Abstract
This chapter summarizes the investigations of the endohedral metallofullerenes (EMFs) with a C80 carbon shell in view of their magnetic properties, where the recently discovered single-molecule magnetism in dysprosium based species are highlighted.
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References
Kroto HW, Heath JR, O’Brien SC et al (1985) C60—Buckminsterfullerene. Nature 318(6042):162–163
Nakao K, Kurita N, Fujita M (1994) Ab-initio molecular-orbital calculation for C70 and seven isomers of C80. Phys Rev B 49(16):11415–11420
Stevenson S, Rice G, Glass T et al (1999) Small-bandgap endohedral metallofullerenes in high yield and purity. Nature 401(6748):55–57
Svitova AL, Ghiassi K, Schlesier C et al (2014) Endohedral fullerene with μ3-carbido ligand and titanium-carbon double bond stabilized inside a carbon cage. Nat Commun 5:3568
Junghans K, Schlesier C, Kostanyan A et al (2015) Methane as a selectivity booster in the arc-discharge synthesis of endohedral fullerenes: selective synthesis of the single-molecule magnet Dy2TiC@C80 and Its congener Dy2TiC2@C80. Angew Chem-Int Edit Engl 54(45):13411–13415
Rinehart JD, Long JR (2011) Exploiting single-ion anisotropy in the design of f-element single-molecule magnets. Chem Sci 2(11):2078–2085
Shu C, Corwin FD, Zhang J et al (2009) Facile preparation of a new gadofullerene-based magnetic resonance imaging contrast agent with high 1H relaxivity. Bioconjugate Chem 20(6):1186–1193
Náfrádi B, Antal Á, Pásztor Á et al (2012) Molecular and spin dynamics in the paramagnetic endohedral fullerene Gd3N@C80. J Phys Chem Lett 3:3291–3296
Svitova AL, Krupskaya Y, Samoylova N et al (2014) Magnetic moments and exchange coupling in nitride clusterfullerenes Gd x Sc3-x N@C80 (x = 1-3). Dalton Trans 43:7387–7390
Tiwari A, Dantelle G, Porfyrakis K et al (2008) Magnetic properties of ErSc2N@C80, Er2ScN@C80 and Er3N@C80 fullerenes. Chem Phys Lett 466:155–158
Zuo T, Olmstead MM, Beavers CM et al (2008) Preparation and structural characterization of the I h and the D 5h isomers of the endohedral fullerenes Tm3N@C80: icosahedral C80 cage encapsulation of a trimetallic nitride magnetic cluster with three uncoupled Tm3+ Ions. Inorg Chem 47(12):5234–5244
Wolf M, Muller KH, Eckert D et al (2005) Magnetic moments in Ho3N@C80 and Tb3N@C80. J Magn Magn Mater 290:290–293
Wolf M, Muller KH, Skourski Y et al (2005) Magnetic moments of the endohedral cluster fullerenes Ho3N@C80 and Tb3N@C80: the role of ligand fields. Angew Chem-Int Edit 44(21):3306–3309
Sessoli R, Gatteschi D, Caneschi A et al (1993) Magnetic bistability in a metal-ion cluster. Nature 365(6442):141–143
Gatteschi D, Sessoli R, Villain J (2006) Molecular nanomagnets. Oxford University Press, New York
Ishikawa N, Sugita M, Ishikawa T et al (2003) Lanthanide double-decker complexes functioning as magnets at the single-molecular level. J Am Chem Soc 125:8694–8695
Westerström R, Dreiser J, Piamonteze C et al (2012) An endohedral single-molecule magnet with long relaxation times: DySc2N@C80. J Am Chem Soc 134(24):9840–9843
Dreiser J, Westerström R, Piamonteze C et al (2014) X-ray induced demagnetization of single-molecule magnets. Appl Phys Lett 105(3):032411
Westerström R, Dreiser J, Piamonteze C et al (2014) Tunneling, remanence, and frustration in dysprosium-based endohedral single-molecule magnets. Phys Rev B 89(6):060406
Dreiser J, Westerström R, Zhang Y et al (2014) The metallofullerene field-induced single-ion magnet HoSc2N@C80. Chem-Eur J 20(42):13536–13540
Vieru V, Ungur L, Chibotaru LF (2013) Key role of frustration in suppression of magnetization blocking in single-molecule magnets. J Phys Chem Lett 4(21):3565–3569
Cimpoesu F, Dragoe N, Ramanantoanina H et al (2014) The theoretical account of the ligand field bonding regime and magnetic anisotropy in the DySc2N@C80 single ion magnet endohedral fullerene. Phys Chem Chem Phys 16:11337–11348
Westerström R, Popov A, Greber T (2015) An operational definition of the 100 second blocking temperature TB100 for single molecule magnets. arXiv:150603657
Rinehart JD, Fang M, Evans WJ et al (2011) Strong exchange and magnetic blocking in N2 3−-radical-bridged lanthanide complexes. Nat Chem 3(7):538–542
Rinehart JD, Fang M, Evans WJ et al (2011) A N2 3– radical-bridged terbium complex exhibiting magnetic Hysteresis at 14 K. J Am Chem Soc 133(36):14236–14239
Le Roy JJ, Ungur L, Korobkov I et al (2014) Coupling strategies to enhance single-molecule magnet properties of erbium-cyclooctatetraenyl complexes. J Am Chem Soc 136(22):8003–8010
Leuenberger MN, Loss D (2001) Quantum computing in molecular magnets. Nature 410(6830):789–793
Bogani L, Wernsdorfer W (2008) Molecular spintronics using single-molecule magnets. Nat Mater 7(3):179–186
Butcher MJ, Nolan JW, Hunt MRC et al (2003) Adsorption and manipulation of endohedral and higher fullerenes on Si(100)-2x1. Phys Rev B 67(12):125413
Huang T, Zhao J, Feng M et al (2012) A multi-state single-molecule switch actuated by rotation of an encapsulated cluster within a fullerene cage. Chem Phys Lett 552:1–12
Yasutake Y, Shi ZJ, Okazaki T et al (2005) Single molecular orientation switching of an endohedral metallofullerene. Nano Lett 5(6):1057–1060
Treier M, Ruffieux P, Fasel R et al (2009) Looking inside an endohedral fullerene: inter- and intramolecular ordering of Dy3N@C80 (I h ) on Cu(111). Phys Rev B 80:081403
Westerström R, Uldry A-C, Stania R et al (2015) Surface aligned magnetic moments and hysteresis of an endohedral single-molecule magnet on a metal. Phys Rev Lett 114:087201
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Westerström, R., Greber, T. (2017). Magnetic Properties of C80 Endofullerenes. In: Popov, A. (eds) Endohedral Fullerenes: Electron Transfer and Spin. Nanostructure Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-47049-8_11
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DOI: https://doi.org/10.1007/978-3-319-47049-8_11
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