Abstract
The previous sections demonstrated that charge-transfer and energy-transfer processes are characterized by many different parameters. We cannot limit ourselves to the molecular building blocks of a system. Instead, the entire supramolecular structure should be analyzed as a whole system. Only this assists in gathering a sufficient understanding of the interplay between the components. In particular, a close inspection reveals that the energetics and the relationship of the energy-levels of donor, bridge and acceptor govern the energy/charge transfer properties of these systems. However, the key roles in these transport processes are played by the molecular bridges connecting the donor with the acceptor. In the following we survey these processes with particular emphasis on the function of the bridges, or, in other words, on their molecular wire properties.
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References
Emberly EG, Kirczenow G (1998) Phys Rev B 58:10911
Nitzan A, Ratner MA (2003) Science Washington DC, US 300:1384
Davis WB, Svec WA, Ratner MA, Wasielewski MR (1998) Nature 396:60
Schatz GC, Ratner MA (2002) Quantum mechanics in chemistry, 2 edn. Dover Pub- lications, Mineola, New York
Linderberg J, Ohrn Y (2004) Propagators in quantum chemistry. Wiley, Hoboken, New Jersey
Pople JA, Beveridge DL (1970) Approximate molecular orbital theory. McGraw-Hill, New York
Jortner J (1976) J Chem Phys 64:4860
Ratner MA, Sutin N (1986) Biochim Biophys Acta 811:265
Kramers KH (1934) Physica 1:182
Anderson PW (1950) Phys Rev Lett 79:350
Anderson PW (1959) Phys Rev Lett 115:2
Nitzan A (2001) Annu Rev Phys Chem 52:681
Berlin YA, Burin AL, Ratner MA (2002) Chem Phys 275:61
Grozema FC, Berlin YA, Siebbeles LDA (2000) J Am Chem Soc 122:10903
Finklea HO, Hanshewm DD (1992) J Am Chem Soc 114:3173
Slowiski K, Chamberlain RV, Miller CJ, Majda M (1997) J Am Chem Soc 119:11910
Chidsey CED (1991) Science Washington DC, US 251:919
Leland BA, Joran AD, Felker PM, Hopfield JJ, Zewail AH, Dervan PB (1985) J Phys Chem A 89:5571
Oevering H, Paddon-Row MN, Heppener M, Oliver AM, Cotsaris E, Verhoeven JW, Hush NS (1987) J Am Chem Soc 109:3258
Closs GL, Miller JR (1988) Science Washington DC, US 240:440
Klan P, Wagner PJ (1998) J Am Chem Soc 120:2198
Osuka A, Maruyama K, Mataga N, Asahi T, Yamazaki I, Tamai N (1990) J Am Chem Soc 112:4958
Helms A, Heiler D, McClendon G (1992) J Am Chem Soc 114:6227
Weiss EA, Ahrens MJ, Sinks LE, Gusev AV, Ratner MA, Wasielewsi MR (2004) J Am Chem Soc 126:5577
Osuka A, Satoshi N, Maruyama K, Mataga N, Asahi T, Yamazaki I, Nishimura Y, Onho T, Nozaki K (1993) J Am Chem Soc 115:4577
Barigelletti F, Flamigni L, Balzani V, Collin J-P, Sauvage J-P, Sour A, Constable EC, Cargill AMW (1994) Thompson. J Am Chem Soc 116:7692
Creager S, Yu CJ, Bamdad C, O’Connor S, MacLean T, Lam E, Chong Y, Olsen GT, Luo J, Gozin M, Kayyem JF (1999) J Am Chem Soc 121:1059
