Abstract
ChapterĀ 5 contains information about applications and physicochemical properties of inorganic citrates. These include solubilities in water, boiling temperatures, freezing points and activity and osmotic coefficients at these temperatures. Presented vapour pressures of water over unsaturated and saturated solutions of alkali metal citrates are thermodynamically analyzed to give activities of components in these systems. From other properties, it also contains sound velocities, densities of binary and ternary solutions and partition data in two-phase ternary systems, namely in the alkali metal citrate + aliphatic alcohol + water and alkali metal citrate + polyethylene glycol (PEG) + water systems. In addition, it includes the literature sources leading to data about crystal structure of many inorganic citrates.
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References
Love WE, Patterson AL (1960) X-ray analysis of the substrates of aconitase. III. Crystallization, cell constants, and space groups of some alkali citrates. Acta Crystallogr 13:426ā428
Rossi M, Rickles LF, Glusker JP (1983) Trilithium citrate pentahydrate, C6H5O7 3ā 3Li+.5H2O. Acta Crystallogr C 89:987ā980
Glusker JP, van der Helm D, Love WE, Dornberg M, Minkin JA, Johnson CK, Patterson AL (1965) X-ray crystal analysis of the substrates of aconitase. VI. The structures of sodium and lithium dihydrogen citrates. Acta Crystallogr 19:561ā572
Tobon-Zapata GE, Piro DE, Etcheverry SB, Baran EJ (1998) Crystal structure and IR spectrum of lithium citrate monohydrate. Z Anorg Allg Chem 13(624):721ā724
Gabe EJ, Glusker JP, Minkin JA, Patterson AL (1967) X-ray analysis of the substrates of aconitase. VII. The structure of lithium ammonium hydrogen citrate monohydrate. Acta Crystallogr 22:366ā375
Venkateswarlu M, Rao TB, Rao KK (1989) Growth and characterization of triammonium citrate. Bull Mater Sci 12:143ā146
Zacharias DE, Glusker JP (1993) Structure of a citrate double salt: potassium dihydrogen citrate-lithium potassium hydrogen citrate monohydrate. Acta Crystallogr C 13:1727ā1730
Burns DM, Iball J (1954) Unit cells and space groups of citric acid and some potassium and sodium citrates. Acta Crystallogr 7:137ā138
Fisher A Palladino G (2003) Trisodium citrate dihydrate. Acta Crystallogr E 59:m1080ām1082
Viossat B, Rodier N, Eberly J (1986) Crystal structure of sodium citrate hydrate. Bull Soc Chim France 522ā525
Kim Y, Koo HG, Shin DH, Park LO, Lee JH, Jang HG, Kim C (2010) Zinc citrate with alkali metal ammonium cations: crystal structure of K4[Zn(Cit)2]. J Struct Chem 51:382ā385
Glusker JP, van der Helm D, Love WR, Dornberg ML, Baran EJ (1960) X. The state of ionization of crystalline sodium dihydrogen citrate. J Am Chem Soc 82:2964ā2965
Zacharias DE, Glusker JP (1993) Structure of dipotassium hydrogen citrate. Acta Crystallogr C 13:1730ā1732
Nordman CE, Weldon AS, Patterson AL (1960) X-ray crystal analysis of the substrates of aconitase. I. Rubidium dihydrogen citrate. Acta Crystallogr 13:414ā417
Holcomb M, Strumpel M, Butler WM, Nordman (1987) A crystallographic study of the phase transition in rubidium dihydrogen citrate. Acta Crystallogr B 43:313ā318
Johnson CK (1965) X-ray analysis of the substrates of aconitase. V. Magnesium citrate decahydrate [Mg(H2O)6] [MgC6H5O7(H2O)]2ā ā2H2O. Acta Crystallogr 18:1004ā1018
Pogainis E.M, Shaw EH Jr (1957) The unit-cell dimensions of tricalcium citrate tetrahydrate. Proc South Dakota Acad Sci 36:56ā59
Herdtweck E, Kornprobst T, Sieber R, Straver L Plank J (2011) Crystal structure, synthesis and properties of tri-calcium di-citrate tetrahydrate [Ca3(C6H5O7)2(H2O)2]Ā·2H2O. Z Anorg Allgem Chemie 637:655ā659
Sheldrick B (1965) Calcium hydrogen citrate trihydrate. Acta Crystallogr B 30:2056ā2057
Wu H, Pan S, Yu H, Huang Z, Jia D (2012) Synthesis structure and characterization of layered Ca{B(C6H6O7)2]Ā·(H2O)4āāHCl. J Mol Struct 1027:111ā115
Zacharias DE, Glusker JP (1993) Structure of strontium citrate pentahydrate. Acta Crystallogr C 13:1732ā1735
Vanhoyland G, Pagnaer J, DāHaen J, Mullens S Mullens J (2005) Characterization and structural study of lanthanum citrate trihydrate. J Solid Chem 178:166ā171
Zviedre II, Fundamenskii VS, Krasnikov VV, Kolesnikova (1984) Crystal structure of potassiumborocitrate(dicitrateborate) [K(C6H6O7)2B]Ā·2H2O. Zh Strukt Khim 25:95ā101
Zviedre II, Belyakov SV (2011) A restudy of the crystal structure of tetraaquastrontium dicitratoborate trihydrate. Russ J Inorg Chem 56:375ā382
Zviedre II, Belyakov SV (2012) Crystal structure of a new copper(II) complex with borocitric acid. Russ J Inorg Chem 57:1321ā1327
Svoronos DR, Boulhassa S, Guillaumont R (1981) Citric complexes and neodymium citrate: NdCitĀ·3H2O. J Inorg Nucl Chem 43:1541ā1545
Dakanali M, Kefalas ET, Raptopoulou CP, Terzis A, Voyiatzis G, Kyrikou I, Mavromoustakos T Salifoglou A (2003) A new dinuclear Ti(IV)-peroxo-citrate complex from aqueous solutions. Synthetic, structural, and spectroscopic studies in relevance to aqueous titanium(IV)-peroxy-citrate speciation. Inorg Chem 42:4632ā4639
Kakihana M, Tada M, Shiro M, Petrykin V, Osada M, Nakamura Y (2001) Structure and stability of water soluble (NH4)8[Ti4(C6H4O7)4(O2)4]Ā·8H2O. Inorg Chem 40:891ā894
Panagiotidis P, Kefalas ET, Raptopoulou CP, Terzis A, Mavromoustakos T Salifoglou A (2008) Delving in the complex picture of Ti(IV)-citrate speciation in aqueous media: synthetic, structural, and electrochemical considerations in mononuclear Ti(IV) complexes containing variably deprotonated citric ligands. Inorg Chim Acta 361:2210ā2224
