Skip to main content
SpringerLink
Log in

AlSBA-1 Molecular Sieves: Synthesis, Characterization and Catalytic Application

  • Conference paper
Green and Smart Technology with Sensor Applications (ICTSM 2011, SIA 2012, GST 2012)

Part of the book series: Communications in Computer and Information Science ((CCIS,volume 338))

  • 1811 Accesses

Abstract

Aluminum containing mesoporous molecular sieves, AlSBA-1 (nSi/nAl = 2, 5, 10 and 15) was synthesized hydrothermally using the template, cetyltriethylammonium bromide. They were characterized by XRD, BET, SEM and FT-IR. All the XRD patterns showed characteristic reflections of the three dimensional space group Pm3n. The catalytic activity was tested for the synthesis of 7-methoxy-4-methyl coumarin via Pechmann condensation of 3-methoxyphenol and ethyl acetoacetate. The reaction parameters, temperature, time, feed ratio, catalyst were optimized in order to obtain high conversion and product selectivity. Among the AlSBA-1 molecular sieves, AlSBA-1(2) exhibited higher activity than others.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Cravotto, G., Nano, G.M., Palmisanob, G., Tagliapietra, S.: An Asymmetric Approach to Coumarin Anticoagulants via Hetero-Diels-Alder cycloaddition. Tetrahedron Asymm. 12, 707–709 (2001)

    Article  Google Scholar 

  2. Kennedy, O., Thornes, R.D.: Coumarins: Biology. Applications and Mode of Action. Wiley and Sons, Chichester (1997)

    Google Scholar 

  3. Zahradnik, M.: The Production and Application of Fluorescent Brightening Agents. Wiley and Sons (1990)

    Google Scholar 

  4. Murray, R.D.H., Mendez, J., Brown, S.A.: The Natural Coumarins: Occurrence, Chemistry and Biochemistry. Wiley and Sons, New York (1982)

    Google Scholar 

  5. Von Pechmann, H., Duisberg, C.: Chem Ber. 17, 929 (1884)

    Google Scholar 

  6. Johnson, J.R.: The Perkin Reaction and Related Reactions. Org. React. 1, 210 (1942)

    Google Scholar 

  7. Jones, G.: The Knoevenagel Condensation. Org. React. 15, 204 (1967)

    Google Scholar 

  8. Shriner, R.L.: The Reformatsky Reaction. Org. React. 1, 1 (1942)

    Google Scholar 

  9. Narasimahan, N.S., Mali, R.S., Barve, M.V.: Synthesis, 906 (1979)

    Google Scholar 

  10. Schönberg, A., Latif, N.: The Action of Oxalyl Chloride on Indoles: A New Approach to Tryptamines. J. Am. Chem. Soc. 76, 6208–6210 (1954)

    Article  Google Scholar 

  11. Li, T.S., Zhang, Z.H., Yang, F., Fu, C.G.: Montmorillonite Clay Catalysis. Part 7.1 An Environmentally Friendly Procedure for the Synthesis of Coumarins via Pechmann Condensation of Phenols with Ethyl Acetoacetate. J. Chem. Res (S), 38–39 (1998)

    Google Scholar 

  12. Gunnewegh, E.A., Hoefnagel, A.J., van Bekkum, H.: Zeolite Catalysed Synthesis of Coumarin Derivatives. J. Mol. Catal. A: Chem. 100, 87–92 (1995)

    Article  Google Scholar 

  13. Horning, E.C.: Organic Synthesis, vol. III, p. 281. Wiley, New York (1955)

    Google Scholar 

  14. Khaligh, N.G.: Synthesis of Coumarins via Pechmann Reaction Catalyzed by 3-Methyl-1-Sulfonic Acid Imidazolium Hydrogen Sulfate as an Efficient, Halogen-Free and Reusable Acidic Ionic Liquid. Catal. Sci. Technol. 2, 1633–1636 (2012)

    Article  Google Scholar 

  15. Hoefnagel, A.J., Gunnewegh, E.A., Downing, R.S., Bekkum, H.V.: Synthesis of 7-Hydroxycoumarins Catalysed by Solid Acid Catalysts. J. Chem. Soc., Chem. Commun. 225 (1995)

