The presentations in the prior chapters have been limited to ideal systems, either gases or solutions. We now extend the thermodynamic and stochastic theory to non-ideal systems.
The formulation of the theory requires deterministic equations either of kinetics or transport for non-ideal systems. We shall illustrate the approach with the Bronsted theory of non-ideal reactants and products, which has been used extensively.
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References
R.S. Berry, S.A. Rice, J. Ross, Physical Chemistry, 2nd edn. (Oxford University Press, New York, 2000)
R. Fowler, E.A. Guggenheim, Statistical Thermodynamics (Cambridge University Press, Cambridge, 1949)
J. Ross, X.-L. Chu, J. Chem. Phys. 98, 9765 (1993)
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(2008). Thermodynamic and Stochastic Theory for Non-Ideal Systems. In: Thermodynamics and Fluctuations far from Equilibrium. Springer Series in chemical physics, vol 90. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-74555-6_9
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DOI: https://doi.org/10.1007/978-3-540-74555-6_9
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