Deng YF, Zhang HL, Hong QM, Weng WZ, Wan HL, Zhou ZH (2007) Titanium-based mixed oxides from a series of titanium(IV) citrate complexes. J Solid State Chem 180:3152ā3159
Collins JM, Uppal R, Incarvito CD, Valentine AM (2005) Titanium(IV) citrate speciation and structure under environmentally and biologically relevant conditions. Inorg Chem 49:3431ā3440
Deng YF, Zhou ZH Wan HL (2004) pH-dependent isolation and spectroscopic, structural and thermal studies of titanium citrate complexes. Inorg Chem 43:6266ā6273
Tsaramyrsi M, Kaliva M, Salifoglou A, Raptopoulou CP, Terzis A, Tangoulis V Giaprintzakis J (2001) Vanadium(IV) ā citrate complex interconversions in aqueous solutions. A pH-dependent synthetic, structural, spectroscopic, and magnetic study. Inorg Chem 40:5772ā5779
Kaliva M, Raptopoulou CP, Terzis A Salifoglou A (2003) Systematic studies on pH-dependent transformations of dinuclear vanadium(V)-citrate complexes inaqueous solutions. A perspective relevance to aqueous vanadium(V)-citrate speciation. J Inorg Biochem 93:161ā173
Zhou ZH, Yan WB, Wan HL, Hu SZ (1995) Metal-hydroxycarboxylate interactions: syntheses and structures of K2[VO2(C6H6O7)]2ā ā4H2O and (NH4)2[VO2(C6H6O7)]2ā ā2H2O. J Chem Crystal 25:807ā811
Zhou ZH, Wan HL, Hu SZ, Tsai KR (1995) Syntheses and structures of the potassium-ammonium dioxocitratovanadate(V) and sodium oxocitratovanadate(IV) dimer. Inorg Chim Acta 237:193ā197
Zhou ZH, Zhang H, Jiang YQ, Lin DH, Wan HL, Tsai KR (1999) Complexation between vanadium(V) and citrate: spectroscopic and structural characterization of a dinuclear vanadium(V) complex. Transit Met Chem 24:605ā609
Wright DW, Humiston PA, Orme-Johnson WH, Davis WM (1995) A unique coordination mode for citrate and a transition metal: K2[V(O)2C6H6O7]2ā ā4H2O. Inorg Chem 34:4194ā4197
Gunari P, Krishnasamy SSO, Bai SQ, Hor TSA (2010)Crystallographic identification of an unusual homoleptic palladium citrate [Na(OH2)6]Ā·{[Na3(OH2)8}3{NaPd3(C6H4O7)3]2}Ā·H2O stabilized by intermetalic aggregation with sodium and heavy hydration. Dalton Trans 39:9462ā9464
Fedosseev AM, Grigoriev MS, Budantseva NA, Guillaumont D, Le Naour C, Simoni E, Den Auwer C, Moisy P (2010) Americium (III) coordination chemistry. An unexplored diversity of structure and bonding. Comp Rend Chimie 13:839ā848
Keizer TS, Scott BL, Sauer NN, McCleskey TM (2005) Stable, soluble beryllium aluminum citrate complexes inspired by the emerald mineral structure. Angew Chem Int Ed Engl 117:2455ā2458
Kaliva M, Giannadaki T Salifoglou A (2002) A new dinuclear vanadium(V)-citrate complex from aqueous solutions. Synthesis, structural, spectroscopic, and pH-dependent studies in relevance to aqueous vanadium(V) ā citrate speciation. Inorg Chem 41:3850ā3858
Djordjevic C, Lee M, Sinn E (1989) Oxyperoxo(citrate)- and dioxo(citrate) vanadates(V): synthesis, spectra, and structure of a hydroxyl oxygen bridged dihydrate, K2[V2O6(Hcit)2] 2H2O. Inorg Chem 28:719ā723
Gabriel C, Raptopoulou CR, Terzis A, Tangocelis V, Mateescu C, Salifoglou A (2007) pH-specific synthesis and spectroscopic, structural and magnetic studies of a chromium(III)-citrate species. Aqueous solution speciation of the binary chromium(III)-citrate system. Inorg Chem 46:2998ā3009
Gabriel C, Raptopoulou CR, Drouza C, Lalioti N Salifoglou A (2009) Synthesis, spectroscopic, structural and magnetic studies of new binary Cr(III)-citrate. pH-specific structural variants from aqueous media. Polyhedron 28:3209ā3220
Zhou ZH, Wan H.l Tsai KR (2000) Syntheses and spectroscopic and structural characterization of molybdenum(VI) citrate monomeric raceme and dimer, K4[MoO3(cit)]ā 2H2O and K4[(MoO2)2O(Hcit)2].ā4H2O. Inorg Chem 39:59ā64
Zhou ZH, Wan HL, Tsai KR (1997) Molybdenum(VI) complex with citric acid: synthesis and structural characterization of 1:1 ratio citro: molybdate K2Na4[(Mo2)2O(Cit)2]Ā·5H2O. Polyhedron 16:75ā79
Cruywagen JJ, Saayman LJ, Niven ML (1992) Complexation between tungsten(VI) and citrate: The crystal and molecular structure of a dinuclear complex, Na6[W2O5(cit)2]ā 10H2O. J Crystal Spectr Res 22:737ā740
Llopis E, Ramirez JA, Domenech A Cervilla A (1993) Tungsten(VI) complexes with citric acid (H4cit). Structural characterization of Na6[{WO2(Cit)2}O}]Ā·10H2O. J Chem Soc Dalton Trans 1121ā1124
Zhang H, Zhao H, Jiang YQ, Hou SY, Zhou ZH Wan HL (2003) pH-mol-ratio dependent tungsten(VI)-citrate speciation from aqueous solutions: syntheses, spectroscopic properties and crystal structures. Inorg Chim Acta 351:311ā3188
Li D, Cui LF, Xing YH, Xu JQ, Yu JH, Wang TG, Jia HQ Hu NH (2007) Syntheses and structural characterization of new tungsten(VI) complexes with carboxylate ligands. J Mol Struct 832:138ā145
Xu JQ, Li DM, Xing YH, Wang RZ, Liu SQ, Wang TG, Xing Y, Lin YH Jia HQ (2000) Synthesis and structure of a novel mononuclear tungsten(VI) complex, (NH4)3[Li(H2O)3WO3(C6H4O7)]. J Coord Chem 53:25ā33
Carrell HL, Glusker JP (1973) Manganous citrate decahydrate. Acta Crystallogr B 29:638ā340
Glusker JP, Carrell HL (1973) X-ray crystal analysis of substrates of aconitase. XI. Manganous citrate decahydrate. J Mol Struct 15:151ā159
Matzapetakis M, Karligiano N, Bino A, Dakanali M, Raptopoulou CP, Tangoulis V, Terzis A, Giapintzakis J, Salifoglou A (2000) Manganese citrate chemistry: synthesis, spectroscopic studies, and structural characterizations of novel mononuclear water-soluble citrate complexes. Inorg Chem 39:4044ā4051
