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Influence of Temperature on Supercapacitor Performance

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Thermal Effects in Supercapacitors

Part of the book series: SpringerBriefs in Applied Sciences and Technology ((BRIEFSTHERMAL))

Abstract

The previous chapter considered the influence of temperature on different supercapacitor components, including electrolytes, electrodes and separators. The thermophysical properties of these components dictate the electrochemical performance of a supercapacitor at different temperatures, which is reflected by two crucial metrics-capacitance and ESR—and also others such as aging, self-discharge and leakage. For instance, the high ionic conductivity and high dissociation rate of the electrolytes at elevated temperatures facilitates ion migration towards the electric double layer [1], leading to a low ESR. Capacitance depends on the amount of ions aggregated at the interface between electrodes and electrolytes, which is determined by the effective specific surface area of the electrodes. Higher temperature promotes the migration of ions to the innermost pores of electrodes, leading to an increase in effective surface area, and thus a higher capacitance. Energy and power densities are directly related to capacitance and ESR. Aging and self-discharge are also important parameters to evaluate the performance of supercapacitors in practical applications. In this chapter, the influence of temperature on electrochemical performance including extreme-temperature performance is discussed.

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  1. Birck Nanotechnology Center, Purdue University, West Lafayette, IN, USA

    Guoping Xiong, Arpan Kundu & Timothy S. Fisher

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  1. Guoping Xiong
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  2. Arpan Kundu
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  3. Timothy S. Fisher
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Correspondence to Guoping Xiong .

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Xiong, G., Kundu, A., Fisher, T.S. (2015). Influence of Temperature on Supercapacitor Performance. In: Thermal Effects in Supercapacitors. SpringerBriefs in Applied Sciences and Technology(). Springer, Cham. https://doi.org/10.1007/978-3-319-20242-6_4

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  • DOI: https://doi.org/10.1007/978-3-319-20242-6_4

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