Abstract
Carbon based dots (CDs) composed of sp2 carbon structures and surface functional groups are a new kind of carbon nanomaterials, exhibiting unique luminescent properties due to the quantum confinement and edge effects. This chapter introduces CDs in detail from their synthetic strategies, morphological and structural characteristics, luminescent properties and mechanisms, and sensing applications. The synthesis methods are summarized as “top-down” and “bottom-up” approaches. Luminescent properties discussed include photoluminescence, upconversion luminescence, chemiluminescence, electrochemiluminescence. Sensing applications mainly refer to the chemical and biological sensors based on the luminescent properties of CDs. This chapter provides an overview of the research field and gives future perspectives for developing the exciting materials.
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References
S.N. Baker, G.A. Baker, Luminescent carbon nanodots: emergent nanolights. Angew. Chem. Int. Ed. 49(38), 6726–6744 (2010). doi:10.1002/anie.200906623
Y. Xu, J. Liu, C. Gao, E. Wang, Applications of carbon quantum dots in electrochemiluminescence: a mini review. Electrochem. Commun. 48, 151–154 (2014). doi:10.1016/j.elecom.2014.08.032
X. Yan, B.S. Li, L.S. Li, Colloidal graphene quantum dots with well-defined structures. Acc. Chem. Res. 46(10), 2254–2262 (2013). doi:10.1021/ar300137p
H.J. Sun, L. Wu, W.L. Wei, X.G. Qu, Recent advances in graphene quantum dots for sensing. Mater. Today 16(11), 433–442 (2013). doi:10.1016/j.mattod.2013.10.020
M. Bacon, S.J. Bradley, T. Nann, Graphene quantum dots. Part. Part. Syst. Char. 31(4), 415–428 (2014). doi:10.1002/ppsc.201300252
L. Cao, M.J. Meziani, S. Sahu, Y.P. Sun, Photoluminescence properties of graphene versus other carbon nanomaterials. Acc. Chem. Res. 46(1), 171–180 (2012). doi:10.1021/ar300128j
H.T. Li, Z.H. Kang, Y. Liu, S.T. Lee, Carbon nanodots: synthesis, properties and applications. J. Mater. Chem. 22(46), 24230–24253 (2012). doi:10.1039/c2jm34690g
X.Y. Xu, R. Ray, Y.L. Gu, H.J. Ploehn, L. Gearheart, K. Raker, W.A. Scrivens, Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments. J. Am. Chem. Soc. 126(40), 12736–12737 (2004). doi:10.1021/ja040082h
Y.P. Sun, B. Zhou, Y. Lin, W. Wang, K.A.S. Fernando, P. Pathak, M.J. Meziani, B.A. Harruff, X. Wang, H.F. Wang, Quantum-sized carbon dots for bright and colorful photoluminescence. J. Am. Chem. Soc. 128(24), 7756–7757 (2006). doi:10.1021/ja062677d
A.B. Bourlinos, R. Zbořil, J. Petr, A. Bakandritsos, M. Krysmann, E.P. Giannelis, Luminescent surface quaternized carbon dots. Chem. Mater. 24(1), 6–8 (2012). doi:10.1021/cm2026637
F. Wang, S. Pang, L. Wang, Q. Li, M. Kreiter, C.Y. Liu, One-step synthesis of highly luminescent carbon dots innoncoordinating solvents. Chem. Mater. 22(16), 4528–4530 (2010). doi:10.1021/cm101350u
X. Chen, W. Zhang, Q. Wang, J. Fan, C8-structured carbon quantum dots: synthesis, blue and green double luminescence, and origins of surface defects. Carbon 79, 165–173 (2014). doi:10.1016/j.carbon.2014.07.056
S. Chandra, S.H. Pathan, S. Mitra, B.H. Modha, A. Goswami, P. Pramanik, Tuning of photoluminescence on different surface functionalized carbon quantum dots. RSC Adv. 2(9), 3602–3606 (2012). doi:10.1039/c2ra00030j
X.M. Wen, P. Yu, Y.R. Toh, X.Q. Ma, J. Tang, On the upconversion fluorescence in carbon nanodots and graphene quantum dots. Chem. Commun. 50(36), 4703–4706 (2014). doi:10.1039/c4cc01213e
A.B. Bourlinos, A. Stassinopoulos, D. Anglos, R. Zboril, V. Georgakilas, E.P. Giannelis, Photoluminescent carbogenic dots. Chem. Mater. 20(14), 4539–4541 (2008). doi:10.1021/cm800506r
A.B. Bourlinos, A. Stassinopoulos, D. Anglos, R. Zboril, M. Karakassides, E.P. Giannelis, Surface functionalized carbogenic quantum dots. Small 4(4), 455–458 (2008). doi:10.1002/smll.200700578
Y.F. Wang, A.G. Hu, Carbon quantum dots: synthesis, properties and applications. J. Mater. Chem. C 2(34), 6921–6939 (2014). doi:10.1039/c4tc00988f
Y.B. Song, S.J. Zhu, B. Yang, Bioimaging based on fluorescent carbon dots. RSC Adv. 4(52), 27184–27200 (2014). doi:10.1039/c3ra47994c
K. Hola, Y. Zhang, Y. Wang, E.P. Giannelis, R. Zboril, A.L. Rogach, Carbon dots—emerging light emitters for bioimaging, cancer therapy and optoelectronics. Nano Today 9(5), 590–603 (2014). doi:10.1016/j.nantod.2014.09.004
J.C.G. Esteves da Silva, H.M.R. Gonçalves, Analytical and bioanalytical applications of carbon dots. TrAC Trends Anal. Chem. 30(8), 1327–1336 (2011). doi:10.1016/j.trac.2011.04.009
L.A. Ponomarenko, F. Schedin, M.I. Katsnelson, R. Yang, E.W. Hill, K.S. Novoselov, A.K. Geim, Chaotic dirac billiard in graphene quantum dots. Science 320(5874), 356–358 (2008). doi:10.1126/science.1154663
D. Pan, J. Zhang, Z. Li, M. Wu, Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots. Adv. Mater. 22(6), 734–738 (2010). doi:10.1002/adma.200902825
S. Zhu, S. Tang, J. Zhang, B. Yang, Control the size and surface chemistry of graphene for the rising fluorescent materials. Chem. Commun. 48(38), 4527–4539 (2012). doi:10.1039/c2cc31201h
X. Zhou, S. Guo, J. Zhang, Solution-processable graphene quantum dots. ChemPhysChem 14(12), 2627–2640 (2013). doi:10.1002/cphc.201300111
Z. Zhang, J. Zhang, N. Chen, L. Qu, Graphene quantum dots: an emerging material for energy-related applications and beyond. Energ. Environ. Sci. 5(10), 8869–8895 (2012). doi:10.1039/c2ee22982j
X. Wang, G. Sun, P. Routh, D.H. Kim, W. Huang, P. Chen, Heteroatom-doped graphene materials: syntheses, properties and applications. Chem. Soc. Rev. 43(20), 7067–7098 (2014). doi:10.1039/c4cs00141a
J. Shen, Y. Zhu, X. Yang, C. Li, Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices. Chem. Commun. 48(31), 3686–3699 (2012). doi:10.1039/c2cc00110a
L. Lin, M. Rong, F. Luo, D. Chen, Y. Wang, X. Chen, Luminescent graphene quantum dots as new fluorescent materials for environmental and biological applications. TrAC Trends Anal. Chem. 54, 83–102 (2014). doi:10.1016/j.trac.2013.11.001
L. Li, G. Wu, G. Yang, J. Peng, J. Zhao, J.J. Zhu, Focusing on luminescent graphene quantum dots: current status and future perspectives. Nanoscale 5(10), 4015–4039 (2013). doi:10.1039/c3nr33849e
J.L. Li, B. Tang, B. Yuan, L. Sun, X.G. Wang, A review of optical imaging and therapy using nanosized graphene and graphene oxide. Biomaterials 34(37), 9519–9534 (2013). doi:10.1016/j.biomaterials.2013.08.066
J. Guttinger, F. Molitor, C. Stampfer, S. Schnez, A. Jacobsen, S. Droscher, T. Ihn, K. Ensslin, Transport through graphene quantum dots. Rep. Prog. Phys. 75(12), 126502 (2012). doi:10.1088/0034-4885/75/12/126502
S.L. Hu, K.Y. Niu, J. Sun, J. Yang, N.Q. Zhao, X.W. Du, One-step synthesis of fluorescent carbon nanoparticles by laser irradiation. J. Mater. Chem. 19(4), 484–488 (2009). doi:10.1039/b812943f
X. Wang, L. Cao, F. Lu, M.J. Meziani, H. Li, G. Qi, B. Zhou, B.A. Harruff, F. Kermarrec, Y.P. Sun, Photoinduced electron transfers with carbon dots. Chem. Commun. 25, 3774–3776 (2009). doi:10.1039/b906252a
S.T. Yang, X. Wang, H.F. Wang, F.S. Lu, P.J.G. Luo, L. Cao, M.J. Meziani, J.H. Liu, Y.F. Liu, M. Chen, Carbon dots as nontoxic and high-performance fluorescence imaging agents. J. Phys. Chem. C 113(42), 18110–18114 (2009). doi:10.1021/jp9085969
S.T. Yang, L. Cao, P.G.J. Luo, F.S. Lu, X. Wang, H.F. Wang, M.J. Meziani, Y.F. Liu, G. Qi, Y.P. Sun, Carbon dots for optical imaging in vivo. J. Am. Chem. Soc. 131(32), 11308–11309 (2009). doi:10.1021/ja904843x