Strouse J, Layten SW, Strouse CE (1977) Structual studies of transition metal complexes of triinized and tetraionized citrate. Models for the citrate ion to transition metal ion insolution and at the active site of aconitase. J Am Chem Soc 99:562ā572
Matzapetakis M, Raptopoulou CP, Tsohos A, Papaefthymiou V, Moon N, Salifoglou A (1998) Synthesis, spectroscopic and structural characterization of the first mononuclear, water soluble iron-citrate complex. J Am Chem Soc 120:13266ā13267
Kotsakis N, Raptopoulou CP, Tangoulis V, Terzis A, Giapintzakis J, Jakusch T, Kiss T Salifoglou A (2003) Correlations of synthetic, spectroscopic, structural, and speciation studies in the biologically relevant cobalt(II)-citrate system. The tale of the first aqueous dinuclear cobalt(II)-citrate complex. Inorg Chem 42:22ā31
Zhou ZH, Lin YJ, Zhang HB, Lin GD Tsai KR (1997) Syntheses, structures and spectroscopic properties of nickel(II) citrate complexes (NH4)2[Ni(Hcit)(H2O)2]2-2H2O and (NH4)4[Ni(Hcit)2]-2H2O. J Coord Chem 42:131ā141
Burshtein IF, Kiosse NV, Ablov AV, Malinovski TI, Shchedrin BM, Rannev NV (1978) Structure of a complex of antimony(III) with citric acid. Dokl Akad Nauk SSSR 239:90ā93
Baker EN, Baker HM, Anderson BF Reeves RD (1983) Chelation of nickel(II) by citrate. The crystal structure of a nickel-citrate complex K2[Ni(C6H5O7)(H2O)2]2ā ā4H2O. Inorg Chim Acta 78:281ā285
Mastropaolo D, Powers DA, Potenza JA, Schugar HJ (1976) Crystal structure and magnetic properties of copper citrate dehydrate Cu2C6H4O7ā ā2H2O. Inorg Chem 15:1444ā1449
Bott RC, Sagatis DS, Lynch DE, Smith G, Kennard CHL, Mak TCW (1991) The preparation and crystal structure of ammonium biscitrate(3-)-cuprate(II). Aust J Chem 44:1495ā1498
Smith G, Sagatys DS, Bott RC, Lynch DE (1992) Crystallographic evidence for the presence of both(2ā) and (3ā) citrate species in a mixed-metal complex [CuSb(C6H6O7 2āC6H5O7 3ā)(H2O)2].2.5H2O. Polyhedron 11:631ā634
Swanson R, Ilsley WH, Stanislowki AG (1983) Crystal structure of zinc citrate. J Inorg Biochem 18:187ā194
Kefalas ET, Dakaneli M, Panagiotidis P, Raptopoulou CP, Terzis A, Mavromoustakos T, Kyrikon I, Karligiano N, Bino A, Salifoglou A (2005) pH-Specific aqueous synthetic chemistry in the binary cadmium(II)-citrate system. Gaining insight into cadmium(II)-citrate speciation with relevance to cadmium toxicity. Inorg Chem 44:4818ā4828
Matzapetakis M, Raptopoulou CP, Terzis A, Lakatos A, Kiss T, Salifoglou A (1999) Synthesis, structural characterization, and solution behavior of the first mononuclear, aqueous aluminum citrate complex. Inorg Chem 38:618ā619
Matzapetakis M, Kourgiantakis M, Dakanali M, Raptopoulou CP, Tangoulis V, Terzis A, Lakatos A, Kiss T, Banyai I, Iordanidis L, Mavromoustakos T, Salifoglou A (2001) Synthesis pH-dependent structural characterization of aqueous aluminum and gallium citrate complexes. Inorg Chem 40:1734ā1744
OāBrien P, Salacinski H, Motevalli M (1997) The X-ray single crystal structure of a gallium citrate complex (NH4)3[Ga(C6H5O7)2]Ā·4H2O. J Am Chem Soc 119:12695ā12696
Hawkes GE, OāBrien P, Salicinski H, Motevalli M, Abrahams I (2001) Solid and solution state NMR spectra and the structure of the gallium citrate complex (NH4)3[Ga(C6H5O7)2]Ā·4H2O. Eur J Inorg Chem 1005ā1011
Martsinko EE, Minacheva LK, Pesaraglo AG, Seifullina II, Churakov AV, Sergienko VS (2011) Bis(citrate) germinates of bivalent 3d metals (Fe, Co, Ni, Cu, Zn): crystal and molecular structure of [Fe(H2O)6 Ge(Hcit)2]Ā·4H2O. Russ J Inorg Chem 56:1243ā1249
Deacon PR, Mahon MF, Molloy KC, Waterfield PC (1997) Synthesis and characterization of tin(II) and tin(IV) citrates. J Chem Soc Dalton Trans 3705ā3712
Chu C, Darling K, Netusil R, Doyle RP, Zubieta J (2011) Synthesis and structure of a lead(II)-citrate {Na(H2O)3[Pb5(C6H5O7)3(C6H6O7)(H2O)3]}Ā·9 5 H2O. Inorg Chim Acta 378:186ā193
Smith G, Sagatys DS, Bott RC, Lynch DE (1993) Group 15 complexes with carboxylic acids ā VI. Preparation and crystal structures of potassium antimony(III) citrate {[K2Sb4(citrate)8(H2O)2]} and lithium antimony(III) citrate{[LiSb(citrate)2(H2O)]Ā·2H2O}. Polyhedron 12:1491ā1497
Hartley DW, Smith G, Sagatys DS, Kennard CHL Antimony(III) complexes with carboxylic acids. Part 2. Preparation and crystal structures of [Sb2Ag2(C6H6O7)4] and [SbNa(C6H6O7)2(H2O)2].H2O. J Chem Soc Dalton Trans 2735ā2739
Antsyshkina AS, Sadikov GG, Kurskinova TB, Skorikov VM, Sergienko VS (2006) Synthesis and crystal structure of KBi (C6H4O7)Ā·3 5H2O. Russ J Inorg Chem 51:374ā385
Asato E, Katsura K, Mikuriya M, Fujii T, Reedijk J (1993) Synthesis structure, and spectroscopic characterization of bismuth citrate compounds and bismuth-containing ulcer healing agent colloidal bismuth subcitrate (CBS). 31. Crystal and solution structures of KNH4[Bi2(cit)2(H2O)2]Ā·(H2O)xā ā(xā=ā2, 4). Inorg Chem 32:5322ā5329
Asato E, Katsura K, Mikuriya M, Turpeinen U, Mutikainen I, Reedijk J (1995) Synthesis, structure, and spectroscopic characterization of bismuth citrate compounds and bismuth-containing ulcer healing agent colloidal bismuth subcitrate (CBS). 41. Crystal K(NH4)[Bi2(cit)2(H2O)2].(H2O)x (x = 2,4). Inorg Chem 34:2447ā2454
Wu H, Pan S, Jia D, Yu H, Chen Z (2012) New borate-citrate: synthesis, structure, and properties of Sr[B(C6H5O7)2 (H2O)4]Ā·3H2O. Z Anorg Allg Chem 638:856ā860
ThuĆ©ry P (2006) Uranyl ion complexation by citric and tricarballylic acids: hydrothermal synthesis and structure of two- and three-dimensional uranium-organic frameworks. Chem Commun 853ā855
Glusker JP (1980) Citrate conformation and chelation: enzymatic implications. Acc Chem Res 13:345ā352