Sachs SB, Dudek SP, Hsung RP, Sita LR, Smalley JF, Newton MD, Feldberg SW, Chidsey CED (1997) J Am Chem Soc 10:563
Sykes HD, Smalley JF, Dudek SP, Cook AR, Newton MD, Chidsey CED, Felberg SW (2001) Science Washington DC, US 291:1519
Martin N, Giacalone F, Segura JL, Guldi DM (2004) Synth Met 147:57
Atienza C, Martín N, Wielopolski M, Haworth N, Clark T, Guldi DM (2006) Chem Commun (Cambridge, UK) 30:3202
Benniston AC, Goulle V, Harriman A, Lehn J-M, Marczinke B (1994) J Phys Chem A 98:7798
Osuka A, Tanabe N, Kawabata S, Speiser IS (1996) Chem Rev Washington DC, US 96:195
Marczinke B (1994) J Phys Chem A 98:7798
Osuka A, Tanabe, Kawabata S, Grosshenny IV, Harriman A, Ziessel R (1995) Angew Chem Int Ed 34:1100
Grosshenny IV, Harriman A, Ziessel R (1995) Angew Chem Int Ed 34:2705
Marcus RA (1987) Chem Phys Lett 133:471
Ogrodnik A, Michel-Beyerle ME, Naturforsch Z (1989) A Phys Sci 44a:763
Kilsa K, Kajanus J, Macpherson AN, Martensson J, Albinsson B (2001) J Am Chem Soc 123:3069
Lukas AS, Bushard PJ, Wasielewski MR (2002) J Phys Chem A 106:2074
Marcus RA (1965) J Chem Phys 43:679
McConnell HM (1961) J Chem Phys 35:508
Closs GL, Piotrowiak P, McInnis JM, Fleming GR (1988) J Am Chem Soc 110:2652
Roest MR, Oliver AM, Paddon-Row MN, Verhoeven JW (1997) J Phys Chem A 101:4867
Paddon-Row MN, Oliver AM, Warman JM, Smit KJ, Haas MP, Oevering H, Verhoeven JW (1988) J Phys Chem A 92:6958
Jortner J, Bixon M, Langenbacher T, Michel-Beyerle ME (1998) Proc Natl Acad Sci USA 95:759
Bixon M, Giese B, Langenbacher T, Michel-Beyerle ME, Jortner J (1999) Proc Natl Acad Sci USA 96:11713
Davis WB, Wasielewski MR, Mujica V, Nitzan A (1997) J Phys Chem A 101:6158
Kharkats YI, Ulstrup J (1991) Chem Phys Lett 182:81
Sourtis SS, Mukamel S (1995) Chem Phys 197:367
Felts AK, Pollard WT, Friesner RA (1995) J Phys Chem A 99:2929
Cave RJ, Newton MD (1996) Chem Phys Lett 249:15
Creutz C, Newton MD, Sutin N (1994) J Photochem Photobiol A 82:47
Kumar K, Kurnikov IV, Beratan DN, Waldeck DH, Zimmt MB (1998) J Phys Chem A 102:5529
Stuchebrukov AA, Marcus RA (1995) J Phys Chem A 99:7581
Golub GH, van Loan CF (1989) Matrix computations. Johns Hopkins University Press, Baltimore
Flannery BP, Teukolsky SA, Vetterlink WT (1988) Numerical recipes. Cambridge Uni- versity Press, Cambridge, UK
Fan F, Yang J, Cai L, Price Jr DW, Dirk SM, Kosynkin DV, Yao Y, Rawlett AM, Tour JM, Bard AJ (2002) J Am Chem Soc 124:5550
Zangmeister CD, Robey SW, van Zee RD, Yao Y, Tour JM (2004) J Phys Chem B 108:16187
Zhu XY (2004) J Phys Chem B 108:8778
Parts a and d (1988) In: Fox MA, Chanon M (eds) Photoinduced Electron Transfer. Elsevier, Amsterdam
Hu X, Schulten K (1997) How nature harvests sunlight. Phys Today 50:28 and references therein
Rice MJ, Gartstein YN (1996) Theory of photoinduced charge transfer in a molecularly doped conjugated polymer. Phys Rev B 53:10764
Wu MW, Conwell EM (1998) Theory of photoinduced charge transfer in weakly coupled donor-acceptor conjugated polymers: application to an meh-ppv:cn-ppv pair. Chem Phys 227:11
