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Characterization of Graphene by Confocal Raman Spectroscopy

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Confocal Raman Microscopy

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 66))

Abstract

Confocal Raman spectroscopy has emerged as a key characterization technique in graphene research, as with this technique important material characteristics can be obtained locally and noninvasively. In this chapter, the fundamentals of the Raman spectrum of graphene are reviewed and the utilization of Raman spectroscopy for graphene characterization is demonstrated. In this regard, we show how crucial properties of graphene samples, i.e. doping , strain , defect-density and layer-number can be extracted from the Raman spectrum. Accessing these quantities is highly relevant for monitoring, understanding and improving graphene synthesis processes and device fabrication techniques for research and emerging industrial applications.

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Notes

  1. 1.

    The ‘D’ here indeed stands for defect.

References

  1. K.S. Novoselov, A.K. Geim, S. Morozov, D. Jiang, Y. Zhang, S. Dubonos, I. Grigorieva, A. Firsov, Science 306(5696), 666 (2004)

    Article  ADS  Google Scholar 

  2. A.K. Geim, K.S. Novoselov, Nat. Mater. 6(3), 183 (2007)

    Article  ADS  Google Scholar 

  3. A. Geim, I. Grigorieva, Nature 499(7459), 419 (2013)

    Article  Google Scholar 

  4. L. Britnell, R. Gorbachev, R. Jalil, B. Belle, F. Schedin, A. Mishchenko, T. Georgiou, M. Katsnelson, L. Eaves, S. Morozov et al., Science 335(6071), 947 (2012)

    Article  ADS  Google Scholar 

  5. B. Hunt, J. Sanchez-Yamagishi, A. Young, M. Yankowitz, B.J. LeRoy, K. Watanabe, T. Taniguchi, P. Moon, M. Koshino, P. Jarillo-Herrero et al., Science 340(6139), 1427 (2013)

    Article  ADS  Google Scholar 

  6. B.W. Baugher, H.O. Churchill, Y. Yang, P. Jarillo-Herrero, Nat. Nanotechnol. 9(4), 262 (2014)

    Article  ADS  Google Scholar 

  7. R. Saito, M. Fujita, G. Dresselhaus, U.M. Dresselhaus, Appl. Phys. Lett. 60(18), 2204 (1992)

    Article  ADS  Google Scholar 

  8. D. Basko, S. Piscanec, A. Ferrari, Phys. Rev. B 80(16), 165413 (2009)

    Article  ADS  Google Scholar 

  9. M. Lazzeri, C. Attaccalite, L. Wirtz, F. Mauri, Phys. Rev. B 78(8), 081406 (2008)

    Article  ADS  Google Scholar 

  10. P. Venezuela, M. Lazzeri, F. Mauri, Phys. Rev. B 84(3), 035433 (2011)

    Article  ADS  Google Scholar 

  11. A.C. Ferrari, D.M. Basko, Nat. Nanotechnol. 8(4), 235 (2013)

    Article  ADS  Google Scholar 

  12. M. Mohr, J. Maultzsch, E. Dobardžić, S. Reich, I. Milošević, M. Damnjanović, A. Bosak, M. Krisch, C. Thomsen, Phys. Rev. B 76(3), 035439 (2007)

    Article  ADS  Google Scholar 

  13. J. Maultzsch, S. Reich, C. Thomsen, Phys. Rev. B 70(15), 155403 (2004)

    Article  ADS  Google Scholar 

  14. A. Grüneis, J. Serrano, A. Bosak, M. Lazzeri, S.L. Molodtsov, L. Wirtz, C. Attaccalite, M. Krisch, A. Rubio, F. Mauri et al., Phys. Rev. B 80(8), 085423 (2009)

    Article  ADS  Google Scholar 

  15. S. Piscanec, M. Lazzeri, F. Mauri, A. Ferrari, J. Robertson, Phys. Rev. Lett. 93(18), 185503 (2004)

    Article  ADS  Google Scholar 

  16. S. Piscanec, M. Lazzeri, J. Robertson, A.C. Ferrari, F. Mauri, Phys. Rev. B 75(3), 035427 (2007)

    Article  ADS  Google Scholar 

  17. C. Thomsen, S. Reich, Phys. Rev. Lett. 85(24), 5214 (2000)

    Article  ADS  Google Scholar 

  18. R. Saito, A. Jorio, A. Souza Filho, G. Dresselhaus, M. Dresselhaus, M. Pimenta, Phys. Rev. Lett. 88(2), 027401 (2001)