Hahn L (1948) Stabilisation of penicillin-salt solutions with sodium citrate. Biochem Biophys Acta 2:113ā120
Deng YF, Jiang Q, Houg QM, Zhou ZH (2007) Speciation of water-soluble titanium citrates: synthesis, structural, spectroscopic properties and biological relevance Polyhedron 26:1561ā1569
Zang Q, Li N, Goebl J, Lu Z, Yin Y (2011) A systematic study of the synthesis of silver nanoplates: is citrate a āmagicā reagent? J Am Chem Soc 133:18931ā18939
Chou YH, Doraiswamy LK, Larson MA (2001) Studies of the dissolution rate of sparingly soluble calcium citrate in water. Chem Eng Comm 185:223ā236
Henglein A, Giersig M (1999) Formation of colloidal silver nanoparticles: capping action of citrate. J Phys Chem B 103:9533ā9539
Pillai ZS, Kamat PV (2004) What factors control the size and shape of silver-nanoparticles in the citrate ion reduction method. J Phys Chem B 108:945ā951
Pei L, Mori K, Adachi M (2004) Formation process of two-dimensional networked gold nanowires by citrate reduction of AuCl4 ā and the shape stabilization. Langmuir 20:7837ā7843
Ji X, Song X, Li J, Bai Y, Yang W (2007) Size control of gold nanocrystals in citrate reduction: the third role of citrate. J Am Chem Soc 129:13939ā13948
Ojea-JimĆ©nez I, Puntes V (2009) Instability of cationic gold nanoparticles bioconjugates: the role of citrate ions. J Am Chem Soc 131:13320ā13327
Xia H, Bai S, Hartmann J, Wang D (2010) Synthesis of monodisperse quasi-spherical gold nanoparticles in water via silver(I)-assisted citrate reduction. Langmuir 26:3585ā3589
Li H, Xia H, Wang D, Tao X (2013) Simple synthesis of monodisperse quasi-spherical, citrate stabilized silver nanocrystals in water. Langmuir 29:5074ā5079
Gajbhiye NS, Prasad S (1996) Thermal decomposition of hexahydrated nickel iron citrate. Thermochim Acta 285:325ā336
Hennings D, Mayr W (1978) Thermal decomposition of (BaTi) citrates into barium titanate. J Solid State Chem 26:329ā338
Tsay J, Fang T (1999) Effects of molar ratio of citric acid to cations and of pH value on the formation and thermal decomposition behavior of barium titanium citrate. J Amer Ceramic Soc 82:1409ā1415
Sankaranarayanan VK, Gajbhiye NS (1989) Thermal decomposition of dysprosium iron citrate. Thermochim Acta 153:337ā348
Sankaranarayanan VK, Gajbhiye NS (1990) Low-temperature preparation of ultrafine rare-earth iron garnets. J Amer Ceram Soc 73:1301ā1307
Chen R, So MH, Che CM, Sun H (2005) Controlled synthesis of high crystalline bismuth sulfide nanarods: using bismuth citrate as a precursor. J Mater Chem 15:4540ā4545
Prasad S, Vijayalakshmi A, Gujbhiye NS (1998) Synthesis of ultrafine cobalt-ferrite by thermal decomposition of citrate precursor. J Therm Anal Calorim 52:595ā607
Randhawa BS, Dosanjh HS, Kaur M (2009) Preparation of spinel ferrites from citrate precursor route. A comparative study. Ceram Int 35:1045ā1049
Devi PS, Rao MS (1989) Rare-earth chromium citrates as precursors for rare-earth chromities: lanthanum biscitrato chromium(III) dihydrate, La[Cr(C6H5O7)2]Ā·2H2O. Thermochim Acta 153:181ā191
MasÄŗowska J (1984) Thermal decomposition and thermofracto-chromatographic studies of metal citrates. J Therm Anal 29:895ā904
Srivastava A, Singh P, Gunjikar VG, Jose CJ (1984) Thermal decomposition of barium citrate. Thermochim Acta 76:249ā254
Srivastava A, Singh P, Gunjikar VG, Sinha APB (1985) Study of the thermal decomposition of iron and barium citrates. Thermochim Acta 86:77ā84
Srivastava A, Gunjikar VG, Sinha APB (1987) Thermoanalytical studies of zinc citrate, bismuth citrate and calcium citrate. Thermochim Acta 117:201ā217
Mansour AAA (1994) Thermal decomposition of magnesium citrate 14 hydrate. Thermochim Acta 233:231ā242
Mansour AAA (1994) Thermal decomposition of calcium citrate tetrahydrate. Thermochim Acta 233:243ā256
Mansour AAA (1994) Thermal decomposition of anhydrous bismuth citrate. Thermochim Acta 233:257ā268
TabĆ³n-Zapata GE, Ferrer EG, Etcheverry SB, Baran EJ (2000) Thermal behaviour of pharmacologically active lithium compounds. J Therm Anal Calorim 61:29ā35
Duval C (1962) Sur la stabilitĆ© thermique des Ć©talons analytiques. Microchim Acta 50(1):268ā274
Szynkaruk P, WesoÄŗowski. M, Samson-Rosa U (2010) Principal component analysis of thermal decomposition of magnesium salts used as drugs. J Therm Anal Calorim 101:505ā512
Radecki A, WesoÄŗowski M (1976) The thermal decomposition of bismuth(III) compounds used in medicine. Thermochim Acta 17:217ā229
Charles J, Kopf PW, Toby S (1966) The reaction of pyrophosphoric lead with oxygen. J Phys Chem 70:1478ā1482
Brown ME (1973) Thermal decomposition of lead citrate. J Chem Soc Faraday Trans I 69:1202ā1212
Bassi PS, Randhawa BS, Janwal HS (1984) Mƶssbauer study of the thermal decomposition of iron(III) citrate pentahydrate. J Therm Anal 29:439ā444
Devi PS, Rao MS (1992) Study of the thermal decomposition of lanthanum and chromium citrate hydrates. J Anal Appl Pyrolysis 22:187ā195
Erdey L, GĆ”l S, Liptay G (1964) Thermoanalytical properties of analytical grade reagents. Ammonium salts. Talanta 11:913ā940
MasÄŗowska J, Bielawski M, Baranowska A (1985) Thermoanalytical investigation of citric acid and complexe salts of transition metals with citric acid. Thermochim Acta 92:235ā239
Wu S, Chang Z, Wang K, Xiong W (1995) Preparation and thermal behaviour of rare earth citrate hydrates. J Therm Anal 45:199ā206
da Silva MFP, Matos JR, Isolani PC (2008) Synthesis characterization and thermal analysis of 1:1 and 2:3 lanthanide(II) citrates. J Therm Anal Calorim 94:305ā311