Q. Li, T.Y. Qhulchanskyy, R.L. Liu, K. Koynov, D.Q. Wu, A. Best, R. Kumar, A. Bonoiu, P.N. Prasad, Photoluminescent carbon dots as biocompatible nanoprobes for targeting cancer cells. J. Phys. Chem. C 114(28), 12062–12068 (2010). doi:10.1021/jp911539r
L. Cao, X. Wang, M.J. Meziani, F.S. Lu, H.F. Wang, P.J.G. Luo, Y. Lin, B.A. Harruff, L.M. Veca, D. Murray, Carbon dots for nultiphoton bioimaging. J. Am. Chem. Soc. 129(37), 11318–11319 (2007). doi:10.1021/ja073527l
H. Liu, T. Ye, C. Mao, Fluorescent carbon nanoparticles derived from candle soot. Angew. Chem. Int. Ed. 46(34), 6473–6475 (2007). doi:10.1002/anie.200701271
S.C. Ray, A. Saha, N.R. Jana, R. Sarkar, Fluorescent carbon nanoparticles: synthesis, characterization, and bioimaging application. J. Phys. Chem. C 113(43), 18546–18551 (2009). doi:10.1021/jp905912n
X.H. Wang, K.G. Qu, B.L. Xu, J.S. Ren, X.G. Qu, Multicolor luminescent carbon nanoparticles: synthesis, supramolecular assembly with porphyrin, intrinsic peroxidase-like catalytic activity and applications. Nano Res. 4(9), 908–920 (2011). doi:10.1007/s12274-011-0147-4
M. Tan, L. Zhang, R. Tang, X. Song, Y. Li, H. Wu, Y. Wang, G. Lv, W. Liu, X. Ma, Enhanced photoluminescence and characterization of multicolor carbon dots using plant soot as a carbon source. Talanta 115, 950–956 (2013). doi:10.1016/j.talanta.2013.06.061
L. Tian, D. Ghosh, W. Chen, S. Pradhan, X.J. Chang, S.W. Chen, Nanosized carbon particles from natural gas soot. Chem. Mater. 21(13), 2803–2809 (2009). doi:10.1021/cm900709w
J.M. Berlin, T.T. Pham, D. Sano, K.A. Mohamedali, D.C. Marcano, J.N. Myers, J.M. Tour, Noncovalent functionalization of carbon nanovectors with an antibody enables targeted drug delivery. ACS Nano 5(8), 6643–6650 (2011). doi:10.1021/nn2021293
Y. Dong, N. Zhou, X. Lin, J. Lin, Y. Chi, G. Chen, Extraction of electrochemiluminescent oxidized carbon quantum dots from activated carbon. Chem. Mater. 22(21), 5895–5899 (2010). doi:10.1021/cm1018844
Y. Dong, C. Chen, X. Zheng, L. Gao, Z. Cui, H. Yang, C. Guo, Y. Chi, C.M. Li, One-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black. J Mater Chem C 22(18), 8764–8766 (2012). doi:10.1039/c2jm30658a
Y. Dong, J. Lin, Y. Chen, F. Fu, Y. Chi, G. Chen, Graphene quantum dots, graphene oxide, carbon quantum dots and graphite nanocrystals in coals. Nanoscale 6(13), 7410–7415 (2014). doi:10.1039/c4nr01482k
Z.A. Qiao, Y. Wang, Y. Gao, H. Li, T. Dai, Y. Liu, Q. Huo, Commercially activated carbon as the source for producing multicolor photoluminescent carbon dots by chemical oxidation. Chem. Commun. 46(46), 8812–8814 (2010). doi:10.1039/c0cc02724c
Y. Dong, C.X. Guo, Y. Chi, C.M. Li, Reply to comment on “one-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black”. J. Mater. Chem. 22(40), 21777–21778 (2012). doi:10.1039/c2jm34130a
P. Teng, J. Xie, Y. Long, X. Huang, R. Zhu, X. Wang, L. Liang, Y. Huang, H. Zheng, Chemiluminescence behavior of the carbon dots and the reduced state carbon dots. J. Lumin. 146, 464–469 (2014). doi:10.1016/j.jlumin.2013.09.036
R. Liu, D. Wu, X. Feng, K. Mullen, Bottom-up fabrication of photoluminescent graphene quantum dots with uniform morphology. J. Am. Chem. Soc. 133(39), 15221–15223 (2011). doi:10.1021/ja204953k
W.S. Hummers, R.E. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80(6), 1339 (1958). doi:10.1021/ja01539a017
J. Peng, W. Gao, B.K. Gupta, Z. Liu, R. Romero-Aburto, L. Ge, L. Song, L.B. Alemany, X. Zhan, G. Gao, S.A. Vithayathil, B.A. Kaipparettu, A.A. Marti, T. Hayashi, J.J. Zhu, P.M. Ajayan, Graphene quantum dots derived from carbon fibers. Nano Lett. 12(2), 844–849 (2012). doi:10.1021/nl2038979
D.V. Kosynkin, A.L. Higginbotham, A. Sinitskii, J.R. Lomeda, A. Dimiev, B.K. Price, J.M. Tour, Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature 458(7240), 872–876 (2009). doi:10.1038/nature07872
S.J. Zhuo, M.W. Shao, S.T. Lee, Upconversion and downconversion gluorescent graphene quantum dots. ACS Nano 6(2), 1059–1064 (2012). doi:10.1021/nn2040395
D. Pan, L. Guo, J. Zhang, C. Xi, Q. Xue, H. Huang, J. Li, Z. Zhang, W. Yu, Z. Chen, Z. Li, M. Wu, Cutting sp2 clusters in graphene sheets into colloidal graphene quantum dots with strong green fluorescence. J. Mater. Chem. 22(8), 3314–3318 (2012). doi:10.1039/c2jm16005f
S. Kim, S.W. Hwang, M.K. Kim, D.Y. Shin, D.H. Shin, C.O. Kim, S.B. Yang, J.H. Park, E. Hwang, S.H. Choi, Anomalous behaviors of visible luminescence from graphene quantum dots: interplay between size and shape. ACS Nano 6(9), 8203–8208 (2012). doi:10.1021/nn302878r
L.L. Li, J. Ji, R. Fei, C.Z. Wang, Q. Lu, J.R. Zhang, L.P. Jiang, J.J. Zhu, A facile microwave avenue to electrochemiluminescent two-color graphene quantum dots. Adv. Funct. Mater. 22(14), 2971–2979 (2012). doi:10.1002/adfm.201200166
M. Nurunnabi, Z. Khatun, K.M. Huh, S.Y. Park, D.Y. Lee, K.J. Cho, Y.K. Lee, In vivo biodistribution and toxicology of carboxylated graphene quantum dots. ACS Nano 7(8), 6858–6867 (2013). doi:10.1021/nn402043c
M. Nurunnabi, Z. Khatun, M. Nafiujjaman, D.G. Lee, Y.K. Lee, Surface coating of graphene quantum dots using mussel-inspired polydopamine for biomedical optical imaging. ACS Appl. Mater. Inter. 5(16), 8246–8253 (2013). doi:10.1021/am4023863
Z.S. Qian, X.Y. Shan, L.J. Chai, J.J. Ma, J.R. Chen, H. Feng, A universal fluorescence sensing strategy based on biocompatible graphene quantum dots and graphene oxide for the detection of DNA. Nanoscale 6(11), 5671–5674 (2014). doi:10.1039/c3nr06583a
Y. Sun, S. Wang, C. Li, P. Luo, L. Tao, Y. Wei, G. Shi, Large scale preparation of graphene quantum dots from graphite with tunable fluorescence properties. Phys. Chem. Chem. Phys. 15(24), 9907–9913 (2013). doi:10.1039/c3cp50691f
R. Ye, C. Xiang, J. Lin, Z. Peng, K. Huang, Z. Yan, N.P. Cook, E.L. Samuel, C.C. Hwang, G. Ruan, G. Ceriotti, A.R. Raji, A.A. Marti, J.M. Tour, Coal as an abundant source of graphene quantum dots. Nat. Commun. 4, 2943 (2013). doi:10.1038/ncomms3943
M. Wu, Y. Wang, W. Wu, C. Hu, X. Wang, J. Zheng, Z. Li, B. Jiang, J. Qiu, Preparation of functionalized water-soluble photoluminescent carbon quantum dots from petroleum coke. Carbon 78, 480–489 (2014). doi:10.1016/j.carbon.2014.07.029
X.J. Zhou, Y. Zhang, C. Wang, X.C. Wu, Y.Q. Yang, B. Zheng, H.X. Wu, S.W. Guo, J.Y. Zhang, Photo-fenton reaction of graphene oxide: a new strategy to prepare graphene quantum dots for DNA cleavage. ACS Nano 6(8), 6592–6599 (2012)
K. Ikehata, M.G. EI-Din, Aqueous pesticide degradation by hydrogen peroxide ultraviolet irradiation and Fenton-type advanced oxidation processes: a review. Environ. Eng. Sci. 5(2), 81–135 (2006). doi:10.1139/S05-046
J.G. Zhou, C. Booker, R.Y. Li, X.T. Zhou, T.K. Sham, X.L. Sun, Z.F. Ding, An electrochemical avenue to blue luminescent nanocrystals from multiwalled carbon nanotubes (MWCNTs). J. Am. Chem. Soc. 129(4), 744–745 (2007). doi:10.1021/ja0669070
Q.L. Zhao, Z.L. Zhang, B.H. Huang, J. Peng, M. Zhang, D.W. Pang, Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite. Chem. Commun. 41, 5116–5118 (2008). doi:10.1039/b812420e
L. Zheng, Y. Chi, Y. Dong, J. Lin, B. Wang, Electrochemiluminescence of water-soluble carbon nanocrystals released electrochemically from graphite. J. Am. Chem. Soc. 131(13), 4564–4565 (2009). doi:10.1021/ja809073f