Paddon-Row MN (1994) Acc Chem Res 27:18
Guldi DM (2002) Chem Soc Rev 31:22
Bixon M, Jortner J (1999) Adv Chem Phys 106:35
Müller GM, Lupton JM, Feldmann J, Lemmer U, Scharber MC, Sariciftci NS, Brabec CJ, Scherf U (2005) Phys Rev B 72:195208
Marcus RA (1964) Annu Rev Phys Chem 15:155
Kavarnos GJ, Turro NJ (1986) Chem Rev Washington DC, US 86:401
Marcus RA (1993) Angew Chem Int Ed 105:1161
Kuznetsov AM, Ulstrup J (1999) Electron transfer in chemistry and biology: an introduction to the theory. JohnWiley and Sons Ltd, New York
Marcus RA (1956) J Chem Phys 24:979
Rehm D, Weller A (1970) Isr J Chem 8:259
Balzani V, Scandola F (1991) Supramolecular Photochemistry. Horwood, Chichester
Jortner J, Ratner M (eds.) (1997) Molecular Electronics. Blackwell, London
McGlynn SP, Smith FJ, Cilento G. Photochem J (1964) Photobiol A 3:269
Dewar MJS, Doughtery RC (1975) The PMO Theory of Organic Chemistry. Plenum, New York
Halliday D, Resnick R (1967) Physics. JohnWiley, New York
Dauben W, Salem L, Turro NJ (1975) Acc Chem Res 8:41
Michl J (1974) Top Curr Chem 46:1
Michl J (1972) Mol Photochem 4:243
Devaquet A (1975) Top Curr Chem 54:1
Dauben W, Salem L (1975) J Am Chem Soc 97:479
Atkins P (1974) Quanta: A Handbook of Concepts. Clarendon Press, Oxford
Förster T (1970) Pure Appl Chem 24:443
Bixon M, Jortner J, Verhoeven JW (1994) J Am Chem Soc 116:7349
Turro NJ (1978) Modern molecular photochemistry. Benjamin Cummings, Menlo Park
Fleming GR (1986) Chemical Applications of Ultrafast Spectroscopy. Oxford University Press, New York
Kasha M (1995) Faraday Discuss 9:14
Turro NJ (1991) Modern Molecular Photochemistry 2nd edition. University Science Books, Sausalito, California
Klessinger M, Michl J (1995) Excited states and photochemistry of organic molecules. VCH Publishers, Inc., New York
Strickler JS, Berg RA (1962) J Chem Phys 37:814
Reichardt C (1990) Solvents and Solvent Effects in Organic Chemistry. VCH VerlagsgesellschaftmbH, Weinheim
Raz B, Jortner J (1969) Chem Phys Lett 4:155
Messing I, Jortner J (1977) Chem Phys 24:183
Born M (1920) Z Phys Chem (Muenchen, Ger) 1:221
Maroncelli M, MacInnis J, Fleming GR (1989) Science Washington DC, US 243:1674
Jortner J, Bixon M (1988) J Chem Phys 88:167
Biswas R, Bagchi B (1999) J Phys Chem A 103:2495
Rosenthal SJ, Xie X, Du M, Fleming GR (1991) J Chem Phys 95:4715
Kahlow MA, Kang TJ, Barbara PF (1988) J Chem Phys 90:2372
Walker GC, Åkesson E, Johnson AE, Levinger NE, Barbara PF (1992) Phys Chem Chem Phys 96:3728
Reynolds L, Gardecki JA, Frankl SJV, Horng ML, Maroncelli M (1996) J Phys Chem A 100:10337
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Wielopolski, M. (2010). Molecule-Assisted Transport of Charges and Energy Across Donor–Wire–Acceptor Junctions. In: Testing Molecular Wires. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-14740-1_4
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