detection in size exclusion chromatography, ACS Symp Ser 893. American Chemical Society, Washington, DC

    Google Scholar 

  16. Piel C, Albrecht A, Neubauer C, Klampfl CW, Reussner J (2001) Anal Bioanal Chem 400:2607

    Article  Google Scholar 

  17. Tackx P, Bremmers S (1997) Proc ISPAC-10, Toronto, p 42

    Google Scholar 

  18. Albrecht A, Bruell R, Macko T, Malz F, Pasch H (2009) Macromol Chem Phys 210:1319

    Article  CAS  Google Scholar 

  19. Albrecht A, Bruell R, Macko T, Sinha P, Pasch H (2008) Macromol Chem Phys 209:1909

    Article  CAS  Google Scholar 

  20. Heinz LC, Graef S, Macko T, Bruell R, Balk S, Keul H, Pasch H (2005) e-polymers no. 54

    Google Scholar 

  21. Macko T, Schulze U, Bruell R, Albrecht A, Pasch H, Fonagy T, Haeussler L, Ivan B (2008) Macromol Chem Phys 209:404

    Article  CAS  Google Scholar 

  22. Verdurmen-Noel L, Baldo L, Bremmers S (2001) Polymer 42:5523

    Article  CAS  Google Scholar 

  23. de Goede S, Bruell R, Pasch H, Marshall N (2003) Macromol Symp 193:35

    Article  Google Scholar 

  24. de Goede S, Bruell R, Pasch H, Marshall N (2004) e-polymers no. 012

    Google Scholar 

  25. de Goede E, Mallon P, Pasch H (2010) Macromol Mat Eng 295:366

    Article  Google Scholar 

  26. de Goede E, Mallon P, Pasch H (2012) Macromol Mat Eng 297:26

    Article  Google Scholar 

  27. de Goede E, Mallon P, Pasch H (2011) Macromol Mat Eng 296:1018

    Article  Google Scholar 

  28. Graef S, Bruell R, Pasch H, Wahner UM (2003) e-polymers no. 005

    Google Scholar 

  29. Luruli N, Pipers T, Bruell R, Grumel V, Pasch H, Mathot VBF (2007) J Polym Sci Polym Phys 45:2956

    Article  CAS  Google Scholar 

  30. Kearney T, Dwyer JL (2008) Am Lab 40:8

    CAS  Google Scholar 

  31. Hiller W, Pasch H, Macko T, Hoffmann M, Ganz J, Spraul M, Braumann U, Streck R, Mason J, van Damme F (2006) J Magn Res 183:290

    Article  CAS  Google Scholar 

  32. Zhou Z, Kuemmerle R, Stevens JC, Redwine D, He Y, Qiu X, Cong R, Klosin J, Montanez N, Roof G (2009) J Magn Res 200:328

    Article  CAS  Google Scholar 

  33. Zhou Z, Stevens JC, Klosin J, Kuemmerle R, Qiu X, Redwine D, Cong R, Taha A, Winniford B, Chauvel P, Montanez N (2009) Macromolecules 42:2291

    Article  CAS  Google Scholar 

  34. Cong R, de Groot AW, Parrott A, Yau W, Hazlitt L, Brown R, Miller MD, Zhou Z (2011) Macromolecules 44:3062

    Article  CAS  Google Scholar 

  35. Berek D (2000) Prog Polym Sci 25:873

    Article  CAS  Google Scholar 

  36. Chang T (2003) Adv Polym Sci 163:1

    Article  CAS  Google Scholar 

  37. Macko T, Pasch H, Kazakevich YV, Fadeev AY (2003) J Chromatogr A 988:69

    Article  CAS  Google Scholar 

  38. Macko T, Pasch H, Denayer JF (2003) J Chromatogr A 1002:55

    Article  CAS  Google Scholar 

  39. Macko T, Pasch H, Milonjic SK, Hiller W (2006) Chromatographia 64:183

    Article  CAS  Google Scholar 

  40. Macko T, Bruell R, Zhu Y, Wang Y (2010) J Sep Sci 33:3446

    Article  CAS  Google Scholar 

  41. Heinz LC, Macko T, Williams A, O’Donohue S, Pasch H (2006) The Column (electronic journal) Feb 13

    Google Scholar 

  42. Pasch H (2012) Chromatography. In: Matyjaszewski K, Moeller M (eds) Polymer science: a comprehensive reference, vol 2. Elsevier BV, p 33