    Google Scholar 

  16. Sudha, S., Venkatachalam, K., Priya, S.V., Mabel, J.H., Palanichamy, M., Murugesan, V.: Single Step Synthesis of Coumarin Derivatives over Al-MCM-41 and its Supported Catalysts under Solvent-Free Condition. J. Mol. Catal. A: Chem. 291, 22–29 (2008)

    Article  Google Scholar 

  17. Sinhamahapatra, A., Sutradhar, N., Pahari, S., Bajaj, H.C., Panda, A.B.: Mesoporous Zirconium Phosphate: An Efficient Catalyst for the Synthesis of Coumarin Derivatives through Pechmann Condensation Reaction. Appl. Catal. A: Gen. 394, 93–100 (2011)

    Article  Google Scholar 

  18. Kalita, P., Kumar, R.: Solvent-Free Coumarin Synthesis via Pechmann Reaction Using Solid Catalysts. Micropor. Mesopor. Mater. 149, 1–9 (2012)

    Article  Google Scholar 

  19. Balasubramanian, V.V., Anand, C., Pal, R.R., Mori, T., Bohlmann, W., Ariga, K., Tyagi, A.K., Vinu, A.: Characterization and the Catalytic Applications of Mesoporous AlSBA-1. Micropor. Mesopor. Mater. 121, 18–25 (2009)

    Article  Google Scholar 

  20. Venkatachalam, K., Palanichamy, M., Murugesan, V.: Acetalization of Heptanal over Al-SBA-1 Molecular Sieve. Catal. Commun. 12, 299–303 (2010)

    Article  Google Scholar 

  21. Kao, H.-M., Cheng, C.-C.: Tetramethoxysilane as a Convenient Silicon Source for Phase Control of Cubic SBA-1 Mesostructures. Mater. Lett. 60, 2594–2599 (2006)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemical Engineering Department, Hanseo University, Seosan, 356-706, South Korea

    Mei Mei Peng, Dong Seung Shin, Pushparaj Hemalatha, Mani Ganesh, Muthiahpillai Palanichamy & Hyun Tae Jang

  2. Sake Company, 548-2 Gubuk, Seosan, South Korea

    Dong Seung Shin

Authors
  1. Mei Mei Peng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dong Seung Shin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Pushparaj Hemalatha
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mani Ganesh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Muthiahpillai Palanichamy
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Hyun Tae Jang
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Chungwoon University, 350-701, Chungnam, Republic of Korea

    Hyun-seob Cho  & Keun-Wang Lee  & 

  2. GVSA and University of Tasmania, 20 Virginia Court, Hobart, TAS, Australia

    Tai-hoon Kim

  3. Lakehead University, ATAC 5013, 955 Oliver Road, P7B 5E1, Thunder Bay, Ontario, Canada

    Sabah Mohammed

  4. The Ohio State University, 4198 Graves Hall 333 W. 10th Avenue, 43210, Columbus, OH, USA

    Hojjat Adeli

  5. Hyejeon University, Hongseong-eup, Hongseong-gun, Chungnam-do, Republic of Korea

    Myoung-kwan Oh

Rights and permissions

Reprints and permissions

Copyright information

© 2012 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Peng, M.M., Shin, D.S., Hemalatha, P., Ganesh, M., Palanichamy, M., Jang, H.T. (2012). AlSBA-1 Molecular Sieves: Synthesis, Characterization and Catalytic Application. In: Cho, Hs., Kim, Th., Mohammed, S., Adeli, H., Oh, Mk., Lee, KW. (eds) Green and Smart Technology with Sensor Applications. ICTSM SIA GST 2011 2012 2012. Communications in Computer and Information Science, vol 338. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-35251-5_16

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-35251-5_16

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-35250-8

  • Online ISBN: 978-3-642-35251-5

  • eBook Packages: Computer ScienceComputer Science (R0)

Publish with us

Policies and ethics

Search

Navigation