Abstract
The advent and use of advanced eco-friendly energetic materials to obtain higher and higher energy and reduced vulnerability, improved mechanical properties along with reduced signature profile and extended useful life has assumed very high importance these days. Use of new powerful and green oxidizers like ADN, HNF and ammonium ozonide along with energetic binders like GAP, BAMO and BAMO-THF copolymer can boost specific impulse (Is) to more than 320 s. Inclusion of energetic plasticizers like tetra azido malonate and tetra azido glutarate can enhance energy further. Likewise, inclusion of nitrogen-rich compounds like nitro guanidinium azides, N8, N10, etc., can boost energy further on higher side. Addition of nano metal powders and nano metal hydrides is likely to enhance burn rates significantly. Thus, there is need to generate reliable exhaustive technical data on the utility of new eco-friendly materials reported recently to obtain unthinkable boost in energy and burn rates.
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Abbreviations
- ADN:
-
Ammonium DiNitramide
- AMMO:
-
3-AzidoMethyl 3-Methyl Oxetane
- AN:
-
Ammonium -Nitrate
- AP:
-
Ammonium Perchlorate
- BAMO:
-
3,3’-Bis(AzidoMethyl) Oxetane
- BAMO-THF:
-
Copolymer of 3,3’-Bis(AzidoMethyl) Oxetane and TetraHydroFuran
- BDNPA/F:
-
Eutectic Mixture of Bis(2,2-DiNitroPropyl)Acetal/Formal
- BP:
-
Boiling Point
- Bu-NENA:
-
n-Butyl-NitratoEthylNitrAmines
- BTTN:
-
ButaneTriol TriNitrate
- CMDB:
-
Composite Modified Double-Base
- CP:
-
Composite Propellant
- CL-20:
-
2,4,6,8,10,12 - hexanitro- 2,4,6,8,10,12-hexaazaisowurtzitane
- DEGBAA:
-
DiEthylene Glycol Bis Azido Acetate
- DEGDN:
-
DiEthylene Glycol DiNitrate
- DNAPE:
-
DiAzido 3-Nitraza Pentane
- DNP:
-
DiNitro Piperazine
- DOA:
-
DiOctyl Adipate
- DOP:
-
DiOctyl Phatalate
- EGBAA:
-
Ethylene Glycol Bis Azido Acetate
- GAP:
-
Glycidyl Azide Polymer
- HE:
-
High Explosives
- HEMRL:
-
High-Energy Materials Research Laboratory
- HMX:
-
Cyclotetramethylenetetranitramine, High Melting Explosive (also known as Octogen, Her Majesty’s Explosive)
- HNC:
-
High-Nitrogen rich Compounds
- HNB:
-
HexaNitroBenzene
- HNF:
-
Hydrazinium NitroFormate
- HTPB:
-
Hydroxyl-Terminated PolyButadiene
- HTPBCP:
-
Co-polymer of Hydroxyl Terminated PolyButadieneandCaProlactone
- HTPE:
-
Hydroxyl-TerminatedPolyEether
- MP:
-
Melting Point
- NC:
-
NitroCellulose
- NG:
-
NitroGlycerine
- NIMMO:
-
3-NitratoMethylMethylOxetane
- OB:
-
Oxygen Balance
- ONC:
-
OctaNitroCubane
- PEP:
-
Propellant Evaluation Program
- PETN:
-
PentaErythritol Tetra Nitrate
- PGN:
-
PolyGlycidyl Nitrate
- PolyGlyn:
-
Polymer of 2-NitratoMethylOxirane
- PSAN:
-
Phase Stabilized Ammonium Nitrate
- R&D:
-
Research and Development
- RDX:
-
Cyclotrimethylenetrinitramine, Research Department eXplosive (also known as Hexogen, Cyclonite, T4, Royal Demolition Explosive)
- TATB:
-
TriAmino Trinitro Benzene
- TDI:
-
2,4-Toluene diisocyanate
- TEGDN:
-
TryEthylene Glycol DiNitrate
- TMETN:
-
TryMethylol EthaneTriNitrate
- TNAZ:
-
TriNitro AZitidine
- VOD:
-
Velocity Of Detonation
References
Gonser BW (1968) Modern materials; advances in development and applications, vol 6. Academic, New York
Shorr M, Zaehringer AJ (1967) Solid rocket technology. Wiley, New York
Gold RF (1969) Propellant manufacture, hazards and testing, vol 88, Advances in chemistry. American Chemical Society, Washington, DC
Warren FA (1970) Solid propellant technology, vol 10, AIAA selected Reprint. AIAA, Washington, DC
Kuo KK, Summerfield M (1984) Progress in astronautics and aeronautics, vol. 90. Fundamental of solid propellant combustion. AIAA, New York
Williams FA, Barrère M, Huang NC (1969) Fundamental aspects of solid propellant rockets, AGARDograph 116. Technivision Services, Slough
Singh H (2008) Advanced green, clean or alternate rocket propellants. International workshop on processing of composite propellants, H.E.M.R.L, Pune, Oct 18–20
Pundlik SM et al (2000) Influence of dinitro pipeazine on the pressure index of extruded double base propellants. J Energetic Mater 18:61–82
Bhatt VK et al (1995) Studies on block co-polymer based fuel rich propellants. International workshop on chemical gas dynamics and combustion of energetic materials ,TW95. June 1995
