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Synthetic Strategies

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Chromium -VI Reagents: Synthetic Applications

Part of the book series: SpringerBriefs in Molecular Science ((BRIEFSMOLECULAR))

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Abstract

A critical comparative account of the special properties of the Cr(VI) reagents are discussed in this chapter. These special properties include enhanced potency towards the oxidation of not only alcohols but also other substrates including oximes and aromatic hydrocarbons; their specific synthetic applications for certain regioselective products and modified selective product distribution. A unique and quite unexpected course of reactions such as the hydroxylation at a tertiary carbon atom, observed with some of these reagents are also briefly discussed.

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Authors and Affiliations

  1. Department of Chemistry, Ramakrishna Mission Vivekananda College, Mylapore, Chennai, 600004, India

    Prof. Sundaram Srinivasan

  2. Department of Chemistry, Madras Christian College, Tambaram, Chennai, 600059, India

    Prof. Raghavan Seshan

Authors
  1. Prof. Sundaram Srinivasan
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  2. Prof. Raghavan Seshan
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Correspondence to Raghavan Seshan .

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Srinivasan, S., Seshan, R. (2011). Synthetic Strategies. In: Chromium -VI Reagents: Synthetic Applications. SpringerBriefs in Molecular Science(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20817-1_3

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