H. Li, X. He, Z. Kang, H. Huang, Y. Liu, J. Liu, S. Lian, C.H. Tsang, X. Yang, S.T. Lee, Water-soluble fluorescent carbon quantum dots and photocatalyst design. Angew. Chem. Int. Ed. 49(26), 4430–4434 (2010). doi:10.1002/anie.200906154
J. Lu, J.X. Yang, J.Z. Wang, A.L. Lim, S. Wang, K.P. Loh, One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids. ACS Nano 3(8), 2367–2375 (2009). doi:10.1021/nn900546b
Y. Li, Y. Hu, Y. Zhao, G. Shi, L. Deng, Y. Hou, L. Qu, An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics. Adv. Mater. 23(6), 776–780 (2011). doi:10.1002/adma.201003819
Y. Li, Y. Zhao, H. Cheng, Y. Hu, G. Shi, L. Dai, L. Qu, Nitrogen-doped graphene quantum dots with oxygen-rich functional groups. J. Am. Chem. Soc. 134(1), 15–18 (2012). doi:10.1021/ja206030c
L. Bao, Z.L. Zhang, Z.Q. Tian, L. Zhang, C. Liu, Y. Lin, B. Qi, D.W. Pang, Electrochemical tuning of luminescent carbon nanodots: from preparation to luminescence mechanism. Adv. Mater. 23(48), 5801–5806 (2011). doi:10.1002/adma.201102866
M. Zhang, L. Bai, W. Shang, W. Xie, H. Ma, Y. Fu, D. Fang, H. Sun, L. Fan, M. Han, C. Liu, S. Yang, Facile synthesis of water-soluble, highly fluorescent graphene quantum dots as a robust biological label for stem cells. J. Am. Chem. Soc. 22(15), 7461–7467 (2012). doi:10.1039/c2jm16835a
D.B. Shinde, V.K. Pillai, Electrochemical resolution of multiple redox events for graphene quantum dots. Angew. Chem. Int. Ed. 52(9), 2482–2485 (2013). doi:10.1002/anie.201208904
D.B. Shinde, V.K. Pillai, Electrochemical preparation of luminescent graphene quantum dots from multiwalled carbon nanotubes. Chem. Eur. J. 18(39), 12522–12528 (2012). doi:10.1002/chem.201201043
D.V. Kosynkin, A.L. Higginboham, A. Sinitskii, J.R. Lomeda, A. Dimiev, B.K. Price, J.M. Tour, Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature 458(7240), 872–876 (2009). doi:10.1038/nature07872
Y. Dong, H. Pang, S. Ren, C. Chen, Y. Chi, T. Yu, Etching single-wall carbon nanotubes into green and yellow single-layer graphene quantum dots. Carbon 64, 245–251 (2013). doi:10.1016/j.carbon.2013.07.059
F. Yang, M. Zhao, B. Zheng, D. Xiao, L. Wu, Y. Guo, Influence of pH on the fluorescence properties of graphene quantum dots using ozonation pre-oxide hydrothermal synthesis. J. Mater. Chem. 22(48), 25471–25479 (2012). doi:10.1039/c2jm35471c
H. Tetsuka, R. Asahi, A. Nagoya, K. Okamoto, I. Tajima, R. Ohta, A. Okamoto, Optically tunable amino-functionalized graphene quantum dots. Adv. Mater. 24(39), 5333–5338 (2012). doi:10.1002/adma.201201930
S. Zhu, J. Zhang, C. Qiao, S. Tang, Y. Li, W. Yuan, B. Li, L. Tian, F. Liu, R. Hu, H. Gao, H. Wei, H. Zhang, H. Sun, B. Yang, Strongly green-photoluminescent graphene quantum dots for bioimaging applications. Chem. Commun. 47(24), 6858–6860 (2011). doi:10.1039/c1cc11122a
L. Lin, S. Zhang, Creating high yield water soluble luminescent graphene quantum dots via exfoliating and disintegrating carbon nanotubes and graphite flakes. Chem. Commun. 48(82), 10177–10179 (2012). doi:10.1039/c2cc35559k
X. Zhu, H. Wang, Q. Jiao, X. Xiao, X. Zuo, Y. Liang, J. Nan, J. Wang, L. Wang, Preparation and characterization of the fluorescent carbon dots derived from the lithium-Intercalated graphite used for cell Imaging. Part. Part. Syst. Char. 31(7), 771–777 (2014). doi:10.1002/ppsc.201300327
J. Lee, K. Kim, W.I. Park, B.H. Kim, J.H. Park, T.H. Kim, S. Bong, C.H. Kim, G. Chae, M. Jun, Y. Hwang, Y.S. Jung, S. Jeon, Uniform graphene quantum dots patterned from self-assembled silica nanodots. Nano Lett. 12(12), 6078–6083 (2012). doi:10.1021/nl302520m
H. Li, X. He, Y. Liu, H. Yu, Z. Kang, S.-T. Lee, Synthesis of fluorescent carbon nanoparticles directly from active carbon via a one-step ultrasonic treatment. Mater. Res. Bull. 46(1), 147–151 (2011). doi:10.1016/j.materresbull.2010.10.013
F. Liu, M.H. Jang, H.D. Ha, J.H. Kim, Y.H. Cho, T.S. Seo, Facile synthetic method for pristine graphene quantum dots and graphene oxide quantum dots: origin of blue and green luminescence. Adv. Mater. 25(27), 3657–3662 (2013). doi:10.1002/adma.201300233doi:10.1002/adma.201300233
Y. Dong, H. Pang, H.B. Yang, C. Guo, J. Shao, Y. Chi, C.M. Li, T. Yu, Carbon-based dots co-doped with nitrogen and sulfur for high quantum yield and excitation-independent emission. Angew. Chem. Int. Ed. 52(30), 7800–7804 (2013). doi:10.1002/anie.201301114
S. Zhu, Q. Meng, L. Wang, J. Zhang, Y. Song, H. Jin, K. Zhang, H. Sun, H. Wang, B. Yang, Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew. Chem. Int. Ed. 52(14), 3953–3957 (2013). doi:10.1002/anie.201300519
M.J. Krysmann, A. Kelarakis, P. Dallas, E.P. Giannelis, Formation mechanism of carbogenic nanoparticles with dual photoluminescence emission. J. Am. Chem. Soc. 134(2), 747–750 (2012). doi:10.1021/ja204661r
D. Qu, M. Zheng, P. Du, Y. Zhou, L. Zhang, D. Li, H. Tan, Z. Zhao, Z. Xie, Z. Sun, Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts. Nanoscale 5(24), 12272–12277 (2013). doi:10.1039/c3nr04402e
H. Zhang, Y. Chen, M. Liang, L. Xu, S. Qi, H. Chen, X. Chen, Solid-phase synthesis of highly fluorescent nitrogen-doped carbon dots for sensitive and selective probing ferric ions in living cells. Anal. Chem. 86(19), 9846–9852 (2014). doi:10.1021/ac502446m
M. Amjadi, J.L. Manzoori, T. Hallaj, M.H. Sorouraddin, Direct chemiluminescence of carbon dots induced by potassium ferricyanide and its analytical application. Spectrochimi. Acta A 122, 715–720 (2014). doi:10.1016/j.saa.2013.11.097
Y. Guo, Z. Wang, H. Shao, X. Jiang, Hydrothermal synthesis of highly fluorescent carbon nanoparticles from sodium citrate and their use for the detection of mercury ions. Carbon 52, 583–589 (2013). doi:10.1016/j.carbon.2012.10.028
K. Qu, J. Wang, J. Ren, X. Qu, Carbon dots prepared by hydrothermal treatment of dopamine as an effective fluorescent sensing platform for the label-free detection of iron(III) ions and dopamine. Chem. Eur. J. 19(22), 7243–7249 (2013). doi:10.1002/chem.20130004295
P. Shen, Y. Xia, Synthesis-modification integration: one-step fabrication of boronic acid functionalized carbon dots for fluorescent blood sugar sensing. Anal. Chem. 86(11), 5323–5329 (2014). doi:10.1021/ac5001338
J. Wei, X. Zhang, Y. Sheng, J. Shen, P. Huang, S. Guo, J. Pan, B. Feng, Dual functional carbon dots derived from cornflour via a simple one-pot hydrothermal route. Mater. Lett. 123, 107–111 (2014). doi:10.1016/j.matlet.2014.02.090
Z. Qian, J. Ma, X. Shan, H. Feng, L. Shao, J. Chen, Highly luminescent N-doped carbon quantum dots as an effective multifunctional fluorescence sensing platform. Chem. Eur. J. 20(8), 2254–2263 (2014). doi:10.1002/chem.201304374
R. Zhang, W. Chen, Nitrogen-doped carbon quantum dots: facile synthesis and application as a “turn-off” fluorescent probe for detection of Hg2+ ions. Biosens. Bioelecton. 55, 83–90 (2014). doi:10.1016/j.bios.2013.11.074
H. Dai, Y. Shi, Y. Wang, Y. Sun, J. Hu, P. Ni, Z. Li, A carbon dot based biosensor for melamine detection by fluorescence resonance energy transfer. Sens. Actuat. B Chem. 202, 201–208 (2014). doi:10.1016/j.snb.2014.05.058
A. Sachdev, I. Matai, P. Gopinath, Implications of surface passivation on physicochemical and bioimaging properties of carbon dots. RSC Adv. 4(40), 20915 (2014). doi:10.1039/c4ra02017k
R.-J. Fan, Q. Sun, L. Zhang, Y. Zhang, A.-H. Lu, Photoluminescent carbon dots directly derived from polyethylene glycol and their application for cellular imaging. Carbon 71, 87–93 (2014). doi:10.1016/j.carbon.2014.01.016