Popa M, Kakihana M (2001) Synthesis and thermoanalytical investigation of an amorphous praseodymium citrate. J Therm Anal Calorim 65:281ā293
Chatterjee KP, Dhar NR (1924) Studies of sparingly soluble salts, readily obtained from hot solutions of reacting substances. J Phys Chem 28:1009ā1028
Shear MJ, Kramer B (1928) Composition of bone. V. Some properties of calcium citrate. J Biol Chem 79:161ā175
Hastings AB, McLean FC, Eichelberger L, Hall JL, Da Costa E (1934) The ionization of calcium, magnesium and strontium citrates. J Biol Chem 107:351ā370
Joseph NR (1946) The dissociation constants of organic calcium complexes. J Biol Chem 164:529ā541
Boulet M, Marier JR (1960) Solubility of tricalcium citrate in solutions of variable ionic strength and milk ultrafiltrates. J Diary Sci 43:155ā164
Meyer JL (1974) Formation constants for interaction of citrate with calcium and magnesium ions. Anal Biochem 62:295ā300
Singh RP, Yeboah YD, Pambid ER, Debayle P (1991) Stability constant of the calcium-citrate(3ā) ion pair complex. J Chem Eng Data 35:52ā54
Apelblat A (1993) Solubilities of organic salts of magnesium, calcium, and iron in water. J Chem Thermodyn 25:1443ā1445
Ciavatta L, De Tommaso G, Iuliano M (2001) The solubility of calcium citrate hydrate in sodium perchlorate solutions. Anal Lett 34:1053ā1062
Gao J, Xie C, Wang Y, Xu Z, Hao H (2012) Solubility data of trisodium citrate hydrates in aqueous solution and crystal-solution interfacial energy of the pentahydrate. Cryst Res Technol 47:399ā403
Van Auken TV (1991) Solubility and heat of solution of potassium dihydrogen citrate. J Chem Eng Data 36:255ā257
Linke WF (1965) Solubilities. Inorganic and Metal-Organic Compounds. volĀ 2, 4thĀ edn. American Chemical Society, Washington, pĀ 51
Shear MJ, Kramer B, Resnikoff L (1929) Composition of bone. VIII. Conductivity titrations of calcium ion with chloride, acetate, lactate and citrate ions at 38Ā°. J Biol Chem 83:729ā735
Wiley WJ (1930) XCIV. The dissociation of calcium citrate. J Biochem 24:856ā859
Muus J, Lebel H (1936) On complex calcium citrate. Del Kgl Danske Videnskabernes Selskab (Mat Phys) 13:1ā17
Al-Khaldi MH, Nasr-El-Din AD, Mehta S, Al-Aamri AD (2007) Reaction of citric acid with calcite. Chem Eng Sci 62:5880ā5896
Bolton S (1960) The interaction of citrate with aspirin and benzoic acid. J Am Pharm Assoc 49:237ā242
Skornik NA, Serebrennikov VV (1963) Solubility of La, Pr, Sm, Gd, Yb, and Y citrates. Trudy Tomskogo Gos Univ Ser Khim 157:198ā201
Skornik NA, Serebrennikov VV (1963) Solubility of lanthanum, gadolinium and yttrium citrates in solutions of alkali metal and group II metal citrates. Trudy Tomskogo Gos Univ Ser Khim 157:307ā310
Skornik NA, Serebrennikov VV (1965) Dependence of solubility of citrates of some rare earth elements on the pH of the medium. Zhurn Neorg Khim 10:407ā409
Skorik NA, Kumok VN, Perov EI, Avgustan KP, Serebrennikov VV (1965) Complexes of rare earth citrates in acid solutions. Zhurn Neorg Khim 10:653ā656
Skornik NA, Serebrennikov VV (1966) Rare earth element citrates in aqueous solutions. Zhurn Neorg Khim 11:764ā765
Skorik NA, Kumok VN, Serebrennikov VV (1967) Thorium citrate. Radiokhimiya 9:515ā517
Skornik NA, Serebrennikov VV (1968) Rare-earth element hydroxycitrate complexes. Trudy Tomskogo Gos Univ Ser Khim 192:37ā39
Skorik NA, Kumok VN (1969) Solubility products of some metal citrates. Zhurn Neorg Khim 14:98ā101
Williamson AT (1944) The exact calculation of heats of solution from solubility data. Trans Faraday Soc 40:421ā436
Apelblat A (1994) Enthalpies of solution of citrates and hydrogen citrates of lithium, sodium, and potassium. J Chem Thermodyn 26:49ā51
Apelblat A, Manzurola E (2003) Cryoscopic studies of aqueous solutions of tartaric acid, sodium hydrogen tartrate, potassium tartrate, sodium dihydrogen citrate, potassium dihydrogen citrate, disodium hydrogen citrate, sodium citrate and potassium citrate. J Chem Thermodyn 35:1225ā1236
Fricke R, SchĆ¼tzdeller H (1924) Investigations of hydrates in aqueous solution-citrate, d-tartrate, acetate and oxalate. Z Anorg Allg Chemie 136:295ā304
Robinson RA, Stokes RH (1965) Electrolyte Solutions. 2nd. revised. edn. Butterworths, London
Manzurola E, Apelblat A (2003) Vapour pressure of water over saturated solutions of tartaric acid, sodium hydrogen tartrate, sodium tartrate, potassium tartrate, calcium tartrate, barium tartrate, citric acid, disodium hydrogen citrate, sodium citrate, and potassium citrate at temperatures from 277 to 317Ā K. J Chem Thermodyn 35:251ā260
Saul A, Wagner W (1987) International equations for the saturation properties of ordinary water substance. J Phys Chem Ref Data 16:893ā901
Martinez dela Cuesta PJ, Rodrigez Maroto JM, Wucherpfennig AT (1986) Determinacion de datos para el diseno de evaporadores. Aplicacion de acidos organicos y sus sales. Parte I. Acido citrico, citrico sodico y citrico potasico. Ing Quim (Madr) 18:219ā223
Timmermans J (1960) The Physico-Chemical Constants of Binary Systems. Systems with Metallic Compounds. volĀ 3. Interscience Publishers, Inc., New York, pĀ 462, 606
Sadeghi R, Ziamajidi F (2007) Vapor-liquid equilibria of binary tri-potassium citrate + water and ternary polypropylene oxide 400 + tri-potassium citrate + water systems from isopiestic measurements over a range of temperatures. Fluid Phase Equilib 255:46ā54
Sadeghi R (2006) Vapor-liquid equilibrium in aqueous systems containing poly(vinylpyrrolidine) and sodium citrate at different temperatures ā experimental and modeling. Fluid Phase Equilib 249:33ā41
