Abstract
The measurement and characterization of reactive sputtered aluminum nitride (AlN) thin films is presented and evaluated as a potential solution for high temperature sensing applications based on its pyroelectric response (PR). This paper provides the PR obtained for our sputtered thin films along with an in-depth film evaluation using X-ray Diffraction, X-ray Photon Spectroscopy, Scanning Electron Microscopy, and Fourier Transform Infrared Spectroscopy to assess the films crystalline orientation and material composition while evaluating surface coatings for maximum infrared absorption. We observed an ~5× PR increase in the polycrystalline AlN films when compared to epitaxial monocrystalline AlN films. A design of experiments was used to help identify the key parameters which play vital roles in obtaining high PR films. Lastly, several MEMS based array concepts are presented for future testing and characterization.
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References
Wu Y-R, Singh J (2005) Polar heterostructures for multifunctional devices: theoretical studies. IEEE Trans Electron Devices 52(2):284–293
Bykhovski D, Kaminski V, Shur M, Chen Q, Khan M (1996) Pyroelectricity in gallium nitride thin films. Appl Phys Lett 69:3254
Shur MS, Bykhovski D, Gaska R (1999) Piezoelectric effects in AlGaN/GaN-based heterostructure field effect transistors. In: Moustakas TD, Mohney SE, Pearton SJ (eds) Proceedings of the third symposium on III-V nitride materials and processes. The Electrochemical Society, Pennington, pp 154–168
Aggarwal MD, Penn BG, Currie Jr JR et al (2010) Pyroelectric materials for uncooled infrared detectors: processing, properties, and applications. NASA/TM 216373 Report
Randhawa H, Johnson PC, Cunningham R (1988) Deposition and characterization of ternary nitrides. J Vac Sci Technol A 6(3):2136–2139
Fuflyigin V, Salley E, Osinsky A, Norris P (2000) Pyroelectric properties of AlN. Appl Phys Lett 77(19):3075–3077
Crisman E, Vasilyev V, Drehman A, Webster R (2011) Observation of large, anomalous pyroelectric response in AlN thin films. In: MRS symposium proceedings, vol 1288. doi:10.1557/opl.2011.627
Shaldin YV, Matyjasik S (2011) Pyroelectric properties of AlN wide-gap semiconductor in the temperature range of 4.2-300K. Semiconductors 45(9):1117–1123
Chynoweth A (1956) Dynamic method for measuring the pyrolectric effect with special reference to barium titanate. J Appl Phys 27(1):78–84
Daglish M (1998) A dynamic method for determining the pyroelectric response of thin films. Integr Ferroelectr 22:473–488
Crisman E, Drehman A, Miller R et al (2014) Enhanced AlN nanostructures for pyroelectric sensors. Phys Status Solidi C 11(3–4):517–520, Special Issue: 10th International Conference on Nitride Semiconductors (ICNS-10)
Engelmark F, Westlinder J, Iriarte GF, Katardjiev IV, Olsson J (2003) Electrical characterization of AlN MIS and MIM structures. IEEE Trans Electron Devices 50(5):1214–1219
Larson III JD, Mishin S, Bader S (2010) Characterization of reversed c-axis AlN thin films. In: IEEE international ultrasonics symposium proceedings, San Diego, CA, pp 1054–1059
Gaspar J, Schmidt ME, Held J, Paul O (2009) Wafer-scale microtensile testing of thin films. J Microelectromech Syst 18(5):1062–1076
Qui-lin T, Wen-dong Z, Chen-yang X, Ji-jun X, Jun L, Jun-hong L, Ting L (2009) Design, fabrication and characterization of pyroelectric thin film and its application for infrared gas sensors. Microelect J 40:58–62
Sengupta S, Sengupta LC, Synowczynski J, Rees DA (1998) Novel pyroelectric sensor materials. IEEE Trans Ultrason Ferroelectr Freq Control 45(6):1444–1452
Jackson N, O’Keeffe R, O’Leary R, O’Neill M, Waldron F, Mathewson A (2012) A diaphragm based piezoelectric AlN film quality test structure. In: 25th anniversary IEEE international conference on microelectronic test structures, San Diego, CA, pp 50–54
Acknowledgments
The authors would like to acknowledge the AFRL Sensors Directorate for providing the necessary funding to complete this work. The authors wish to thank Dr. Bruce Claflin for XPS testing, Dr. Beth Moore and Mr. John Hoelscher for Raman testing and characterization, and Mr. Doug McFarland for preparing the test structures.
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Starman, L.A., Vasilyev, V.S., Holbrook, C.M., Goldsmith, J.H. (2015). Pyroelectric AlN Thin Films Used as a MEMS IR Sensing Material. In: Prorok, B., Starman, L., Hay, J., Shaw, III, G. (eds) MEMS and Nanotechnology, Volume 8. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-319-07004-9_7
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DOI: https://doi.org/10.1007/978-3-319-07004-9_7
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