L. Wang, H.S. Zhou, Green synthesis of luminescent nitrogen-doped carbon dots from milk and its imaging application. Anal. Chem. 86(18), 8902–8905 (2014). doi:10.1021/ac502646x
Z. Qian, X. Shan, L. Chai, J. Ma, J. Chen, H. Feng, Si-doped carbon quantum dots: a facile and general preparation strategy, bioimaging application, and multifunctional sensor. ACS Appl. Mater. Inter. 6(9), 6797–6805 (2014). doi:10.1021/am500403n
Q. Wang, X. Huang, Y. Long, X. Wang, H. Zhang, R. Zhu, L. Liang, P. Teng, H. Zheng, Hollow luminescent carbon dots for drug delivery. Carbon 59, 192–199 (2013). doi:10.1016/j.carbon.2013.03.009
L. Hu, Y. Sun, S. Li, X. Wang, K. Hu, L. Wang, WuY Liang X-j, Multifunctional carbon dots with high quantum yield for imaging and gene delivery. Carbon 67, 508–513 (2014). doi:10.1016/j.carbon.2013.10.023
X. Yang, Y. Zhuo, S. Zhu, Y. Luo, Y. Feng, Y. Dou, Novel and green synthesis of high-fluorescent carbon dots originated from honey for sensing and imaging. Biosens. Bioelectron. 60, 292–298 (2014). doi:10.1016/j.bios.2014.04.046
S. Sahu, B. Behera, T.K. Maiti, S. Mohapatra, Simple one-step synthesis of highly luminescent carbon dots from orange juice: application as excellent bio-imaging agents. Chem. Commun. 48(70), 8835–8837 (2012). doi:10.1039/c2cc33796g
W. Wang, Y.C. Lu, H. Huang, J.J. Feng, J.R. Chen, A.J. Wang, Facile synthesis of water-soluble and biocompatible fluorescent nitrogen-doped carbon dots for cell imaging. Analyst 139(7), 1692–1696 (2014). doi:10.1039/c3an02098c
Z.C. Yang, M. Wang, A.M. Yong, S.Y. Wong, X.H. Zhang, H. Tan, A.Y. Chang, X. Li, J. Wang, Intrinsically fluorescent carbon dots with tunable emission derived from hydrothermal treatment of glucose in the presence of monopotassium phosphate. Chem. Commun. 47(42), 11615–11617 (2011). doi:10.1039/c1cc14860e
Z.C. Yang, X. Li, J. Wang, Intrinsically fluorescent nitrogen-containing carbon nanoparticles synthesized by a hydrothermal process. Carbon 49(15), 5207–5212 (2011). doi:10.1016/j.carbon.2011.07.038
O. Kozák, K.K.R. Datta, M. Greplová, V. Ranc, J. Kašlík, R. Zbořil, Surfactant-derived amphiphilic carbon dots with tunable photoluminescence. J. Phys. Chem. C 117(47), 24991–24996 (2013). doi:10.1021/jp4040166
Z.C. Liang, L. Zeng, X.D. Cao, Q. Wang, X.H. Wang, R.C. Sun, Sustainable carbon quantum dots from forestry and agricultural biomass with amplified photoluminescence by simple NH4OH passivation. J. Mater. Chem. C 2, 9760–9766. (2014). doi:10.1039/C4TC01714E
P.C. Hsu, H.T. Chang, Synthesis of high-quality carbon nanodots from hydrophilic compounds: role of functional groups. Chem. Commun. 48(33), 3984–3986 (2012). doi:10.1039/c2cc30188a
X.M. Li, S.P. Lau, L.B. Tang, R.B. Ji, P.Z. Yang, Multicolour light emission from chlorine-doped graphene quantum dots. J. Mater. Chem. C 1, 7308–7313 (2014). doi:10.1039/C3TC31473A
Y. Xu, C.J. Tang, H. Huang, C.Q. Sun, Y.K. Zhang, Q.F. Ye, A.J. Wang, Green synthesis of fluorescent carbon quantum dots for detection of Hg2+. Chine. J. Anal. Chem. 42(9), 1252–1258 (2014). doi:10.1016/s1872-2040(14)60765-9
Y. Dong, J. Shao, C. Chen, H. Li, R. Wang, Y. Chi, X. Lin, G. Chen, Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid. Carbon 50(12), 4738–4743 (2012). doi:10.1016/j.carbon.2012.06.002
Y. Dong, R. Wang, H. Li, J. Shao, Y. Chi, X. Lin, G. Chen, Polyamine-functionalized carbon quantum dots for chemical sensing. Carbon 50(8), 2810–2815 (2012). doi:10.1016/j.carbon.2012.02.046
X. Teng, C. Ma, C. Ge, M. Yan, J. Yang, Y. Zhang, P.C. Morais, H. Bi, Green synthesis of nitrogen-doped carbon dots from konjac flour with “off–on” fluorescence by Fe3+ and l-lysine for bioimaging. J. Mater. Chem. B 2(29), 4631–4639 (2014). doi:10.1039/c4tb00368c
P.Y. Lin, C.W. Hsieh, M.L. Kung, L.Y. Chu, H.J. Huang, H.T. Chen, D.C. Wu, C.H. Kuo, S.L. Hsieh, S. Hsieh, Eco-friendly synthesis of shrimp egg-derived carbon dots for fluorescent bioimaging. J. Biotechnol. 189, 114–119 (2014). doi:10.1016/j.jbiotec.2014.08.043
J. Niu, H. Gao, Synthesis and drug detection performance of nitrogen-doped carbon dots. J. Lumin. 149, 159–162 (2014). doi:10.1016/j.jlumin.2014.01.026
Y. Xu, M. Wu, X.Z. Feng, X.B. Yin, X.W. He, Y.K. Zhang, Reduced carbon dots versus oxidized carbon dots: photo- and electrochemiluminescence investigations for selected applications. Chem. Eur. J. 19(20), 6282–6288 (2013). doi:10.1002/chem.201204372
K. Hola, A.B. Bourlinos, O. Kozak, K. Berka, K.M. Siskova, M. Havrdova, J. Tucek, K. Safarova, M. Otyepka, E.P. Giannelis, R. Zboril, Photoluminescence effects of graphitic core size and surface functional groups in carbon dots: COO− induced red-shift emission. Carbon 70, 279–286 (2014). doi:10.1016/j.carbon.2014.01.008
J. Niu, H. Gao, L. Wang, S. Xin, G. Zhang, Q. Wang, L. Guo, W. Liu, X. Gao, Y. Wang, Facile synthesis and optical properties of nitrogen-doped carbon dots. New J. Chem. 38(4), 1522–1527 (2014). doi:10.1039/c3nj01068f
J. Wei, J. Shen, X. Zhang, S. Guo, J. Pan, X. Hou, H. Zhang, L. Wang, B. Feng, Simple one-step synthesis of water-soluble fluorescent carbon dots derived from paper ash. RSC Adv. 3(32), 13119–13122 (2013). doi:10.1039/c3ra41751d
J. Wang, C.F. Wang, S. Chen, Amphiphilic egg-derived carbon dots: rapid plasma fabrication, pyrolysis process, and multicolor printing patterns. Angew. Chem. Int. Ed. 51(37), 9297–9301 (2012). doi:10.1002/anie
J. Zhou, Z. Sheng, H. Han, M. Zou, C. Li, Facile synthesis of fluorescent carbon dots using watermelon peel as a carbon source. Mater. Lett. 66(1), 222–224 (2012). doi:10.1016/j.matlet.2011.08.081
X. Dong, Y. Su, H. Geng, Z. Li, C. Yang, X. Li, Y. Zhang, Fast one-step synthesis of N-doped carbon dots by pyrolyzing ethanolamine. J. Mater. Chem. C 2(36), 7477–7481 (2014). doi:10.1039/c4tc01139b
Z. Jiang, A. Nolan, J.G. Walton, A. Lilienkampf, R. Zhang, M. Bradley, Photoluminescent carbon dots from 1,4-addition polymers. Chem. Eur. J. 20(35), 10926–10931 (2014). doi:10.1002/chem.201403076
D. Pan, J. Zhang, Z. Li, C. Wu, X. Yan, M. Wu, Observation of pH-, solvent-, spin-, and excitation-dependent blue photoluminescence from carbon nanoparticles. Chem. Commun. 46(21), 3681–3683 (2010). doi:10.1039/c000114g
F. Wang, M. Kreiter, B. He, S. Pang, C.Y. Liu, Synthesis of direct white-light emitting carbogenic quantum dots. Chem. Commun. 46(19), 3309–3311 (2010). doi:10.1039/c002206c
X. Guo, C.F. Wang, Z.Y. Yu, L. Chen, S. Chen, Facile access to versatile fluorescent carbon dots toward light-emitting diodes. Chem. Commun. 48(21), 2692–2694 (2012). doi:10.1039/c2cc17769b
H. Zhu, X. Wang, Y. Li, Z. Wang, F. Yang, X. Yang, Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties. Chem. Commun. 34, 5118–5120 (2009). doi:10.1039/b907612c
X. Wang, K. Qu, B. Xu, J. Ren, X. Qu, Microwave assisted one-step green synthesis of cell-permeable multicolor photoluminescent carbon dots without surface passivation reagents. J. Mater. Chem. 21(8), 2445–2450 (2011). doi:10.1039/c0jm02963g
X. Zhai, P. Zhang, C. Liu, T. Bai, W. Li, L. Dai, W. Liu, Highly luminescent carbon nanodots by microwave-assisted pyrolysis. Chem. Commun. 48(64), 7955–7957 (2012). doi:10.1039/c2cc33869f
Z. Lin, W. Xue, H. Chen, J.M. Lin, Peroxynitrous-acid-induced chemiluminescence of fluorescent carbon dots for nitrite sensing. Anal. Chem. 83(21), 8245–8251 (2011). doi:10.1021/ac202039h