Sadeghi R, Goodarzi B (2008) Effect of potassium citrate salts on the vapor-liquid equilibrium properties of aqueous solutions of alanine at different temperatures. Biophys Chem 135:116ā124
Sadeghi R, Goodarzi B (2008) Measurement of water activities of alanine + tripotassium citrate + water systems at temperature between 293 and 313 K. Experiment and modeling. Fluid Phase Equilib 267:61ā69
Sadeghi R, Golabiazar R, Parsi E (2010) Vapor-liquid equilibria density, and speed of sound of aqueous solutions of sodium dihydrogen citrate and disodium hydrogen citrate. J Chem Eng Data 55:5874ā5882
Sadeghi R, Mostafa B, Parsi E, Shahebrahimi Y (2010) Toward an understanding of the salt-out effects in aqueous ionic liquid solutions: vapour-liquid equilibria, liquid-liquid equilibria, volumetric, compressibility, and conductivity behavior. J Phys Chem B 114:16528ā16541
Sadeghi R, Gholamireza A (2011) Thermodynamics of the ternary systems: (water + glycine, L-alanine and L-serine + di-ammonium hydrogen from volumetric, compressibility, and (vapour + liquid) equilibria measurements. J Chem Thermodyn 43:200ā215
Schunk A, Maurer G (2004) Activity of water in aqueous solutions of sodium citrate and in aqueous solutions of (an investigated salt and citric acid) at 298 15 K. J Chem Eng Data 49:944ā949
Salabat A, Shamshiri L, Sahrakar F (2005) Thermodynamic and transport properties of aqueous trisodium citrate system at 298 15 K. J Mol Liq 118:67ā70
Kazemi S, Zafarami-Moatter MT, Taghikhami V, Ghotbi C (2007) Measurement and correlation of vapor-liquid equilibria of the aqueous poly(ethylene glycol) + sodium citrate and poly(ethylene glycol) + potassium citrate systems. Fluid Phase Equilib 262:137ā148
Clarke ECW, Glew DN (1985) Evaluation of the thermodynamic functions for aqueous sodium chloride from equilibrium and calorimetric measurements below 154āĀ°C. J Phys Chem Ref Data 14:489ā610
Pitzer KS (1979) Theory: ion interaction approach. In: Pytkowicz RM (ed) Activity Coefficients in Electrolyte Solutions, volĀ 1. CRC, Inc., Boca Raton, ppĀ 157ā208
Halasey SME (1941) Partial molal volumes of potassium salts of the Hofmeister series. J Phys Chem 45:1252ā1263
Dhake KP, Padmini ARKL (1970) Ultrasonic parameters and hydration numbers in aqueous solutions of electrolytes. Indian J Pure Appl Phys 8:311ā315
Apelblat A, Manzurola E (1990) Apparent volumes of organic acids and salts in water at 298 15Ā K. Fluid Phase Equilib 60:157ā171
Sadeghi R, Ziamajidi (2007) Apparent molar volume and isentropic compressibility of trisodium citrate in water and in aqueous solutions polyvinylpyrrolidone at Tā=ā(283.15 to 308.15)Ā K. J Chem Eng Data 52:1037ā1044
Sadeghi R, Ziamajidi F (2007) Thermodynamic properties of tripotassium citrate in water and in aqueous solutions of polypropylene oxide 400 over a range of temperatures. J Chem Eng Data 52:1753ā1759
Sadeghi R, Goodarzi B (2008) Apparent molar volumes and isentropic compressibilities of transfer of L-alanine from water to aqueous potassium di-hydrogen citrate and tri-citrate at Tā=ā283 15 to 308 15)Ā K. J Mol Liq 141:62ā68
Sadeghi R, Goodarzi B (2008) Volumetric properties of potassium dihydrogen citrate and tripotassium citrate in water and aqueous solutions of alanine at T =ā(283.15 to 308.15)Ā K. J Chem Eng Data 53:26ā35
Sadeghi R, Goodarzi B, Karami K (2009) Effect of potassium citrate salts on the transport behavior of L-alanine in aqueous solutions at Tā=ā(293.15 to 308.15)Ā K. J Chem Eng Data 54:791ā794
Regupathi I, Govindarajan R, Amaresh SP, Murugesan T (2009) Densities and viscosities of polyethylene glycol 6000+ triammonium citrate + water systems. J Chem Eng Data 54:3291ā3295
Sadeghi R, Golabiazar R, Shekaari H (2010) Effect of simple electrolytes on the thermodynamic properties of room temperature ionic liquids in aqueous solutions. Fluid Phase Equilib 298:231ā239
Zafarami-Moattar MT, Izadi F (2011) Effect of KCl on the volumetric and transport properties of aqueous tri-potassium citrate solutions at different temperatures. J Chem Thermodyn 43:552ā561
Zafarami-Moatter MT, Izadi F (2011) Effect of temperature and concentration of KBr or KNO3 on the volumetric and transport properties of aqueous solutions of tripotassium citrate. J Chem Eng Data 56:2818ā2829
Lu JG, Hua AC, Xu ZW, Fan F, Cheng L, Lin F (2012) Measurement and prediction of densities, viscosities, and surface tensions for aqueous solutions of potassium citrate. Fluid Phase Equil 327:9ā13
Kalaivani S, Srikanth CK, Regupathi I (2012) Densities and viscosities of binary and ternary mixtures and aqueous two-phase system of ply(ethylene glycol) 2000 + diammonium hydrogen citrate + water at different temperatures. J Chem Eng Data 57:2528ā2534
Kumar H, Kaur K, Kaur SP, Singla M (2013) Studies of volumetric and acoustic properties of trisodium citrate and tripotassium citrate in aqueous solutions of N-acetyl glycine at different temperatures. J Chem Thermodyn 59:173ā181
Govindarajan R, Diviya K, Perumalsamy M (2013) Phase behavior and density of binary and ternary solutions of PEG 4000 + triammonium citrate + water aqueous two phase systems at different temperatures. J Chem Eng Data 58:315ā321
Patterson BA, Wooley EM (2001) Thermodynamics of proton dissociation from aqueous citric acid: apparent molar volumes and apparent heat capacities of citric acid and its sodium salts at the pressure of 0.35 MPa and at temperatures from 278.15 to 393.15Ā K. J Chem Thermodyn 33:1735ā1764
