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Vacuum Ultraviolet Negative Photoion Spectroscopy of CF3Cl, CF3Br and CF3I

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Two Studies in Gas-Phase Ion Spectroscopy

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Abstract

This chapter presents and analyses the data collected for trifluorochloromethane (CF3Cl), trifluorobromomethane (CF3Br) and trifluoroiodomethane (CF3I). This series of molecules will be referred to as the CF3 X series, where X = Cl, Br or I, and the main aim of this study is to compare the data and see the effects and resulting trends of changing substituent X. These results were collected in September 2006 at the Daresbury synchrotron radiation source on beamline 3.1. Many thanks go to Professors Richard Tuckett and Colin Latimer, Drs Ken Dunn, Adam Hunniford, and David Shaw for their individual contributions in the data collection. I also thank Richard Tuckett and Michael Parkes for their part in analysing the data. This work was published in the Journal of Chemical Physics in 2009 [1].

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References

  1. Simpson MJ, Tuckett RP, Dunn KF, Hunniford CA, Latimer CJ (2009) J Chem Phys 130:194302

    Article  CAS  Google Scholar 

  2. United Nations Environment Programme (2008) (http://ozone.unep.org/). Oct 2008

  3. Solomon S, Burkholder JB, Ravishankara AR, Garcia RR (1994) J Geophys Res D 99:20929

    Article  Google Scholar 

  4. Christophorou LG, Olthoff JK (2000) J Phys Chem Ref Data 29:553

    Article  CAS  Google Scholar 

  5. Li Y, Patten KO, Youn D, Wuebbles DJ (2006) Atmos Chem Phys 6:4559

    Article  CAS  Google Scholar 

  6. Cvitaš T, Güsten H, Klasinc L (1977) J Chem Phys 67:2687

    Article  Google Scholar 

  7. Jadrny R, Karlsson L, Mattsson L, Siegbahn K (1977) Phys Scr 16:235

    Article  CAS  Google Scholar 

  8. Cvitaš T, Güsten H, Klasinc L, Novadj I, Vančik H (1978) Z Naturforsch 33A:1528

    Google Scholar 

  9. Doucet J, Sauvageau P, Sandorfy C (1972) J Chem Phys 58:3708

    Article  Google Scholar 

  10. Creasey JC, Smith DM, Tuckett RP, Yoxall KR, Codling K, Hatherly PA (1996) J Phys Chem 100:4350

    Article  CAS  Google Scholar 

  11. Powis I, Dutult O, Richard-Viard M, Guyon PM (1990) J Chem Phys 92:1643

    Article  CAS  Google Scholar 

  12. Gilbert R, Sauvageau P, Sandorfy C (1974) J Chem Phys 60:4820

    Article  CAS  Google Scholar 

  13. Jochims HW, Lohr W, Baumgärtel H (1976) Ber Bunsen Ges Phys Chem 80:130

    CAS  Google Scholar 

  14. King GC, McConkey (1978) J Phys B 11:1861

    Article  CAS  Google Scholar 

  15. Au JW, Burton GR, Brion CE (1997) Chem Phys 221:151

    Article  CAS  Google Scholar 

  16. Eden S, Limão-Vieira P, Hoffmann SV, Mason NJ (2006) Chem Phys 323:313

    Article  CAS  Google Scholar 

  17. Hoshino M, Sunohara K, Makochekanwa C, Pichl L, Cho H, Tanaka H (2007) J Chem Phys 126:024303

    Article  CAS  Google Scholar 

  18. Ali S (2007) Ph.D. thesis, University of Birmingham. http://etheses.bham.ac.uk/897/

  19. Biehl H, Boyle KJ, Tuckett RP, Baumgärtel H, Jochims HW (1997) Chem Phys 214:367

    Article  CAS  Google Scholar 

  20. Schenk H, Oertel H, Baumgärtel H (1979) Ber Bunsen Ges Phys Chem 83:683

    CAS  Google Scholar 

  21. Macleod NA, Wang S, Hennessy J, Ridley T, Lawley KP, Donovan RJ (1998) J Chem Soc, Faraday Trans 94:2689

    Article  CAS  Google Scholar 

  22. Lide DR (2007) Handbook of chemistry and physics, 88th edn. Taylor & Francis, London

    Google Scholar 

  23. Simpson MJ, Tuckett RP, Dunn KF, Hunniford CA, Latimer CJ, Scully SWJ (2008) J Chem Phys 128:124315

    Article  CAS  Google Scholar 

  24. Christophorou LG (1996) Z Phys Chem 195:195

    Article  CAS  Google Scholar 

  25. Marienfield S, Sunagawa T, Fabrikant II, Braun M, Ruf M-W, Hotop H (2006) J Chem Phys 124:154316

    Article  Google Scholar 

  26. Marienfield S, Fabrikant II, Braun M, Ruf M-W, Hotop H (2006) J Phys B 39:105

    Article  Google Scholar 

  27. Parkes MA (2007) Ph.D. thesis, University of Birmingham. http://etheses.bham.ac.uk/74/

  28. Berkowitz J (1996) In: Becker U, Shirley DA (eds) VUV and soft X-ray photoionization. Plenum Press, New York Chap. 8

    Google Scholar 

  29. Simpson MJ, Tuckett RP (2011) Int Rev Phys Chem 30:197

    Article  CAS  Google Scholar 

  30. Rogers NJ, Simpson MJ, Tuckett RP, Dunn KF, Latimer CJ (2010) Phys Chem Chem Phys 12:10971

    Article  CAS  Google Scholar 

  31. Chim RYL, Cicman C, Märk TD, Mayhew CA, Scheier P, Tuckett RP (2007) Int J Mass Spectrom 261:208

    Article  CAS  Google Scholar 

  32. Bilde M, Sehested J, Mogelberg TE, Wallington TJ, Nielsen OJ (1996) J Phys Chem 100:7050

    Article  CAS  Google Scholar 

  33. Gilles MK, Turnipseed AA, Talukdar RK, Rudich Y, Villalta PW, Huey LG, Burkholder JB, Ravishankara AR (1996) J Phys Chem 100:14005

    Article  CAS  Google Scholar 

  34. Tuckett RP (2006) Adv Fluorine Sci (Elsevier) 1:89 ISBN: 9780444528117

    Article  CAS  Google Scholar 

  35. Deyerl HJ, Alconcel LS, Continetti RE (2001) J Phys Chem A 105:552

    Article  CAS  Google Scholar 

  36. Chase MW (1998) J Phys Chem Ref Data, Monograph no. 9

    Google Scholar 

  37. Blondel C, Delsart C, Goldfarb F (2001) J Phys B 34:L281

    Article  CAS  Google Scholar 

  38. Garcia GA, Guyon PM, Powis I (2001) J Phys Chem A 105:8296

    Article  CAS  Google Scholar 

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Correspondence to Matthew J. Simpson .

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Simpson, M.J. (2012). Vacuum Ultraviolet Negative Photoion Spectroscopy of CF3Cl, CF3Br and CF3I. In: Two Studies in Gas-Phase Ion Spectroscopy. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23129-2_4

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