Abstract
The manufacture of pulp for paper and board employs mechanical and chemical methods. Chemical pulping is used on most papers produced commercially in the world today. The Kraft process is the most dominant chemical pulping process worldwide. The problem of kraft mill odour originating from the sulphide in the white liquor in the initial pulping has long been an environmental and public relations issue for the pulp and paper industry. The kraft mill odour is caused predominantly by malodourous reduced sulphur compounds, or total reduced sulphur compounds namely, methyl mercaptan, dimethylsulphide, dimethyldisulphide and hydrogen sulphide. Reduction of odourous gas emissions in kraft mills will significantly improve the environmental competitiveness of the pulp and paper industry, and will also improve public relations with their respective surrounding communities. When it is more economically feasible, odour reduction, instead of odour elimination, can improve significantly the air quality and the environment of a kraft mill, since it will reduce the radius of the area being impacted by the odour emission. Typical characteristics of the gaseous emissions from kraft pulp mill, neutral sulphite semi-chemical (NSSC) pulping, sulphites and mechanical pulping are presented in this chapter.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Adams TN, Frederik WJ, Grace TM (1997) Kraft recovery boilers. TAPPI, Atlanta (USA 99)
Anderson K (1970) Formation of organic sulphur compounds during Kraft pulping. II. Influence of some cooking variables on the formation of organic sulphur compounds during kraft pulping of Pine. Svensk Paperstid 73(1):1
Andersson B, Lovblod R, Grennbelt P (1973) Diffuse emissions of odourous sulphur compounds from kraft pulp mills, 1 VLB145. Swedish Water and Air Pollution Research Laboratory, Gotenborg
Bajpai P (2008) Chemical recovery in pulp and paper making. PIRA International, U.K. 166Â p
Biermann CJ (1996) Handbook of pulping and papermaking, 2nd edn. Academic, New York
Bordado JCM, Gomes JFP (1997) Pollutant atmospheric emissions from Portuguese Kraft pulp mills. Sci Total Environ 208(1–2):139–143
Bordado JCM, Gomes JFP (2003) Emission and odour control in kraft pulp mills. J Clean Prod 11:797–801
Dallons V (1979) Multimedia assessment of pollution potentials of non-sulphur chemical pulping technology. Environmental Protection Agency, Office of Research and Development, Industrial Environmental Research Laboratory, Cincinnati (EPA-600/2–79-026, January 1979)
Das TK, Jain AK (2004) Pollution prevention advances in pulp and paper processing. Environ Prog 20(2):87–92
EPA (2001a) Pulp and paper combustion sources National Emission Standards for Hazardous. U.S. Environmental Protection Agency, Office of Air and Radiation, Office of Air Quality Planning and Standards, Washington, DC
EPA (2001b) Pulping and bleaching system NESHAP for the pulp and paper Industry: a plain English description. U.S. Environmental Protection Agency. EPA-456/R-01–002. September 2001.http://www.epa.gov/ttn/atw/pulp/guidance.pdf. Accessed 12 Nov 2012
European Commission (2001) Integrated Pollution Prevention and Control (IPPC). Reference document on best available techniques in the pulp and paper industry. Institute for Prospective Technological Studies, Seville
Frederick WJ, Danko JP, Ayers RJ (1996) Control of TRS emissions from dissolving-tank vent stacks. TAPPI J 79(6):144
Gullichsen J (2000) Fibre line operations. In: Gullichsen J, Fogelholm C-J (eds) Chemical pulping—papermaking science and technology. Fapet Oy, Helsinki, p. A19 (Book 6 A)
Jarvensivu M, Lammi R, Kivivasara J (1997) Proceedings of the 1997 TAPPI Int. Environmental Conference, 645
Kringstad KP, McKean WT, Libert J, Kleppe PJ, Laishong C (1972) Odour reduction by in-digester oxidation of kraft black liquor with oxygen. TAPPI J 55(10):1528