    Article  ADS  Google Scholar 

  19. O. Frank, M. Mohr, J. Maultzsch, C. Thomsen, I. Riaz, R. Jalil, K.S. Novoselov, G. Tsoukleri, J. Parthenios, K. Papagelis et al., ACS Nano 5(3), 2231 (2011)

    Article  Google Scholar 

  20. S. Berciaud, X. Li, H. Htoon, L.E. Brus, S.K. Doorn, T.F. Heinz, Nano Lett. 13(8), 3517 (2013)

    Article  ADS  Google Scholar 

  21. F. Herziger, M. Calandra, P. Gava, P. May, M. Lazzeri, F. Mauri, J. Maultzsch, Phys. Rev. Lett. 113(18), 187401 (2014)

    Article  ADS  Google Scholar 

  22. M. Mohr, J. Maultzsch, C. Thomsen, Phys. Rev. B 82(20), 201409 (2010)

    Article  ADS  Google Scholar 

  23. D. Graf, F. Molitor, K. Ensslin, C. Stampfer, A. Jungen, C. Hierold, L. Wirtz, Nano Lett. 7(2), 238 (2007)

    Article  ADS  Google Scholar 

  24. A. Ferrari, J. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K. Novoselov, S. Roth, A. Geim, Phys. Rev. Lett. 97(18), 187401 (2006)

    Article  ADS  Google Scholar 

  25. C. Neumann, S. Reichardt, P. Venezuela, M. Drögeler, L. Banszerus, M. Schmitz, K. Watanabe, T. Taniguchi, F. Mauri, B. Beschoten et al., Nat. Commun. 6, 8429 (2015)

    Article  Google Scholar 

  26. L.G. Cançado, A. Jorio, E.M. Ferreira, F. Stavale, C. Achete, R. Capaz, M. Moutinho, A. Lombardo, T. Kulmala, A. Ferrari, Nano Lett. 11(8), 3190 (2011)

    Article  ADS  Google Scholar 

  27. M.M. Lucchese, F. Stavale, E.M. Ferreira, C. Vilani, M. Moutinho, R.B. Capaz, C. Achete, A. Jorio, Carbon 48(5), 1592 (2010)

    Article  Google Scholar 

  28. C. Stampfer, F. Molitor, D. Graf, K. Ensslin, A. Jungen, C. Hierold, L. Wirtz, Appl. Phys. Lett. 91(24), 241907 (2007)

    Article  ADS  Google Scholar 

  29. J. Yan, Y. Zhang, P. Kim, A. Pinczuk, Phys. Rev. Lett. 98(16), 166802 (2007)

    Article  ADS  Google Scholar 

  30. G. Froehlicher, S. Berciaud, Phys. Rev. B 91(20), 205413 (2015)

    Article  ADS  Google Scholar 

  31. A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. Saha, U. Waghmare, K. Novoselov, H. Krishnamurthy, A. Geim, A. Ferrari et al., Nat. Nanotechnol. 3(4), 210 (2008)

    Article  Google Scholar 

  32. M. Lazzeri, F. Mauri, Phys. Rev. Lett. 97(26), 266407 (2006)

    Article  ADS  Google Scholar 

  33. S. Pisana, M. Lazzeri, C. Casiraghi, K.S. Novoselov, A.K. Geim, A.C. Ferrari, F. Mauri, Nat. Mater. 6(3), 198 (2007)

    Article  ADS  Google Scholar 

  34. T. Mohiuddin, A. Lombardo, R. Nair, A. Bonetti, G. Savini, R. Jalil, N. Bonini, D. Basko, C. Galiotis, N. Marzari, Phys. Rev. B 79(20), 205433 (2009)