Singh H (2013) Emerging trends of R&D in the field of High Energy Materials. 9th international seminar on high energy materials and eco-friendly green applications, Simahara, Kanagawa, 7–9 Oct
Borman S (1994) Advanced energetic materials for military and space applications. Chem Eng News 72:18–22
Hormuz P, Mama (1996) Solid rocket propellants – latest developments promise significant advances, Spaceflight, vol 38, The British Interplanetary Magazine, London, UK
David E et al (2000) A novel high nitrogen energetic material. Angew Chem Int Ed 39(10):1791–1793
Chakravarthy SR (1998) Characterization of heterogeneous solid propellants. In: Krishnan S et al (eds) Propellant and explosives technology. Allied Publishers Limited, New Delhi (chapter3)
Pak ZP (1993) Some ways to higher environmental safety of solid rocket propellant applications. AIAA paper 93- 1755
Schoyer HFR et al (1995) High performance propellants based on hydrazinium nitro- formate. J Propuls Power 11:856–869
Schoyer HFR et al (1995) Advanced solid propellants based on HNF – a status report
Frenkel MB et al (1992) Historical development of glycidyl azide polymer. J Propuls Power 8:560–563
Vandenburg FJ (1972) Polymers containing azido methyl side chains, US Patent 3,645,317
Ahad E (1992) Preparation and uses of branched hydroxyl terminated azide rubbers, US Patent 5,130,381
Nair JK et al (2000) Synthesis and characterization of BAMO, its precursor, polymer and co-polymer with THF. In: Proceedings 3rd international conference on high energy materials, Thiruvananthapuram
Frenkel MB et al (1981) Synthesis of energetic compounds, CPIA Pub.340, Jannaf propulsion meeting, England
Nazare AN et al (1997) Burn rate studies of gas generator propellants containing AP/RDX. Chapter in book, “Challenges in propellant and combustion – 100 years after Noble”, Published by Begell House
Sanghavi RR et al (2001) Studies on thermoplastic elastomers based propellant compositions. J Energetic Mater 19:79–95
Kumari D (2014) Ph.D. thesis, Synthetical approaches to novel azido esters and their applications in LOVA propellants, D.I.A.T., Pune
Kumari D, Yamajala KDB, Singh H, Sanghavi RR, Asthana SN, Raju K, Banerjee S (2013) Application of azido ester as energetic plasticizer for LOVA propellants formulations. Propellants Explos Pyrotech 38:805–809
Singh H, Shekhar H (2005) Science and technology of solid rocket propellants, Print well, India
Agrawal JP, Singh H (1993) Propellants Explos Pyrotech 18:106–110
Ghosh K, Pant CS, Sanghavi R, Adhav S, Singh H (2009) Studies on triple base gun propellant based on two energetic azido esters. J Energ Mater 27:40–50
Frankel MB et al (1984) US Patent 44,328,17
Sayles DC (1991) US Patent 5059260
Dendage PS et al (2003) Ecofriendly energetic oxidizers HNF and propellants based on HNF. J Indian Chem Soc 80:563–568
Dendage PS et al (2000) Thermal decomposition of HNF and propellants based on HNF. In: Proc 3rd international conference on high energy materials, VSSC, Trivandrum, 6–8 Dec
Nair UR et al (2004) Studies on advanced CL-20 based CMDB propellants. J Propuls Power 20:952–955
Singh H (2005) Current trends of R&D in the field of high energy materials. Proc int. seminar on high energy material. Japan Explosive Society, Tokyo
Talawar MB et al (2005) Novel ultra high energy materials. Combust Explosion Shock Waves 141:264–277
Gartner J (2005) Military reloads with nanotech. Technol Rev MIT, USA. Accessed May 2014
Brown M (2010) Nanofibres defuse explosives. Chem World, R Soc Chem, Cambridge, UK. Accessed May 2014
Granier J (2009) Combustion characteristic of Al nano particles and nano composites, Ph.D. thesis, D.I.A.T., Pune
Roberts G, Dreger A (2010) Advanced pyrotechnic or advanced materials discovered in WTC dust, ACS new service weekly
Dadson B (2012) Most powerful military explosive for use, ACS new science weekly
Weiser (2013) ADN based propellants, 9th International high energy materials (HEMs) workshop, Sagamihara, Kanagawa, Japan
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Singh, H. (2017). Survey of New Energetic and Eco-friendly Materials for Propulsion of Space Vehicles. In: De Luca, L., Shimada, T., Sinditskii, V., Calabro, M. (eds) Chemical Rocket Propulsion. Springer Aerospace Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-27748-6_4
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