Nordic Council of Ministers (1993) Study on Nordic pulp and paper industry and the environment. Nordic Council of Ministers, 1993
Pinkerton JE (1993) Emissions of SO2 and NOx from pulp and paper mills. J Air Waste Manag Assoc 43:1404–1407
Pinkerton J (1998) Trends in U.S. pulp and paper mill S and N emissions, 1980–1995. TAPPI J 181:114–122
Pinkerton J (2000a) Sulphur dioxide and nitrogen oxides emissions from pulp and paper mills in 2000. Special Report No. 02–06. National Council for Air and Stream Improvement, Inc., Research Triangle Park, NC, 2002
Pinkerton JE (2000b) Pulp and paper air pollution problems, Industrial environmental control. Pulp and paper industry. In: Springer AM (ed) 3rd edn. Atlanta, TAPPI, pp 501–535, 711 pp (Chap. 26)
Rydholm SA (1965) Pulping process. Wiley, New York, p 452
Smook GA (1992) Handbook for pulp & paper technologists, 2nd edn. Angus Wilde Publications, Vancouver
Someshwar AV (1989) Impact of burning oil as auxiliary fuel in kraft recovery furnaces upon SO2 emissions. NCASI Technical Bulletin No. 578, December 1989
Someshwar AV, Pinkerton JE (1992) Wood processing industry. In: Buonicore AD, Davis WT (eds) Air pollution engineering manual. Van Nostrand Reinhold, New York
Springer AM, Courtney FE (1993) Air Pollution: a problem without boundaries. In: Springer AM (ed) Industrial environmental control pulp and paper industry, 2nd edn. TAPPI, Atlanta, pp 525–533
Tarpey T (1995) Odour reduction at [Daishowa- Marubeni International Ltd.’s] Peace River Pulp [Division Peace River Alberta]. International Environmental Conference Proceedings, 589
Tormund D, Teder A (1987) Elimination of malodorous organic sulphur compounds from the kraft pulping process with polythionate and sulfite. Nordic Pulp Paper Res J 2(3):97
US EPA (1973) Atmospheric emissions from the pulp and paper manufacturing industry. EPA-450/1-73-002. USEPA, Research Triangle Park
US EPA (1976) Environmental pollution control pulp and paper industry, Part 1, Air, U.S. EPA Technology Transfer Series, EPA-625/7-76-001, October 1976
US EPA (1986) Compilation of air pollutant emission factors, vol I. USEPA, Research Triangle Park
US EPA (1993a) Pulp, paper and paperboard industry background information for proposed air emission standards, manufacturing processes at kraft, sulfite, soda, and semi-chemical mills. EPA-453 R-93 – 050a. Office of Air Quality Planning and Standards, Research Triangle Park, NC27711
US EPA (1993b) Development document for proposed effluent limitations guidelines and standards for the pulp, paper and paperboard point source category. EPA-821-R-93-019. Office of Water, Mail Code 4303, Washington, DC
US EPA (2001) Air pollutants: a plain English description. EPA-456/R-01-003. September 2001. http://www.epa.gov/ttn/atw/pulp/Chaps.1-6pdf.zip. Accessed 18 Nov 2012
Wag KJ, Frederick WJ, Sricharoenchaikul V, Grace TM, Kymalainen MW (1995) Sulfate reduction and carbon removal during kraft char burning. International Chemical Recovery Conference: Preprints B, B35–50
Zhang Z, Luan G, Du P, Guo H (1999) More suitable process for dealing with the malodourous gases from sulfate cooking. Chin Pulp Paper Ind (4):16–18
Zhao H, Zhu J (2004) Operation experience of Kvaerner NCG System. Paper Paper Mak (1):21–23
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2014 The Author(s)
About this chapter
Cite this chapter
Bajpai, P. (2014). Emissions from Pulping. In: Biological Odour Treatment. SpringerBriefs in Environmental Science. Springer, Cham. https://doi.org/10.1007/978-3-319-07539-6_2
Download citation
DOI: https://doi.org/10.1007/978-3-319-07539-6_2
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-07538-9
Online ISBN: 978-3-319-07539-6
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)