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Kinetic Aspects

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Chromium -VI Reagents: Synthetic Applications

Part of the book series: SpringerBriefs in Molecular Science ((BRIEFSMOLECULAR))

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Abstract

In this chapter, the general kinetic characteristics such as the order, activation parameters and isotopic effect on the rate of oxidation with some of the Cr(VI) reagents and their mechanistic implications are discussed.

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References

  1. Battacharjee Manbendra N, Chaudhuri Mihir K, Dasgupta Himadri S (1984) Bull Chem Soc Jpn 57:258

    Article  Google Scholar 

  2. Rajasekharan K, Bhaskaran T, Gnanasekaran C (1984) J Chem Soc Perkins Trans 2:1183

    Article  Google Scholar 

  3. Grigor’ev MG, Buketova IA, Polevschikov PF (1987) Izv Vyssh Uchebn Zaved Khim Technol 30:22 Chem Abstr 109:6142

    Google Scholar 

  4. Nagi Reddy K, Uma Devi PS, Saiprakash PK (1983) Acta Cienc Indica Chem 9:112. Chem Abstr 100:208915t

    Google Scholar 

  5. Valechha ND, Dakwala DS (1984) J Indian Chem Soc 61:581

    CAS  Google Scholar 

  6. Samal PG, Patnaik BB, Rao SCD, Mahapatra SN (1983) Tetrahedron 39:143

    Article  CAS  Google Scholar 

  7. Sen Gupta KK, Tapashi S, Sumarendra Nath B (1985) Tetrahedron 41:205

    Article  CAS  Google Scholar 

  8. Venkateswra Rao S, Jagannadham V (1988) Indian J Chem 27A:252

    Google Scholar 

  9. Rao LV, Prasada S, Brahmaji S (1988) J Indian Chem Soc 65(6):404

    CAS  Google Scholar 

  10. Anis SS, Mansour MA, Stefan Shaker L (1988) Microchem J 37(3):345

    Article  CAS  Google Scholar 

  11. Farize Hasan, Rocek J (1976) J Amer Chem Soc 98:6574

    Article  Google Scholar 

  12. Ramesh S, Rocek J, Schoellor DA (1978) J Phys Chem 82:2752

    Article  Google Scholar 

  13. Ip D, Rocek J (1979) J Amer Chem Soc, 101:6311 and references cited therein

    Google Scholar 

  14. Nagarajan K, Sundaram S, Venkatasubramanian N (1979) Ind J Chem 18:260

    Google Scholar 

  15. Nagarajan K, Sundaram S, Venkatasubramanian N (1979) Ind J Chem 18A:335

    CAS  Google Scholar 

  16. Alvarez Macho MP (1988) An Quim Ser A 84(1):14

    CAS  Google Scholar 

  17. Baldea Ioan (1987) Stud Univ Babes-Bolyai Chem 32(2):42 CA 110:56881v

    Google Scholar 

  18. Szeto May Nin-Ping (1988) Diss Abstr Int B 48(10):2979 CA 110:7407 m

    Google Scholar 

  19. Banerji KK (1988) J Org Chem 53(10):2154

    Article  CAS  Google Scholar 

  20. Sharma VK, Rai RC (1983) J Indian Chem Soc 60:745

    CAS  Google Scholar 

  21. Banerji KK (1983) Indian J Chem 22B:413

    CAS  Google Scholar 

  22. Adegboyega Olatunji M, Adefikayo Ayoko G (1988) Polyhedron 7:11

    Article  Google Scholar 

  23. Alvarez Macho MP, Ontequi martin MI (1987) An Quim Ser A 83:248 CA:108:132217j

    CAS  Google Scholar 

  24. Crespo Pinilla MC, Mata Parez F, Alvarez Macho MP, Crespo Pinilla (1987) An Quim Ser A 83:130 CA:108:130832g

    CAS  Google Scholar 

  25. Kamannarayana P, Raghavachari K (1986) Acta Cienc Indica Chem 12:79 CA:108:5430y

    CAS  Google Scholar 

  26. Sen Gupta KK, Sen Gupta S, Subrata Kumar M, Sumarendra nath B (1985) Carbohydr Res 139:185

    CAS  Google Scholar 

  27. Alvarez Macho MP, Sermentero Calzada J (1984) An Quin Ser A 80:687 CA:103:27988k

    CAS  Google Scholar 

  28. Alvarez Macho MP (1984) An Quim Ser A 80:672 CA 103:27986h

    CAS  Google Scholar 

  29. Uma P, Kanta Rao P, Sastri MN (1985) Indian J Chem 24A:539

    CAS  Google Scholar 

  30. Varadarajan R, Dhar RK (1986) Indian J Chem 35A:474

    Google Scholar 

  31. Herscovici J, Marie Jose E, Antonakis K (1982) J Chem Soc Perkin Trans 1:1967

    Article  Google Scholar 

  32. Bhattacharji B, Bhattacharji MN, Bhattacharji M, Bhattachaji AK (1986) Bull Chem Soc Jpn 59:3276

    Google Scholar 

  33. Srinivasan C, Chellamani A, Rajagopal S (1985) J Org Chem 50:1201

    Article  CAS  Google Scholar 

  34. Bhattacharji B, Bhattacharji MN, Bhattacharji M, Bhattachaji AK (1985) Int J Chem Kinet 17:629

    Article  Google Scholar 

  35. Banerji KK (1978) J Chem Soc Perkin Trans 2:639

    Google Scholar 

  36. Bell RP (1973) The proton in chemistry. Cornell University Press, Ithaca, NY