Sadeghi R, Ziamajidi F (2007) Volumetric and isentropic compressibility behaviour of aqueous solutions of (polyvinylpyrrolidone + sodium citrate) at Tā=ā(283.15 to 308.15)Ā K. J Chem Thermodyn 39:1118ā1124
Kumar H, Singla M, Jindal R (2014) Volumetric properties of glycine, L-alanine and L-valine in aqueous solutions of triammonium citrate at different temperatures. Monatsh Chem 145:565ā575
Sadeghi R, Ziamajidi F (2007) Effect of aqueous solution of tri-potassium citrate on the volumetric behaviour of poly(propylene glycol) 400 at T ā (288.15 to 313.15)Ā K. J Chem Eng Data 52:1268ā1272
Kumar H, Singla M, Jindal R (2013) Interactions of glycine, L-alanine and L-valine with aqueous solutions of trisodium citrate at different temperatures: A volumetric and acoustic approach. J Chem Thermodyn 67:170ā180
Millero FJ (1972) The partial molal volumes of electrolytes in aqueous solutions. In: Horne RA (ed) Water and Aqueous Solutions. Structure, Thermodynamics and Transport Processes. Wiley, New York, ppĀ 519ā595
Hepler LG (1969) Thermal expansion and structure in water and aqueous solutions. Can J Chem 47:4613ā4616
Apelblat A, Manzurola(1999) Volumetric properties of water, and solutions of sodium chloride and potassium chloride at temperatures Tā=ā277 15Ā K to Tā=ā343 15Ā K at molalities of (0 1, 0 5, and 1 0) molĀ kgā1. J Chem Thermodyn 31:869ā893
Rao MR (1940) Relation between velocity of sound in liquids and molecule volume. Indian J Phys 14:109ā116
Rao MR (1941) The adiabatic compressibility of liquids. J Chem Phys 14:699
Passynski A (1940) Compressibility and salvation of solution of electrolytes. Acta Physicochim USSR 8:358ā418
Barradas RG, Donaldson GJ, Shoesmith DW (1973) Double layer studies of aqueous sodium citrate solution at the mercury electrode. J Electroanal Chem 41:243ā258
McDonald DM, Hsu HW (1972) Transport phenomena in zonal centrifuge rotors. VI. Concentration-dependent diffusivities of potassium citrate and potassium tartrate in aqueous solutions. Separ Sci 7:491ā503
Jenkins HDB, Marcus Y (1995) Viscosity B-coefficients of ions in solution. Chem Rev 95:2695ā2724
Washburn EW (ed) (1926) International Critical Tables of Numerical Data Physics, Chemistry and Technology, volĀ V. McGraw-Hill, New York, pĀ 150
Sadeghi R, Golabiazar R, Shekaari H (2010) The salting effect and phase separation in aqueous solutions of tri-sodium citrate and 1-butylā3-methylimidazolium bromide. J Chem Thermodyn 42:441ā453
Livingston J, Morgan R, McKirahan WW (1913) The weight of falling drop and the laws of Tate. XIV. The drop weights of aqueous solutions of the salts of organic acids. J Am Chem Soc 35:1759ā1761
Bhat JI, Manjunatha MN (1998) Transport behaviour of sodium, potassium and ammonium citrate in water and water ā DMF as a function of temperature. Proc Natl Acad Sci India 68:29ā40
Greve A, Kula MR (1991) Phase diagrams of new aqueous phase systems composed of aliphatic alcohol, salts and water. Fluid Phase Equil 62:53ā63
Zafarami-Moattar MT, Banisaeid S, Shamsi Beirami MA (2005) Phase diagrams of some aliphatic alcohols + potassium or sodium + water at 25āĀ°C. J Chem Eng Data 50:1409ā1413
Katayama H, Sugahara K (2008) Liquid-liquid phase equilibria in the system ethanol(1)ā+āwater(2)ā+ātripotassium citrate(3). J Chem Eng Data 53:1940ā1943
Wang Y, Hu S, Han J, Yan Y (2010) Measurement and correlation of phase diagram data for several hydrophilic alcohol + citrate two phase systems at 298.15Ā K. J Chem Eng Data 55:4574ā4579
Wang Y, Mao Y, Han J, Liu Y, Yan Y (2010) Liquid-liquid equilibrium of potassium phosphate/potassium citrate/sodium citrate + ethanol aqueous two-phase systems at (298.15 and 313.15)Ā K and correlation. J Chem Eng Data 55:5621ā5626
Nemati-Kande E, Shekaari H (2012) Liquid-liquid equilibria in some aliphatic alcohols + disodium hydrogen citrate + water ternary systems. J Solut Chem 41:1649ā1663
Nemati-Kande E, Shekaari H, Zofarami-Moattar MT (2012) Binodal curves and tie-lines inaliphatic alcohols + diammonium hydrogen citrate + water systems: measurement and modeling. J Chem Eng Data 57:1678ā1688
Zafarami-Moattar MT, Jafari P (2013) The effect of temperature on the liquid-liquid equilibria of some aliphatic alcohols + di-sodium hydrogen citrate + water systems: experimental and correlation. Fluid Phase Equil 353:50ā60
Zafarami-Moattar MT, Hamidi AA (2003) Liquid-liquid equilibria of aqueous two-phase poly(propylene glycol) ā potassium citrate system. J Chem Eng Data 48:262ā265
Zafarani-Moattar MT, Sadeghi R, Hamidi AA (2004) Liquid-liquid equilibria of an aqueous two-phase system containing polyethylene glycol and sodium citrate: experiment and correlation. Fluid Phase Equil 219:149ā155
Murugesan T, Perumalsamy M (2005) Liquid-liquid equilibrium of poly(ethylene glycol) 2000 + sodium citrate + water at (25, 30, 35, 40, and 45)āĀ°C. J Chem Eng Data 50:1392ā1395
Tubio G, Pellegrini L, Nerli BB, Pico GA (2006) Liquid-liquid equilibria of aqueous two-phase systems containing poly(ethylene glycols) of different molecular weight and sodium citrate. J Chem Eng Data 51:209ā212
Perumalsamy M, Murugesan T (2006) Prediction of liquid-liquid equilibria for PEG 2000-sodium citrate based aqueous two-phase systems. Fluid Phase Equil 244:52ā61
Perumalsamy M, Bathmalakshmi A, Murugesan T (2007) Experiment and correlation of liquid-liquid equilibria of an aqueous salt + polymer system containing PEG 6000 + sodium citrate. J Chem Eng Data 52:1186ā1188
Jayapal M, Regupathi I, Murugesan T (2007) Liquid-liquid equilibrium of poly(ethylene glycol) 2000 + potassium citrate + water at (25, 35, and 45)āĀ°C. J Chem Eng Data 52:56ā59