    Google Scholar 

  43. Heinz LC, Macko T, Pasch H, Weiser MS, Mülhaupt R (2006) Int J Polym Anal Charact 11:47

    Article  CAS  Google Scholar 

  44. Heinz LC, Pasch H (2005) Polymer 46:12040

    Article  CAS  Google Scholar 

  45. Albrecht A, Heinz LC, Lilge D, Pasch H (2007) Macromol Symp 257:46

    Article  CAS  Google Scholar 

  46. Weiser MS, Thomann Y, Heinz LC, Pasch H, Mülhaupt R (2006) Polymer 47:4505

    Article  CAS  Google Scholar 

  47. Dolle V, Albrecht A, Brüll R, Macko T (2011) Macromol Chem Phys 212:959

    Article  CAS  Google Scholar 

  48. Albrecht A, Brüll R, Macko T, Pasch H (2007) Macromolecules 40:5545

    Article  CAS  Google Scholar 

  49. Pasch H, Albrecht A, Bruell R, Macko T, Hiller W (2009) Macromol Symp 282:71

    Article  CAS  Google Scholar 

  50. http://www.interscience.be/promotiesites/hypersil/topics/promotiesites/hypersil/nieuws/hypercarb_technical.pdf

  51. Gilbert MT, Knox JH, Kaur B (1982) Chromatographia 16:138

    Article  CAS  Google Scholar 

  52. Macko T, Pasch H, Wang Y (2009) Macromol Symp 282:93

    Article  CAS  Google Scholar 

  53. Macko T, Pasch H (2009) Macromolecules 42:6063

    Article  CAS  Google Scholar 

  54. Macko T, Brüll R, Wang Y (2009) Polym Prepr (Am Chem Soc Div Polym Chem) 50:228

    CAS  Google Scholar 

  55. Macko T, Brüll R, Alamo RG, Thomann Y, Grumel V (2009) Polymer 50:5443

    Article  CAS  Google Scholar 

  56. Macko T, Brüll R, Wang Y, Thomann Y (2009) The Column (electronic journal) 4:15

    Google Scholar 

  57. Macko T, Brüll R, Wang Y, Coto B, Suarez I (2011) J App Polym Sci 122:3211

    Article  CAS  Google Scholar 

  58. Macko T, Cutillo F, Bussico V, Brüll R (2010) Macromol Symp 298:182

    Article  CAS  Google Scholar 

  59. Chitta R, Macko T, Brüll R, van Doremaele G, Heinz LC (2011) J Polym Sci Polym Chem 49:1840

    Article  CAS  Google Scholar 

  60. Macko T, Brüll R, Alamo RG, Stadler FJ, Losio S (2011) Anal Bioanal Chem 399:1547

    Article  CAS  Google Scholar 

  61. Lipatov YS, Sergeeva LM (1974) Adsorption of polymers. Wiley, New York, NY

    Google Scholar 

  62. Lochmüller CH, Moebus MA, Liu QC, Jung C, Elomaa M (1996) J Chromatogr Sci 34:69

    Article  Google Scholar 

  63. Lee HC, Chang T (1996) Polymer 37:S747

    Google Scholar 

  64. Ginsburg A, Macko T, Dolle V, Bruell R (2010) J Chromatogr A 1217:6867

    Article  Google Scholar 

  65. Ginsburg A, Macko T, Dolle V, Bruell R (2011) Eur Polym J 47:319

    Article  Google Scholar 

  66. Roy A, Miller MD, Meunier DM, de Groot AW, Winniford WL, van Damme FA, Pell RJ, Lyons JW (2010) Macromolecules 43:3710

    Article  CAS  Google Scholar 

  67. Lee D, Miller MD, Meunier DM, Lyons JW, Bonner JM, Pell RJ, Li Pi Chan C, Huang T (2011) J Chromatogr A 1218:7173

    Article  CAS  Google Scholar 

  68. Bashir MA, Brüll A, Radke W (2005) Polymer 46:3223

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry and Polymer Science, University of Stellenbosch, Stellenbosch, South Africa

    Harald Pasch

  2. Institute of Chemistry, Karl-Franzens-University Graz, Graz, Austria

    Bernd Trathnigg

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  1. Harald Pasch
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  2. Bernd Trathnigg
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Pasch, H., Trathnigg, B. (2013). Polyolefin Analysis by Multidimensional Liquid Chromatography. In: Multidimensional HPLC of Polymers. Springer Laboratory. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36080-0_8

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