Abstract
In this chapter the advances and problems associated with the preparation, properties and structure of coordination polymers containing metal chelate units are presented and assessed. The crystal engineering, reticular chemistry, metalloligand strategy, columnar-layered strategy, as well as approaches based on supramolecular building blocks and supramolecular building layers in the chemistry of coordination polymers containing metal chelate units are considered. The conventional (solvent evaporation, diffusion, hydro(solvo)thermal, urothermal, ionothermal, microfluidic, surfactant-thermal, in situ spacer methods as well as synthesis in supercritical CO2) and alternative (microwave-assisted, electrochemical, mechanochemical, and sonochemical methods) synthesis routes are described. Special attention is paid to the post-synthetic approaches to the preparation of coordination polymers containing metal chelate units including post-synthetic modification, post-synthetic deprotection, and post-synthetic exchange.
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Dzhardimalieva, G.I., E. Uflyand, I. (2018). Coordination Polymers Containing Metal Chelate Units. In: Chemistry of Polymeric Metal Chelates. Springer Series in Materials Science, vol 257. Springer, Cham. https://doi.org/10.1007/978-3-319-56024-3_6
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DOI: https://doi.org/10.1007/978-3-319-56024-3_6
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