A. Salinas-Castillo, M. Ariza-Avidad, C. Pritz, M. Camprubi-Robles, B. Fernandez, M.J. Ruedas-Rama, A. Megia-Fernandez, A. Lapresta-Fernandez, F. Santoyo-Gonzalez, A. Schrott-Fischer, L.F. Capitan-Vallvey, Carbon dots for copper detection with down and upconversion fluorescent properties as excitation sources. Chem. Commun. 49(11), 1103–1105 (2013). doi:10.1039/c2cc36450f
A. Zhao, C. Zhao, M. Li, J. Ren, X. Qu, Ionic liquids as precursors for highly luminescent, surface-different nitrogen-doped carbon dots used for label-free detection of Cu2+/Fe3+ and cell imaging. Anal. Chem. Acta 809, 128–133 (2014). doi:10.1016/j.aca.2013.10.046
Y. Zhai, Z. Zhu, C. Zhu, J. Ren, E. Wang, S. Dong, Multifunctional water-soluble luminescent carbon dots for imaging and Hg2+ sensing. J. Mater. Chem. B 2(40), 6995–6999 (2014). doi:10.1039/c4tb01035c
E.F. Simoes, J.C. da Silva, J.M. Leitao, Carbon dots from tryptophan doped glucose for peroxynitrite sensing. Anal. Chem. Acta 852, 174–180 (2014). doi:10.1016/j.aca.2014.08.050
W. Wang, Y. Li, L. Cheng, Z. Cao, W. Liu, Water-soluble and phosphorus-containing carbon dots with strong green fluorescence for cell labeling. J. Mater. Chem. B 2(1), 46–48 (2014). doi:10.1039/c3tb21370f
Y.F. Huang, X. Zhou, R. Zhou, H. Zhang, K.B. Kang, M. Zhao, Y. Peng, Q. Wang, H.L. Zhang, W.Y. Qiu, One-pot synthesis of highly luminescent carbon quantum dots and their nontoxic ingestion by zebrafish for in vivo imaging. Chem. Eur. J. 20(19), 5640–5648 (2014). doi:10.1002/chem.201400011
C. Liu, P. Zhang, X. Zhai, F. Tian, W. Li, J. Yang, Y. Liu, H. Wang, W. Wang, W. Liu, Nano-carrier for gene delivery and bioimaging based on carbon dots with PEI-passivation enhanced fluorescence. Biomaterials 33(13), 3604–3613 (2012). doi:10.1016/j.biomaterials.2012.01.052
J. Gong, X. An, X. Yan, A novel rapid and green synthesis of highly luminescent carbon dots with good biocompatibility for cell imaging. New J. Chem. 38(4), 1376–1379 (2014). doi:10.1039/c3nj01320k
Q. Liu, S. Xu, C. Niu, M. Li, D. He, Z. Lu, L. Ma, N. Na, F. Huang, H. Jiang, J. Ouyang, Distinguish cancer cells based on targeting turn-on fluorescence imaging by folate functionalized green emitting carbon dots. Biosens. Bioelectron. 64, 119–125 (2015). doi:10.1016/j.bios.2014.08.052
J. Wang, C. Cheng, Y. Huang, B. Zheng, H. Yuan, L. Bo, M.-W. Zheng, S.-Y. Yang, Y. Guo, D. Xiao, A facile large-scale microwave synthesis of highly fluorescent carbon dots from benzenediol isomers. J. Mater. Chem. C 2(25), 5028–5035 (2014). doi:10.1039/c3tc32131b
S. Liu, L. Wang, J. Tian, J. Zhai, Y. Luo, W. Lu, X. Sun, Acid-driven, microwave-assisted production of photoluminescent carbon nitride dots from N. N-dimethylformamide. RSC Adv. 1(6), 951–953 (2011). doi:10.1039/c1ra00249j
C. Liu, P. Zhang, F. Tian, W. Li, F. Li, W. Liu, One-step synthesis of surface passivated carbon nanodots by microwave assisted pyrolysis for enhanced multicolor photoluminescence and bioimaging. J. Mater. Chem. 21(35), 13163–13167 (2011). doi:10.1039/c1jm12744f
R.J. Libin Tang, Xiangke Cao, Jingyu Lin, Hongxing Jiang, Xueming Li, Kar Seng Teng, Chi Man Luk, Songjun Zeng, Jianhua Hao, Shu Ping Lau, Deep ultraviolet photoluminescence of water-soluble self-passivated graphene quantum dots. ACS Nano 6, 5102–5110 (2012). doi:10.1021/nn300760g
L.B. Tang, R.B. Ji, X.M. Li, G.X. Bai, C.P. Liu, J.H. Hao, J.Y. Lin, H.X. Jiang, K.S. Teng, Z.B. Yang, Deep ultraviolet to near-infrared emission and photoresponse in layered N-doped graphene quantum dots. ACS Nano 8(6), 6312–6320 (2014). doi:10.1021/nn501796r
R. Liu, D. Wu, S. Liu, K. Koynov, W. Knoll, Q. Li, An aqueous route to multicolor photoluminescent carbon dots using silica spheres as carriers. Angew. Chem. Int. Ed. 48(25), 4598–4601 (2009). doi:10.1002/anie.200900652
J. Zong, Y. Zhu, X. Yang, J. Shen, C. Li, Synthesis of photoluminescent carbogenic dots using mesoporous silica spheres as nanoreactors. Chem. Commun. (Camb.) 47(2), 764–766 (2011). doi:10.1039/c0cc03092a
J. Zong, X. Yang, A. Trinchi, S. Hardin, I. Cole, Y. Zhu, C. Li, T. Muster, G. Wei, Carbon dots as fluorescent probes for “off-on” detection of Cu2+ and L-cysteine in aqueous solution. Biosens. Bioelectron. 51, 330–335 (2014). doi:10.1016/j.bios.2013.07.042
S. Liu, J. Tian, L. Wang, Y. Luo, J. Zhai, X. Sun, Preparation of photoluminescent carbon nitride dots from CCl4 and 1,2-ethylenediamine: a heat-treatment-based strategy. J. Mater. Chem. 21(32), 11726–11729 (2011). doi:10.1039/c1jm12149a
E.J. Goh, K.S. Kim, Y.R. Kim, H.S. Jung, S. Beack, W.H. Kong, G. Scarcelli, S.H. Yun, S.K. Hahn, Bioimaging of hyaluronic acid derivatives using nanosized carbon dots. Biomacromolecules 13(8), 2554–2561 (2012). doi:10.1021/bm300796q
R. Liu, H. Li, W. Kong, J. Liu, Y. Liu, C. Tong, X. Zhang, Z. Kang, Ultra-sensitive and selective Hg2+ detection based on fluorescent carbon dots. Mater. Res. Bull. 48(7), 2529–2534 (2013). doi:10.1016/j.materresbull.2013.03.015
H. Nie, M. Li, Q. Li, S. Liang, Y. Tan, L. Sheng, W. Shi, S.X.-A. Zhang, Carbon dots with continuously tunable full-color emission and their application in ratiometric pH sensing. Chem. Mater. 26(10), 3104–3112 (2014). doi:10.1021/cm5003669
W. Kong, R. Liu, H. Li, J. Liu, H. Huang, Y. Liu, Z. Kang, High-bright fluorescent carbon dots and their application in selective nucleoli staining. J. Mater. Chem. B 2(31), 5077–5082 (2014). doi:10.1039/c4tb00579a
C.-W. Lai, Y.-H. Hsiao, Y.-K. Peng, P.-T. Chou, Facile synthesis of highly emissive carbon dots from pyrolysis of glycerol; gram scale production of carbon dots/mSiO2 for cell imaging and drug release. J. Mater. Chem. 22(29), 14403–14409 (2012). doi:10.1039/c2jm32206d
Y.Y. Zhang, M. Wu, Y.Q. Wang, X.W. He, W.Y. Li, X.Z. Feng, A new hydrothermal refluxing route to strong fluorescent carbon dots and its application as fluorescent imaging agent. Talanta 117, 196–202 (2013). doi:10.1016/j.talanta.2013.09.003
Y. Hu, J. Yang, J. Tian, L. Jia, J.-S. Yu, Waste frying oil as a precursor for one-step synthesis of sulfur-doped carbon dots with pH-sensitive photoluminescence. Carbon 77, 775–782 (2014). doi:10.1016/j.carbon.2014.05.081
X. Yan, B. Li, X. Cui, Q. Wei, K. Tajima, Li L-s, Independent tuning of the band gap and redox potential of graphene quantum dots. J. Phys. Chem. Lett. 2(10), 1119–1124 (2011). doi:10.1021/jz200450r
X. Yan, X. Cui, B. Li, L.S. Li, Large, solution-processable graphene quantum dots as light absorbers for photovoltaics. Nano Lett. 10(5), 1869–1873 (2010). doi:10.1021/nl101060h
Yan L-sLX, Colloidal graphene quantum dots. J. Phys. Chem. Lett. 1, 2572–2576 (2010). doi:10.1021/jz100862f|J
X.C. Xin Yan, Liang-shi Li, Synthesis of large, stable colloidal graphene quantum dots with tunable size. J. Am. Chem. Soc. 132, 5944–5945 (2010). doi:10.1021/ja1009376
M.L. Mueller, X. Yan, J.A. McGuire, L.S. Li, Triplet states and electronic relaxation in photoexcited graphene quantum dots. Nano Lett. 10(7), 2679–2682 (2010). doi:10.1021/nl101474d
J. Zhang, W. Shen, D. Pan, Z. Zhang, Y. Fang, M. Wu, Controlled synthesis of green and blue luminescent carbon nanoparticles with high yields by the carbonization of sucrose. New J. Chem. 34(4), 591–593 (2010). doi:10.1039/b9nj00662a
Y. Liu, Liu C-y, Zhang Z-y, Synthesis of highly luminescent graphitized carbon dots and the application in the Hg2+ detection. Appl. Surf. Sci. 263, 481–485 (2012). doi:10.1016/j.apsusc.2012.09.088