Zafarami-Moattar MT, Emamian S, Hamzehzadeh S (2008) Effect of temperature on the phase equilibrium of the aqueous two-phase poly(propylene glycol) + tripotassium citrate system. J Chem Eng Data 53:456ā461
Oliveira RM, Reis Coimbra JS, Minim LA, Silva LHM, Fontes MPF (2008) Liquid-liquid equilibria of biphasic systems composed of sodium citrate + polyethylene (glycol) 1500 or 4000 at different temperatures. J Chem Eng Data 53:895ā899
Alves JGLF, Brenneisen J, Ninni L, Meirelles AJA, Maurer G (2008) Aqueous two-phase systems of poly(ethylene glycol) and sodium citrate: experimental results and modeling. J Chem Eng Data 53:1587ā1594
Regupathi I, Murugesan S, Govindarajan R, Amaresh SP, Thanapalan M (2009) Liquid-liquid equilibrium of poly(ethylene glycol) 6000 + triammonium citrate + water at different temperatures. J Chem Eng Data 54:1094ā1097
Perumalsamy M, Murugesan T (2009) Phase compositions, molar mass, and temperature effect on densities, viscosities, and liquid-liquid equilibrium of polyethylene glycol and salt ā based aqueous two-phase systems. J Chem Eng Data 54:1359ā1366
Regupathi I, Brikanth CK, Sindhu N (2011) Liquid-liquid equilibrium of poly(ethylene glycol) 2000 + diammonium hydrogen citrate + water system at different temperatures. J Chem Eng Data 56:3643ā3650
Duraiayya R, Arumugam S, Settu S (2012) Equilibrium phase behavior of poly (ethylene glycol) 4000 and biodegradable salts at various temperatures. J Chem Eng Data 57:1112ā1117
Souza Jr EC, Diniz RS, Reis CJS, Oliveira LM, Santos GR, Cruz RAM, Salva LHM (2013) Measurements and modeling of polyethylene glycol 400, sodium phosphate, or sodium citrate aqueous two-phase systems at (298.2, 308.2, and 318.2)Ā K. J Chem Eng Data 58:2008ā2017
Govindarajan R, Perumalsamy M (2013) Phase equilibrium of PEG 2000 + triammonium citrate + water system relating PEG molecular weight, cation, anion with effective excluded volume, Gibbs free energy of hydration, size of cation, and type of anion at (298.15, 308.15, and 318.15)Ā K. J Chem Eng Data 58:2952ā2958
Nagaraja VH, Iyyaswami R (2013) Phase demixing studies in aqueous two-phase system with polyethylene glycol (PEG) and sodium citrate. Chem Eng Comm 200:1293ā1308
Zafarani-Moattar MT, Jafari P (2013) Phase diagrams for liquid-liquid and liquid-solid equilibrium of the ternary polyethylene glycol + di-sodium hydrogen citrate + water system. Fluid Phase Equil 337:224ā233
Perumalsamy M, Murugesan T (2014) Liquid-liquid equilibrium of aqueous two-phase system (PEG 2000āsodium citrateāwater) using potential difference as a key tool. Phys Chem Liq 52:26ā36
Pazuki G, Vossoughi M, Taghikhani V (2010) Partitioning of penicillin G acylase in aqueous two-phase systems of poly (ethylene glycol) 20,000 or 35,000 and potassium dihydrogen phosphate or sodium citrate. J Chem Eng Data 55:243ā248
Zafarani-Moattar MT, Hamzehzadeh S (2009) Phase diagrams for the aqueous two-phase ternary system containing the ionic liquid 1-butyl-3-methylimidazolium bromide and tri-potassium citrate at āT = ā(278.15, 298.15, and 318.15)Ā K. Chem J Eng Data 54:833ā841
Zafarani-Moattar MT, Hamzehzadeh S (2010) Salting-out effect, preferential exclusion, and phase separation in aqueous solutions of chaotropic water-miscible ionic liquids and kosmotropic salts: effects of temperature, anions, and cations. J Chem Eng Data 55:1598ā1610
Han J, Pan R, Xie X, Wang Y, Yan Y, Yin G, Guan G (2010) Liquid-liquid equilibria of ionic liquid 1-butyl-3-methylimidazolium Tetrafluoroborate + sodium and ammonium citrate aqueous two-phase systems at (298 15, 308 15, and 323 15)Ā K. J Chem Eng Data 55:3749ā3754
Li YL, Zhang MS, Su H, Liu Q, Guan WS (2013) Liquid-liquid equilibria of aqueous two-phase systems of the ionic liquid brominated N-ethyl pyridine and sodium dihydrogen phosphate, sodium sulfate, ammonium citrate, and potassium tartrate at different temperatures: experimental determination and correlation. Fluid Phase Equil 341:70ā78
Porto TS, PessĆ“a-Filho PA, Neto BB, Filho JLL, Converti A, Porto ALF, Pessoa Jr A (2007) Removal of proteases from Clostridium perfringens fermented broth by aqueous two-phase systems (PEG/citrate). J Ind Microbiol Biotechnol 34:547ā552
Sadeghi R, Rafiei HR, Motamedi M (2006) Phase equilibrium in aqueous two-phase systems containing poly(vinylpyrrolidone) and sodium citrate at different temperatures ā experimental and modeling. Thermochim Acta 451:163ā167
Sadeghi R (2006) Aqueous two-phase systems of poly(vinylpyrrolidone) and potassium citrate at different temperatures ā experimental results and modeling of liquid-liquid equilibrium data. Fluid Phase Equil 246:89ā95
da Rocha Patricio P, Mageste AB, de Lemos LR, de Carvalho RMM, da Silva LHM, da Silva MCH (2011) Phase diagram and thermodynamic modeling of PEO + organic salts + H2O and PPO + organic salts + H2O aqueous two-phase systems. Fluid Phase Equil 305:1ā8
Virtuoso LS, Vello KASF, de Oliveira AA, Junqueira CM, Mesquita AF, Lemes NHT, de Carvalho RMM, da Silva MCH, da Silva LHM (2012) Measurement and modeling of phase equilibrium in aqueous two-phase systems: L35 + sodium citrate + water, L35 + sodium tartrate + water, and L35 + sodium hydrogen sulfite + water at different temperatures. J Chem Eng Data 57:462ā468
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Apelblat, A. (2014). Physicochemical Properties of Inorganic Citrates. In: Citric Acid. Springer, Cham. https://doi.org/10.1007/978-3-319-11233-6_5
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