    Google Scholar 

  37. Melander L (1960) Isotope effects on reaction rates. Ronald Press, NY

    Google Scholar 

  38. Wiberg KB (1955) Chem Rev 55:713

    Article  CAS  Google Scholar 

  39. Westheimer FH (1961) Chem Rev 61:265

    Article  CAS  Google Scholar 

  40. Bell R P (1965) Discuss Faraday Soc 16

    Google Scholar 

  41. Albery WJ (1967) Trans Faraday Soc 63:200

    Article  CAS  Google Scholar 

  42. Stewart R, Lee DG (1964) Can J Chem 42:439

    Article  CAS  Google Scholar 

  43. Venkatasubramanian N (1965) Indian J Chem 3:225

    CAS  Google Scholar 

  44. Banerji KK (1983) Indian J Chem 22B:650

    CAS  Google Scholar 

  45. Kwart H (1982) Acc Chem Res 15:401

    Article  CAS  Google Scholar 

  46. Sharma K, Sharma VK, Rai RC (1983) J Indian Chem Soc 60:747

    CAS  Google Scholar 

  47. Raj Rabindra N, Glushka John N, Chew Warren, Perlin Arthur S (1989) Carbohydr Res 189:135

    Article  Google Scholar 

  48. Manorama S, Panigrahi GP, Mahapatra SN (1985) J Org Chem 50:3651

    Article  Google Scholar 

  49. Rao Venkateshwar G, Saiprakash PK (1988) Oxid Commun 11:33

    Google Scholar 

  50. Rajasekharan K, Bhaskaran T, Gnanasekaran C (1987) Indian J Chem 26A:956

    Google Scholar 

  51. Musale Reddy P, Jagannadham V, Sethuraman B, Sethuraman B, Navaneeth Rao T (1982) Pol J Chem 56:865

    Google Scholar 

  52. Chidambaram N, Sathyanarayan K, Chandrasekaran S (1989) Tetrahedron Lett 30(18):2429

    Article  CAS  Google Scholar 

  53. Satyanarayana Reddy T, Jagannadham V (1986) Proc Natl Acad Sci India 56A:129

    Google Scholar 

  54. Bhatta D, Behera SM, Mohanty SR (1987) Indian J Chem 26A:778

    CAS  Google Scholar 

  55. Balaiah V, Satyanarayana PVV (1985) Curr Sci 54:384

    CAS  Google Scholar 

  56. Kharga RD, Mishra HB (1983) J Nepal Chem Soc 3:45

    CAS  Google Scholar 

  57. Nambi K, Basheer AKA, Arulraj SJ (1988) J Indian Chem Soc LXV(2):85

    Google Scholar 

  58. Basheer AKA, Nambi K, Arulraj S (1987) Indian J Chem 26A:672

    Google Scholar 

  59. Saran NK, Acharya RC, Rao SR (1985) J Indian Chem Soc 62:747

    CAS  Google Scholar 

  60. Height GP, Gregory GM, Terry KM, Patrick M (1985) J Inorg Chem 24:2740

    Article  Google Scholar 

  61. Singh VP, Fandey IM, Sharma SB (1985) J Indian Chem Soc 62:64

    CAS  Google Scholar 

  62. Gupta KK, Taneja SC, Dhar KL (1989) Indian J Chem B 28B(2):136

    CAS  Google Scholar 

  63. Wetheimer FH, Leo A (1952) J Am Chem Soc 74:4383

    Article  Google Scholar 

  64. Rocek J, Krupicka J (1958) Coll Czech Chem Commun 23:2068

    Google Scholar 

  65. Venkatasubramanian N (1960) Proc Indian Acad Sci 50:156

    Google Scholar 

  66. Kwart H, Francis PS (1959) J Am Chem Soc 81:2116

    Article  CAS  Google Scholar 

  67. Gokavi GS, Raju R (1988) Indian Chem 27A:494

    CAS  Google Scholar 

  68. Sagi R, Prakasa Raju GS, Ramana KV (1975) Talanta 22:93

    Article  CAS  Google Scholar 

  69. Tret’yakov VP, Zimtseva GP, Min’ko LA, Chudaev VV, Rudakov ES, Tyupalo NV (1987) Ukr Khim Zh 53(11):176 C.A.:109: 189624q

    Google Scholar 

  70. Saavedra JE, Fransworth W, Guokui Pei (1988) Synth Commun 18(3):313

    Article  CAS  Google Scholar 

  71. Dorfman Ya A, Polimbetova GS, Kelman IV et al (1989) Koord Khim 15(1):77 C.A. 110:180124q

    Google Scholar 

  72. Mimicos N, Mylona A, Paleos CM (1987) Mol Cryst Liq Cryst 543

    Google Scholar 

  73. Ahamed Jamil Astin, Brain K (1988) Langmuir 4(3):780

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Ramakrishna Mission Vivekananda College, Mylapore, Chennai, 600004, India

    Prof. Sundaram Srinivasan

  2. Department of Chemistry, Madras Christian College, Tambaram, Chennai, 600059, India

    Prof. Raghavan Seshan

Authors
  1. Prof. Sundaram Srinivasan
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  2. Prof. Raghavan Seshan
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Correspondence to Raghavan Seshan .

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Srinivasan, S., Seshan, R. (2011). Kinetic Aspects. In: Chromium -VI Reagents: Synthetic Applications. SpringerBriefs in Molecular Science(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20817-1_4

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