Y. Dong, H. Pang, H. Yang, J. Jiang, Y. Chi, T. Yu, Nitrogen-doped carbon-based dots prepared by dehydrating EDTA with hot sulfuric acid and their electrocatalysis for oxygen reduction reaction. RSC Adv. 4(62), 32791–32795 (2014). doi:10.1039/c4ra06594h
S.S. Wee, Y.H. Ng, S.M. Ng, Synthesis of fluorescent carbon dots via simple acid hydrolysis of bovine serum albumin and its potential as sensitive sensing probe for lead (II) ions. Talanta 116, 71–76 (2013). doi:10.1016/j.talanta.2013.04.081
D. Sun, R. Ban, P.-H. Zhang, G.-H. Wu, J.-R. Zhang, J.-J. Zhu, Hair fiber as a precursor for synthesizing of sulfur- and nitrogen-co-doped carbon dots with tunable luminescence properties. Carbon 64, 424–434 (2013). doi:10.1016/j.carbon.2013.07.095
J.S. Suh JKa, Size-controllable and low-cost fabrication of graphene quantum dots using thermal plasma jet. ACS Nano 8, 4190–4196 (2014)
C. Jiang, H. Wu, X. Song, X. Ma, J. Wang, M. Tan, Presence of photoluminescent carbon dots in Nescafe(R) original instant coffee: applications to bioimaging. Talanta 127, 68–74 (2014). doi:10.1016/j.talanta.2014.01.046
H. Li, X. He, Y. Liu, H. Huang, S. Lian, S.-T. Lee, Z. Kang, One-step ultrasonic synthesis of water-soluble carbon nanoparticles with excellent photoluminescent properties. Carbon 49(2), 605–609 (2011). doi:10.1016/j.carbon.2010.10.004
Z. Ma, H. Ming, H. Huang, Y. Liu, Z. Kang, One-step ultrasonic synthesis of fluorescent N-doped carbon dots from glucose and their visible-light sensitive photocatalytic ability. New J. Chem. 36(4), 861–864 (2012). doi:10.1039/c2nj20942j
Y. Fang, S. Guo, D. Li, C. Zhu, W. Ren, S. Dong, E. Wang, Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles. ACS Nano 6, 400–409 (2012). doi:10.1021/nn2046373
J. Lu, P.S. Yeo, C.K. Gan, P. Wu, K.P. Loh, Transforming C60 molecules into graphene quantum dots. Nat. Nanotechnol. 6(4), 247–252 (2011). doi:10.1038/nnano.2011.30
J. Shen, Y. Zhu, X. Yang, J. Zong, J. Zhang, C. Li, One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light. New J. Chem. 36(1), 97–101 (2012). doi:10.1039/c1nj20658c
H. Peng, J. Travas-Sejdic, Simple aqueous solution route to luminescent carbogenic dots from carbohydrates. Chem. Mater. 21(23), 5563–5565 (2009). doi:10.1021/cm901593y
Y. Liu, Liu C-y, Zhang Z-y, Synthesis and surface photochemistry of graphitized carbon quantum dots. J. Colloid Interface Sci. 356(2), 416–421 (2011). doi:10.1016/j.jcis.2011.01.065
H. Sun, L. Wu, N. Gao, J. Ren, X. Qu, Improvement of photoluminescence of graphene quantum dots with a biocompatible photochemical reduction pathway and its bioimaging application. ACS Appl. Mater. Interfaces 5(3), 1174–1179 (2013). doi:10.1021/am3030849
G.S. Kumar, R. Roy, D. Sen, U.K. Ghorai, R. Thapa, N. Mazumder, S. Saha, K.K. Chattopadhyay, Amino-functionalized graphene quantum dots: origin of tunable heterogeneous photoluminescence. Nanoscale 6(6), 3384–3391 (2014). doi:10.1039/c3nr05376h
S.H. Jin, D.H. Kim, G.H. Jun, S.H. Hong, S. Jeon, Tuning the photoluminescence of graphene quantum dots through the charge transfer effect of functional groups. ACS Nano 7(2), 1239–1245 (2012). doi:10.1021/nn3046759
Y. Feng, J. Zhao, X. Yan, F. Tang, Q. Xue, Enhancement in the fluorescence of graphene quantum dots by hydrazine hydrate reduction. Carbon 66, 334–339 (2014). doi:10.1016/j.carbon.2013.09.008
H. Zheng, Q. Wang, Y. Long, H. Zhang, X. Huang, R. Zhu, Enhancing the luminescence of carbon dots with a reduction pathway. Chem. Commun. 47(38), 10650–10652 (2011). doi:10.1039/c1cc14741b
K. Lingam, R. Podila, H. Qian, S. Serkiz, A.M. Rao, Evidence for edge-state photoluminescence in graphene quantum dots. Adv. Funct. Mater. 23(40), 5062–5065 (2013). doi:10.1002/adfm.201203441
G. Eda, Y.Y. Lin, C. Mattevi, H. Yamaguchi, H.A. Chen, I.S. Chen, C.W. Chen, M. Chhowalla, Blue photoluminescence from chemically derived graphene oxide. Adv. Mater. 22(4), 505–509 (2010). doi:10.1002/adma.200901996
K.P. Loh, Q. Bao, G. Eda, M. Chhowalla, Graphene oxide as a chemically tunable platform for optical applications. Nat. Chem. 2(12), 1015–1024 (2010). doi:10.1038/nchem.907
J. Robertson, G.A.J. Amaratunga, Photoluminescence behavior of hydrogenated amorphous carbon. J. Appl. Phys. 80(5), 2998–3003 (1996). doi:10.1063/1.363158
F. Demichelis, S. Schreiter, A. Tagliaferro, Photoluminescence in a-C-H films. Phys. Rev. B 51(4), 2143–2147 (1995). doi:10.1103/PhysRevB.51.2143
M. Li, W. Wu, W. Ren, H.-M. Cheng, N. Tang, W. Zhong, Y. Du, Synthesis and upconversion luminescence of N-doped graphene quantum dots. Appl. Phys. Lett. 101(10), 103107 (2012). doi:10.1063/1.4750065
X. Wang, L. Cao, S.T. Yang, F. Lu, M.J. Meziani, L. Tian, K.W. Sun, M.A. Bloodgood, Y.P. Sun, Bandgap-like strong fluorescence in functionalized carbon nanoparticles. Angew. Chem. Int. Ed. 49(31), 5310–5314 (2010). doi:10.1002/anie.201000982
P. Anilkumar, X. Wang, L. Cao, S. Sahu, J.H. Liu, P. Wang, K. Korch, K.N. Tackett 2nd, A. Parenzan, Y.P. Sun, Toward quantitatively fluorescent carbon-based “quantum” dots. Nanoscale 3(5), 2023–2027 (2011). doi:10.1039/c0nr00962h
Y.P. Sun, X. Wang, F.S. Lu, L. Cao, M.J. Meziani, P.J.G. Luo, L.R. Gu, L.M. Veca, Doped carbon nanoparticles as a new platform for highly photoluminescent dots. J. Phys. Chem. C 112(47), 18295–18298 (2008). doi:10.1021/jp8076485
A. Cayuela, M.L. Soriano, M. Valcarcel, Strong luminescence of carbon dots induced by acetone passivation: efficient sensor for a rapid analysis of two different pollutants. Anal. Chim. Acta 804, 246–251 (2013). doi:10.1016/j.aca.2013.10.031
S. Zhu, J. Zhang, S. Tang, C. Qiao, L. Wang, H. Wang, X. Liu, B. Li, Y. Li, W. Yu, X. Wang, H. Sun, B. Yang, Surface chemistry routes to modulate the photoluminescence of graphene quantum dots: from fluorescence mechanism to up-conversion bioimaging applications. Adv. Func. Mater. 22(22), 4732–4740 (2012). doi:10.1002/adfm.201201499
Y. Dong, R. Dai, T. Dong, Y. Chi, G. Chen, Photoluminescence, chemiluminescence and anodic electrochemiluminescence of hydrazide-modified graphene quantum dots. Nanoscale 6(19), 11240–11245 (2014). doi:10.1039/c4nr02539c
Q. Liu, B. Guo, Z. Rao, B. Zhang, J.R. Gong, Strong two-photon-induced fluorescence from photostable, biocompatible nitrogen-doped graphene quantum dots for cellular and deep-tissue imaging. Nano Lett. 13(6), 2436–2441 (2013). doi:10.1021/nl400368v
C. Hu, Y. Liu, Y. Yang, J. Cui, Z. Huang, Y. Wang, L. Yang, H. Wang, Y. Xiao, J. Rong, One-step preparation of nitrogen-doped graphene quantum dots from oxidized debris of graphene oxide. J. Mater. Chem. B 1(1), 39–42 (2013). doi:10.1039/c2tb00189f
X.-M. Wei, Y. Xu, Y.-H. Li, X.-B. Yin, X.-W. He, Ultrafast synthesis of nitrogen-doped carbon dots via neutralization heat for bioimaging and sensing applications. RSC Adv. 4(84), 44504–44508 (2014). doi:10.1039/c4ra08523j
L. Tang, R. Ji, X. Li, K.S. Teng, S.P. Lau, Energy-level structure of nitrogen-doped graphene quantum dots. J. Mater. Chem. C 1(32), 4908–4915 (2013). doi:10.1039/c3tc30877d
Q.-Q. Shi, Y.-H. Li, Y. Xu, Y. Wang, X.-B. Yin, X.-W. He, Y.-K. Zhang, High-yield and high-solubility nitrogen-doped carbon dots: formation, fluorescence mechanism and imaging application. RSC Adv. 4(4), 1563–1566 (2014). doi:10.1039/c3ra45762a
J. Shen, Y. Zhu, X. Yang, J. Zong, J. Zhang, C. Li, One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light. New J. Chem. 36(1), 97–101 (2012). doi:10.1039/c1nj20658c
