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Synergistic Effect of C12A7 and CA on Alumina Leaching Property Under Low Calcium/Aluminum Ratio

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Light Metals 2015

Abstract

High calcium/aluminum ratio (C/A=12:7) is one of the main problems which inhibit the development of lime sinter process. Decrease the C/A of clinker is studied in this paper. 12CaO•7Al2O3 (C12A7) and CaO•Al2O3 (CA) were synthesized at 1350 °C by analytical pure reagents. The phase composition of sinters was analyzed by XRD and the alumina leaching experiments were carried out. The results show that the optimal alumina leaching ratio of C12A7 and CA are 93.40% and 73.18%. The leaching experiments of the mixture of C12A7 and CA with different proportions were carried out. The alumina leaching ratio of the mixture reaches 91.12% when the content of C12A7 is 40% (in mass). Above this proportion, the alumina leaching ratio increases little. The results show that the existence of C12A7 can promote the leaching property of CA.

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References

  1. P. Smith, “The processing of high silica bauxites-review of existing and potential processes,” Hydrometallurgy, 98(1)(2009), 162–176.

    Article  Google Scholar 

  2. R. Paramguru, P. Rath, V. Misra, “Trends in red mud utilization-A review,” Mineral Processing & Extractive Metall Rev, 26(1)(2004), 1–29.

    Article  Google Scholar 

  3. J. Grzymek, et al. The new way of alumina lixiviation from sinters containing 12CaO.7 Al2O3 in J. Grzymek’s Method [M]. Light Metals 1988: 129–133.

    Google Scholar 

  4. W. Bo, et al., “Effect of material ratio on leaching and self-disintegrating property of calcium aluminate slag,” Journal of Northeastern University: Natural Science, 29(11)(2008), 1593–1596.

    Google Scholar 

  5. Eva Selic, Jan-Dirk Herbell. “Utilization of Fly Ash from Coal-fired Power Plants in China,” Journal of Zhejiang University(Science A), 9(5)(2008): 681–687.

    Article  Google Scholar 

  6. T. Zhi-fang, B. Shi-wen, Y. Hai-yan, “Leaching kinetics of non-constant temperature process of calcium aluminate slag under microwave radiation,” The Chinese Journal of Nonferrous Metals, 16(2)(2006), 357–362.

    Article  Google Scholar 

  7. X. Wei, et al., “Study on the process of extracting alumina from the middling grade bauxite using lime sinter,” Journal of Guizhou University of Technology(Natural Science Edition), 05)(2008), 41–43.

    Google Scholar 

  8. L. Zhi-ying, et al., “Research on the intensified sintering mechanism of middle-grade bauxite and its digestion performances,” Light Metals, 12)(2009), 14–17.

    Google Scholar 

  9. Z. Wu. “Phase composition and leaching law of the sinter of CaO-Al2O3-SiO2 system”. Shenyang; Northeastern University, 2011.

    Google Scholar 

  10. B. M. Mohamed, J. H. Sharp. Kinetics and mechanism of formation of monocalcium aluminate, CaAl2O4. Journal of material chemistry, 7(8)(1997), 1595–1599.

    Article  Google Scholar 

  11. Z. Bai-yong, Z. Feng-lu, “The limestone sintering process to produce alumina with fly ash”. Light Metals, (6)2007, 17–19.

    Google Scholar 

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© 2015 TMS (The Minerals, Metals & Materials Society)

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Bo, W., Jiajia, L., Huilan, S., Yubing, Z., Dongdong, L. (2015). Synergistic Effect of C12A7 and CA on Alumina Leaching Property Under Low Calcium/Aluminum Ratio. In: Hyland, M. (eds) Light Metals 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-48248-4_11

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