    Article  ADS  Google Scholar 

  35. M. Mohr, K. Papagelis, J. Maultzsch, C. Thomsen, Phys. Rev. B 80(20), 205410 (2009)

    Article  ADS  Google Scholar 

  36. J. Zabel, R.R. Nair, A. Ott, T. Georgiou, A.K. Geim, K.S. Novoselov, C. Casiraghi, Nano Lett. 12(2), 617 (2012)

    Article  ADS  Google Scholar 

  37. D. Yoon, Y.W. Son, H. Cheong, Phys. Rev. Lett. 106(15), 155502 (2011)

    Article  ADS  Google Scholar 

  38. G. Tsoukleri, J. Parthenios, K. Papagelis, R. Jalil, A.C. Ferrari, A.K. Geim, K.S. Novoselov, C. Galiotis, Small 5(21), 2397 (2009)

    Article  Google Scholar 

  39. M. Huang, H. Yan, T.F. Heinz, J. Hone, Nano Lett. 10(10), 4074 (2010)

    Article  ADS  Google Scholar 

  40. J.E. Lee, G. Ahn, J. Shim, Y.S. Lee, S. Ryu, Nat. Commun. 3, 1024 (2012)

    Article  ADS  Google Scholar 

  41. S. Engels, B. Terrés, F. Klein, S. Reichardt, M. Goldsche, S. Kuhlen, K. Watanabe, T. Taniguchi, C. Stampfer, Phys. Status Solidi (b) 251(12), 2545 (2014)

    Article  ADS  Google Scholar 

  42. M. Drögeler, F. Volmer, M. Wolter, B. Terrés, K. Watanabe, T. Taniguchi, G. Güntherodt, C. Stampfer, B. Beschoten, Nano Lett. (2014)

    Google Scholar 

  43. L. Banszerus, M. Schmitz, S. Engels, J. Dauber, M. Oellers, F. Haupt, K. Watanabe, T. Taniguchi, B. Beschoten, C. Stampfer, Sci. Adv. 1(6), e1500222 (2015)

    Article  ADS  Google Scholar 

  44. F. Forster, A. Molina-Sanchez, S. Engels, A. Epping, K. Watanabe, T. Taniguchi, L. Wirtz, C. Stampfer, Phys. Rev. B 88, 085419 (2013). https://doi.org/10.1103/PhysRevB.88.085419

    Article  ADS  Google Scholar 

  45. A.V. Kretinin, Y. Cao, J.S. Tu, G. Yu, R. Jalil, K.S. Novoselov, S. Haigh, A. Gholinia, A. Mishchenko, M. Lozada et al., Nano Lett. 14(6), 3270 (2014)

    Article  ADS  Google Scholar 

  46. N.J. Couto, D. Costanzo, S. Engels, D.K. Ki, K. Watanabe, T. Taniguchi, C. Stampfer, F. Guinea, A.F. Morpurgo, Phys. Rev. X 4(4), 041019 (2014)

    Google Scholar 

  47. C. Neumann, S. Reichardt, M. Drögeler, B. Terrés, K. Watanabe, T. Taniguchi, B. Beschoten, S.V. Rotkin, C. Stampfer, Nano Lett. 15(3), 1547 (2015)

    Article  ADS  Google Scholar 

  48. A.C. Ferrari, Solid State Commun. 143(1), 47 (2007)

    Article  ADS  Google Scholar 

  49. S. Reich, C. Thomsen, Philos. Trans. R. Soc. Lond Ser. A: Mat. Phys. Eng. Sci. 362(1824), 2271 (2004)

    Article  ADS  Google Scholar 

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Acknowledgements

The authors wish to thank Sven Reichardt, Marc Drögeler, Luca Banszerus, Michael Schmitz, Donatus Halpaap, Bernat Terrés, Takashi Taniguchi, Kenji Watanabe, Slava V. Rotkin, Francesco Mauri, Pedro Venezuela and Bernd Beschoten, who contributed in different ways to the sample fabrication, measurements and data interpretation shown in this chapter.

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Correspondence to Christoph Neumann .

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Neumann, C., Stampfer, C. (2018). Characterization of Graphene by Confocal Raman Spectroscopy. In: Toporski, J., Dieing, T., Hollricher, O. (eds) Confocal Raman Microscopy. Springer Series in Surface Sciences, vol 66. Springer, Cham. https://doi.org/10.1007/978-3-319-75380-5_8

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