S.J. Zhuo, M.W. Shao, S.T. Lee, Upconversion and downconversion fluorescent graphene quantum dots: ultrasonic preparation and photocatalysis. ACS Nano 6(2), 1059–1064 (2012). doi:10.1021/nn2040395
S. Zhu, J. Zhang, X. Liu, B. Li, X. Wang, S. Tang, Q. Meng, Y. Li, C. Shi, R. Hu, B. Yang, Graphene quantum dots with controllable surface oxidation, tunable fluorescence and up-conversion emission. RSC Adv. 2(7), 2717–2720 (2012). doi:10.1039/c2ra20182h
Y. Su, M. Xie, X. Lu, H. Wei, H. Geng, Z. Yang, Y. Zhang, Facile synthesis and photoelectric properties of carbon dots with upconversion fluorescence using arc-synthesized carbon by-products. RSC Adv. 4(10), 4839–4842 (2014). doi:10.1039/c3ra45453c
D.Z. Tan, S.F. Zhou, J.R. Qiu, Comment on “upconversion and downconversion fluorescent graphene quantum dots: ultrasonic preparation and photocatalysis”. ACS Nano 6(8), 6530–6531 (2012). doi:10.1021/nn3016822
Z. Gan, X. Wu, G. Zhou, J. Shen, P.K. Chu, Is there real upconversion photoluminescence from graphene quantum dots. Adv. Opt. Mater. 1(8), 554–558 (2013). doi:10.1002/adom.201300152
S.K. Poznyak, D.V. Talapin, E.V. Shevchenko, H. Weller, Quantum dot chemiluminescence. Nano Lett. 4(4), 693–698 (2004). doi:10.1021/nl049713w
Z. Ding, B.M. Quinn, S.K. Haram, L.E. Pell, B.A. Korgel, A.J. Bard, Electrochemistry and electrogenerated chemiluminescence from silicon nanocrystal quantum dots. Science 296(5571), 1293–1297 (2002). doi:10.1126/science.1069336
Y. Bae, N. Myung, A.J. Bard, Electrochemistry and electrogenerated chemiluminescence of CdTe nanoparticles. Nano Lett. 4(6), 1153–1161 (2004). doi:10.1021/nl049516x
Y. Dong, W. Tian, S. Ren, R. Dai, Y. Chi, G. Chen, Graphene quantum dots/L-cysteine coreactant electrochemiluminescence system and its application in sensing lead(II) ions. ACS Appl. Mater. Interface 6(3), 1646–1651 (2014). doi:10.1021/am404552s
Y. Dong, C. Chen, J. Lin, N. Zhou, Y. Chi, G. Chen, Electrochemiluminescence emission from carbon quantum dot-sulfite coreactant system. Carbon 56, 12–17 (2013). doi:10.1016/j.carbon.2012.12.086
T.T. Zhang, H.M. Zhao, X.F. Fan, S. Chen, X. Quan, Electrochemiluminescence immunosensor for highly sensitive detection of 8-hydroxy-2′-deoxyguanosine based on carbon quantum dot coated Au/SiO2 core-shell nanoparticles. Talanta 131, 379–385 (2015). doi:10.1016/j.talanta.2014.08.024
M. Zhang, H. Liu, L. Chen, M. Yan, L. Ge, S. Ge, J. Yu, A disposable electrochemiluminescence device for ultrasensitive monitoring of K562 leukemia cells based on aptamers and ZnO@carbon quantum dots. Biosens. Bioelectron. 49, 79–85 (2013). doi:10.1016/j.bios.2013.05.003
S. Yang, J. Liang, S. Luo, C. Liu, Y. Tang, Supersensitive detection of chlorinated phenols by multiple amplification electrochemiluminescence sensing based on carbon quantum dots/graphene. Anal. Chem. 85(16), 7720–7725 (2013). doi:10.1021/ac400874h
M. Su, H. Liu, L. Ge, Y. Wang, S. Ge, J. Yu, M. Yan, Aptamer-Based electrochemiluminescent detection of MCF-7 cancer cells based on carbon quantum dots coated mesoporous silica nanoparticles. Electrochim. Acta 146, 262–269 (2014). doi:10.1016/j.electacta.2014.08.129
Q. Lu, W. Wei, Z. Zhou, Z. Zhou, Y. Zhang, S. Liu, Electrochemiluminescence resonance energy transfer between graphene quantum dots and gold nanoparticles for DNA damage detection. Analyst 139(10), 2404–2410 (2014). doi:10.1039/c4an00020j
J. Lu, M. Yan, L. Ge, S. Ge, S. Wang, J. Yan, J. Yu, Electrochemiluminescence of blue-luminescent graphene quantum dots and its application in ultrasensitive aptasensor for adenosine triphosphate detection. Biosens. Bioelectron. 47, 271–277 (2013). doi:10.1016/j.bios.2013.03.039
Y. Chen, Y. Dong, H. Wu, C. Chen, Y. Chi, G. Chen, Electrochemiluminescence sensor for hexavalent chromium based on the graphene quantum dots/peroxodisulfate system. Electrochim. Acta 151, 552–557 (2015). doi:10.1016/j.electacta.2014.11.068
W. Xue, Z. Lin, H. Chen, C. Lu, J.-M. Lin, Enhancement of ultraweak chemiluminescence from reaction of hydrogen peroxide and bisulfite by water-soluble carbon nanodots. J. Phys. Chem. C 115(44), 21707–21714 (2011). doi:10.1021/jp207554t
Z. Lin, W. Xue, H. Chen, J.M. Lin, Classical oxidant induced chemiluminescence of fluorescent carbon dots. Chem. Commun. 48(7), 1051–1053 (2012). doi:10.1039/c1cc15290d
L. Zhao, F. Di, D. Wang, L.H. Guo, Y. Yang, B. Wan, H. Zhang, Chemiluminescence of carbon dots under strong alkaline solutions: a novel insight into carbon dot optical properties. Nanoscale 5(7), 2655–2658 (2013). doi:10.1039/c3nr00358b
H. Gonçalves, P.A.S. Jorge, J.R.A. Fernandes, J.C.G. Esteves da Silva, Hg(II) sensing based on functionalized carbon dots obtained by direct laser ablation. Sensor. Actuat. B-Chem. 145(2), 702–707 (2010). doi:10.1016/j.snb.2010.01.031
H.M. Goncalves, A.J. Duarte, J.C. Esteves da Silva, Optical fiber sensor for Hg(II) based on carbon dots. Biosens. Bioelectron. 26(4), 1302–1306 (2010). doi:10.1016/j.bios.2010.07.018
B. Cao, C. Yuan, B. Liu, C. Jiang, G. Guan, M.Y. Han, Ratiometric fluorescence detection of mercuric ion based on the nanohybrid of fluorescence carbon dots and quantum dots. Anal. Chim. Acta 786, 146–152 (2013). doi:10.1016/j.aca.2013.05.015
W. Wang, T. Kim, Z. Yan, G. Zhu, I. Cole, N.T. Nguyen, Q. Li, Carbon dots functionalized by organosilane with double-sided anchoring for nanomolar Hg2+ detection. J. Colloid Interface Sci. 437, 28–34 (2015). doi:10.1016/j.jcis.2014.09.013
F. Yan, Y. Zou, M. Wang, X. Mu, N. Yang, L. Chen, Highly photoluminescent carbon dots-based fluorescent chemosensors for sensitive and selective detection of mercury ions and application of imaging in living cells. Sens. Actuat. B Chem. 192, 488–495 (2014). doi:10.1016/j.snb.2013.11.041
H. Li, J. Zhai, J. Tian, Y. Luo, X. Sun, Carbon nanoparticle for highly sensitive and selective fluorescent detection of mercury(II) ion in aqueous solution. Biosens. Bioelectron. 26(12), 4656–4660 (2011). doi:10.1016/j.bios.2011.03.026
X. Cui, L. Zhu, J. Wu, Y. Hou, P. Wang, Z. Wang, M. Yang, A fluorescent biosensor based on carbon dots-labeled oligodeoxyribonucleotide and graphene oxide for mercury(II) detection. Biosens. Bioelectron. 63, 506–512 (2015). doi:10.1016/j.bios.2014.07.085
I. Costas-Mora, V. Romero, I. Lavilla, C. Bendicho, In situ building of a nanoprobe based on fluorescent carbon dots for methylmercury detection. Anal. Chem. 86(9), 4536–4543 (2014). doi:10.1021/ac500517h
Y. Dong, R. Wang, G. Li, C. Chen, Y. Chi, G. Chen, Polyamine-functionalized carbon quantum dots as fluorescent probes for selective and sensitive detection of copper ions. Anal. Chem. 84(14), 6220–6224 (2012). doi:10.1021/ac3012126
X. Lin, G. Gao, L. Zheng, Y. Chi, G. Chen, Encapsulation of strongly fluorescent carbon quantum dots in metal-organic frameworks for enhancing chemical sensing. Anal. Chem. 86(2), 1223–1228 (2014). doi:10.1021/ac403536a
Y. Dong, R. Wang, W. Tian, Y. Chi, G. Chen, “Turn-on” fluorescent detection of cyanide based on polyamine-functionalized carbon quantum dots. RSC Adv. 4(8), 3701–3705 (2014). doi:10.1039/c3ra45893h
Q. Qu, A. Zhu, X. Shao, G. Shi, Y. Tian, Development of a carbon quantum dots-based fluorescent Cu2+ probe suitable for living cell imaging. Chem. Commun. 48(44), 5473–5475 (2012). doi:10.1039/c2cc31000g
