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Heat Capacity of 1D Chains of Atom/Molecule Adsorbates in the Grooves of c-SWNT Bundles

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Nanocomposites, Nanophotonics, Nanobiotechnology, and Applications

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 156))

Abstract

The heat capacity of quasi-one-dimensional (1D) chains of Xe atom/N2molecule adsorbates (C Xe, C N2) in the outer grooves of closed single-walled carbon nanotube (c-SWNT) bundles have been first investigated at a temperature range of 2–60 K. Below 3–4 K, the temperature dependencies of C Xe(T) and C N2(T) are linear. The experimental data C Xe have been compared with theory (Šiber). The experimental and theoretical heat capacity curves are close to below 8 K. Above 8 K, the experimental curve C Xe(T) exceeds the theoretical one and the excess increases monotonously with temperature. We assume that the excess is caused mainly by the thermal expansion of 1D chains and the occurrence of vacancies in the 1D chains due to spatial redistribution of the Xe atoms from grooves to the positions near the grooves above 30 K. Below 8 K, the behavior of C N2(T) is qualitatively similar to the theoretical phonon heat capacity of 1D chains of Kr adatoms. Above 8 K, the dependence C N2(T) becomes steeper in comparison with the case of Kr adatoms. This behavior of the heat capacity C N2(T) is due to both the contribution of the rotational degrees of freedom of the N2 molecules and thermal expansion of 1D chains. The Debye temperatures have been estimated for 1D adsorbate chains.

PACS: 65.40.Ba Heat capacity

65.80.-g Thermal properties of small particles, nanocrystals, nanotubes, and other related systems

68.65.-k Low-dimensional, mesoscopic, nanoscale and other related systems: structure and nonelectronic properties;81.07.De Nanotubes

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Acknowledgments

The authors are grateful to V. Manzhelii, Yu. Freiman, M. Strzhemechny, S. Feodosyev, and K. Chishko for helpful discussions.

Electronic address: sumarokov@ilt.kharkov.ua

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Authors and Affiliations

  1. B.Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine, 47 Lenin Ave., 61103, Kharkov, Ukraine

    V. V. Sumarokov, M. I. Bagatskii & M. S. Barabashko

Authors
  1. V. V. Sumarokov
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  2. M. I. Bagatskii
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  3. M. S. Barabashko
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Correspondence to V. V. Sumarokov .

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Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Physics, Kiev, Ukraine

    Olena Fesenko

  2. National Academy of Sciences of Ukraine, Institute of Physics, Kiev, Ukraine

    Leonid Yatsenko

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Sumarokov, V., Bagatskii, M., Barabashko, M. (2015). Heat Capacity of 1D Chains of Atom/Molecule Adsorbates in the Grooves of c-SWNT Bundles. In: Fesenko, O., Yatsenko, L. (eds) Nanocomposites, Nanophotonics, Nanobiotechnology, and Applications. Springer Proceedings in Physics, vol 156. Springer, Cham. https://doi.org/10.1007/978-3-319-06611-0_15

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