A. Zhu, Q. Qu, X. Shao, B. Kong, Y. Tian, Carbon-dot-based dual-emission nanohybrid produces a ratiometric fluorescent sensor for in vivo imaging of cellular copper ions. Angew. Chem. Int. Ed. 51(29), 7185–7189 (2012). doi:10.1002/anie.201109089
X. Liu, N. Zhang, T. Bing, D. Shangguan, Carbon dots based dual-emission silica nanoparticles as a ratiometric nanosensor for Cu2+. Anal. Chem. 86(5), 2289–2296 (2014). doi:10.1021/ac404236y
H. Sun, N. Gao, L. Wu, J. Ren, W. Wei, X. Qu, Highly photoluminescent amino-functionalized graphene quantum dots used for sensing copper ions. Chem. Eur. J. 19(40), 13362–13368 (2013). doi:10.1002/chem.201302268
S. Zhang, Q. Wang, G. Tian, H. Ge, A fluorescent turn-off/on method for detection of Cu2+ and oxalate using carbon dots as fluorescent probes in aqueous solution. Mater. Lett. 115, 233–236 (2014). doi:10.1016/j.matlet.2013.10.086
L. Liu, Y. Li, L. Zhan, Y. Liu, C. Huang, One-step synthesis of fluorescent hydroxyls-coated carbon dots with hydrothermal reaction and its application to optical sensing of metal ions. Sci. China Chem. 54(8), 1342–1347 (2011). doi:10.1007/s11426-011-4351-6
Y. Song, S. Zhu, S. Xiang, X. Zhao, J. Zhang, H. Zhang, Y. Fu, B. Yang, Investigation into the fluorescence quenching behaviors and applications of carbon dots. Nanoscale 6(9), 4676–4682 (2014). doi:10.1039/c4nr00029c
Y. Liu, N. Xiao, N. Gong, H. Wang, X. Shi, W. Gu, L. Ye, One-step microwave-assisted polyol synthesis of green luminescent carbon dots as optical nanoprobes. Carbon 68, 258–264 (2014). doi:10.1016/j.carbon.2013.10.086
S. Hu, Q. Zhao, Q. Chang, J. Yang, J. Liu, Enhanced performance of Fe3+ detection via fluorescence resonance energy transfer between carbon quantum dots and Rhodamine B. RSC Adv. 4(77), 41069–41075 (2014). doi:10.1039/c4ra06371f
X. Li, S. Zhu, B. Xu, K. Ma, J. Zhang, B. Yang, W. Tian, Self-assembled graphene quantum dots induced by cytochrome c: a novel biosensor for trypsin with remarkable fluorescence enhancement. Nanoscale 5(17), 7776–7779 (2013). doi:10.1039/c3nr00006k
S. Gomez-de Pedro, A. Salinas-Castillo, M. Ariza-Avidad, A. Lapresta-Fernandez, C. Sanchez-Gonzalez, C.S. Martinez-Cisneros, M. Puyol, L.F. Capitan-Vallvey, J. Alonso-Chamarro, Microsystem-assisted synthesis of carbon dots with fluorescent and colorimetric properties for pH detection. Nanoscale 6(11), 6018–6024 (2014). doi:10.1039/c4nr00573b
W. Wei, C. Xu, J. Ren, B. Xu, X. Qu, Sensing metal ions with ion selectivity of a crown ether and fluorescence resonance energy transfer between carbon dots and graphene. Chem. Commun. 48(9), 1284–1286 (2012). doi:10.1039/c2cc16481g
Y. Dong, G. Li, N. Zhou, R. Wang, Y. Chi, G. Chen, Graphene quantum dot as a green and facile sensor for free chlorine in drinking water. Anal. Chem. 84(19), 8378–8382 (2012). doi:10.1021/ac301945z
Z. Huang, F. Lin, M. Hu, C. Li, T. Xu, C. Chen, X. Guo, Carbon dots with tunable emission, controllable size and their application for sensing hypochlorous acid. J. Lumin. 151, 100–105 (2014). doi:10.1016/j.jlumin.2014.02.013
H.X. Zhao, L.Q. Liu, Z.D. Liu, Y. Wang, X.J. Zhao, C.Z. Huang, Highly selective detection of phosphate in very complicated matrixes with an off-on fluorescent probe of europium-adjusted carbon dots. Chem. Commun. 47(9), 2604–2606 (2011). doi:10.1039/c0cc04399k
J.M. Bai, L. Zhang, R.P. Liang, J.D. Qiu, Graphene quantum dots combined with europium ions as photoluminescent probes for phosphate sensing. Chem. Eur. J. 19(12), 3822–3826 (2013). doi:10.1002/chem.201204295
J.J. Liu, X.L. Zhang, Z.X. Cong, Z.T. Chen, H.H. Yang, G.N. Chen, Glutathione-functionalized graphene quantum dots as selective fluorescent probes for phosphate-containing metabolites. Nanoscale 5(5), 1810–1815 (2013). doi:10.1039/c3nr33794d
J. Xu, Y. Zhou, G. Cheng, M. Dong, S. Liu, C. Huang, Carbon dots as a luminescence sensor for ultrasensitive detection of phosphate and their bioimaging properties. Luminescence 30(4), 411–415 (2015). doi:10.1002/bio.2752
Y.H. Li, L. Zhang, J. Huang, R.P. Liang, J.D. Qiu, Fluorescent graphene quantum dots with a boronic acid appended bipyridinium salt to sense monosaccharides in aqueous solution. Chem. Commun. 49(45), 5180–5182 (2013). doi:10.1039/c3cc40652k
Z.B. Qu, X.G. Zhou, L. Gu, R.M. Lan, D.D. Sun, D.J. Yu, G.Y. Shi, Boronic acid functionalized Graphene quantum dots as fluorescent. Chem. Comm. 49(84), 9830–9832 (2013). doi:10.1039/C3CC44393K
L. Zhu, X. Cui, J. Wu, Z. Wang, P. Wang, Y. Hou, M. Yang, Fluorescence immunoassay based on carbon dots as labels for the detection of human immunoglobulin G. Anal. Methods 6(12), 4430–4436 (2014). doi:10.1039/c4ay00717d
H. Zhao, Y. Chang, M. Liu, S. Gao, H. Yu, X. Quan, A universal immunosensing strategy based on regulation of the interaction between graphene and graphene quantum dots. Chem. Commun. 49(3), 234–236 (2013). doi:10.1039/c2cc35503e
D. Bu, H. Zhuang, G. Yang, X. Ping, An immunosensor designed for polybrominated biphenyl detection based on fluorescence resonance energy transfer (FRET) between carbon dots and gold nanoparticles. Sens. Actuat. B Chem. 195, 540–548 (2014). doi:10.1016/j.snb.2014.01.079
Y. Wang, L. Zhang, R.P. Liang, J.M. Bai, J.D. Qiu, Using graphene quantum dots as photoluminescent probes for protein kinase sensing. Anal. Chem. 85(19), 9148–9155 (2013). doi:10.1021/ac401807b
Z.S. Qian, X.Y. Shan, L.J. Chai, J.J. Ma, J.R. Chen, H. Feng, DNA nanosensor based on biocompatible graphene quantum dots and carbon nanotubes. Biosens. Bioelectron. 60, 64–70 (2014). doi:10.1016/j.bios.2014.04.006
Y. Shi, Y. Pan, H. Zhang, Z. Zhang, M.J. Li, C. Yi, M. Yang, A dual-mode nanosensor based on carbon quantum dots and gold nanoparticles for discriminative detection of glutathione in human plasma. Biosens. Bioelectron. 56, 39–45 (2014). doi:10.1016/j.bios.2013.12.038
S. Li, J. Luo, G. Yin, Z. Xu, Y. Le, X. Wu, N. Wu, Q. Zhang, Selective determination of dimethoate via fluorescence resonance energy transfer between carbon dots and a dye-doped molecularly imprinted polymer. Sens. Actuat. B Chem. 206, 14–21 (2015). doi:10.1016/j.snb.2014.09.038
L. Wu, M. Li, M. Zhang, M. Yan, S. Ge, J. Yu, Ultrasensitive electrochemiluminescence immunosensor for tumor marker detection based on nanoporous sliver@carbon dots as labels. Sens. Actuat. B Chem. 186, 761–767 (2013). doi:10.1016/j.snb.2013.06.092
J. Lou, S. Liu, W. Tu, Z. Dai, Graphene quantums dots combined with endonuclease cleavage and bidentate chelation for highly sensitive electrochemiluminescent DNA biosensing. Anal. Chem. 87(2), 1145–1151 (2015). doi:10.1021/ac5037318
J. Shi, C. Lu, D. Yan, L. Ma, High selectivity sensing of cobalt in HepG2 cells based on necklace model microenvironment-modulated carbon dot-improved chemiluminescence in Fenton-like system. Biosens. Bioelectron. 45, 58–64 (2013). doi:10.1016/j.bios.2013.01.056
M. Amjadi, J.L. Manzoori, T. Hallaj, Chemiluminescence of graphene quantum dots and its application to the determination of uric acid. J. Lumin. 153, 73–78 (2014). doi:10.1016/j.jlumin.2014.03.020
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Dong, Y., Cai, J., Chi, Y. (2016). Carbon Based Dots and Their Luminescent Properties and Analytical Applications. In: Yang, N., Jiang, X., Pang, DW. (eds) Carbon Nanoparticles and Nanostructures. Carbon Nanostructures. Springer, Cham. https://doi.org/10.1007/978-3-319-28782-9_6
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