Abstract
Arsenic is a naturally occurring toxic metalloid and its contamination in the hydrological system has significantly received worldwide attention in the last three decades. It is widely distributed in all the components of the environment and varies by more than four orders of magnitude ranging from <0.5 μg/l to 5000 μg/l in the natural water systems. Natural systems, with climate as the controlling mechanism, play an important role in strong geochemical fractionation with quantitative elemental transportation (Raju, 2012a). Natural systems of tropical environment are, therefore, a major concern for environmental scientists (Dissanayake and Chandrajith, 1999; Smedley and Kinniburgh, 2002). The study of fluvial time series provides the key for the understanding of elemental mobilization that controls the dissolved elemental concentration in the various components of the hydrological system (Raju 2012a). Studies have shown that dissolved As concentration in river water varies at a great extent and is mainly dependent on geology, hydrology, climate as well as various anthropogenic activities (Raju 2012b; Masson et al., 2007; Elbaz-Poulichet et al., 2006; Pettine et al., 1997; McLaren and Kim, 1995). In northern India, the Ganga Alluvial Plain (GAP) is one of the most densely populated regions of the world. It is drained by several alluvial rivers and supports nearly 500 million people. The objective of this paper is to report the seasonal variation and flux of dissolved As in the Gomati river and to understand the As mobilization for its eco-toxicological potentials in the GAP.
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References
APHA (2002). Standard methods for the examination of water and wastewater. 20th ed. American Public Health Association, Washington, DC.
Banfield, J.F., Barker, W.W., Welch, S.A. and Taunton, A. (1999). Biological impact on mineral dissolution: Application of the lichen model to understanding mineral weathering in the rhizosphere. Proceedings of National Academy of Science USA, 96: 3404-3411.
Breit, G.N. (2000). Arsenic cycling in eastern Bangladesh: The role of phyllosilicates. Proceedings of the Annual Meeting of the Geological Society of America, A-192.
Chakraborty, S., Bardelli, F., Mullet, M., Greneche, J.M., Varma, S., Ehrhardt, J.J., Banerjee, D. and Charlet, L. (2011). Spectroscopic studies of arsenic retention onto biotite. Chemical Geology, 281: 83-92. Doi: 10.1016/j.chemgeo.2010.11.030.
Dasgupta, S.P. (1984). The Ganga Basin, Part II. Central Board for Prevention and Control of Water Pollution, New Delhi.
Dissanayake, C.B. and Chandrajith, R. (1999). Medical geochemistry of tropical environments. Earth Science Review, 47: 219-258. Doi:10.1016/S0012-8252(99)00033-1.
Dong, H., Peacor, D.R. and Murphy, S.F. (1998). TEM study of progressive alteration of igneous biotite to kaolinite throughout a weathered soil. Geochimica et Cosmochimica Acta, 62: 1881-1887. doi:10.1016/S0016-7037(98)00096-9.
Ehrlich, H.L. and Newman, D.K. (2009). Geomicrobiology. CRC Press, Boca Raton.
Elbaz-Poulichet, F., Seidel, J-L., Casiot, C. and Tusseau-Vuillemin, M-H. (2006). Short-term variability of dissolved trace element concentrations in the Marne and Seine Rivers near Paris. Science of Total Environment, 367: 278-287. doi.org/10.1016/j.scitotenv.2005.11.009.
IAEA (1981). Statistical Treatment of Environmental Isotope Data in Precipitation. International Atomic Energy Agency, Vienna, Austria. Technical Report Series 206. Accessible at http://naweb.iaea.org. October 2012.
Islam, S.M.N., Rahman, S.H., Chowdhury, D.A., Rahman, M.M. and Tareq, S.M. (2012). Seasonal variations of arsenic in the Ganges and Brahmaputra River, Bangladesh. Journal of Scientific Research, 4(1): 65-75. doi:10.3329/jsr.v4i1.7820.
Masson, M., Schäfer, J., Blanc, G. and Pierre, A. (2007). Seasonal variations and annual fluxes of arsenic in the Garonne, Dordogne and Isle Rivers, France. Science of Total Environment, 373: 196-207. doi:10.1016/j.scitotenv.2006.10.039.
McLaren, S.J. and Kim, N.D. (1995). Evidence for a seasonal fluctuation of arsenic in New Zealand’s longest river and the effect of treatment on concentrations in drinking water. Environmental Pollution, 90: 67-73. doi.org/10.1016/0269-7491(94)00092-R.
Oremland, R.S. and Stolz, J.F. (2003). The Ecology of Arsenic. Science, 300: 939-944. doi:10.1126/science.1081903.
Pal, D.K., Bhattacharyya, T., Sinha, R., Srivastava, P., Dasgupta, A.S., Chandran, P., Ray, S.K. and Nimje, A. (2011). Clay minerals record from late quaternary drill cores of the Ganga Plains and their implications for provenance and climate change in the Himalayan foreland. Palaeogeography Palaeoclimatology Palaeoecology, 356–357: 27-37. doi:10.1016/j.palaeo.2011.05.009.
Pettine, M., Mastroianni, D., Camusso, M., Guzzi, L. and Martinotti, W. (1997). Distribution of As, Cr and V species in the Po–Adriatic mixing area (Italy). Marine Chemistry, 58: 335-349. doi.org/10.1016/S0304-4203(97)00060-1.
Raju, N.J. (2012a). Arsenic exposure through groundwater in the middle Ganga plain in the Varanasi environs, India: A future threat. Journal of Geological Society of India, 79: 302-314.
Raju, N.J. (2012b). Evaluation of hydrogeochemical processes in the Pleistocene aquifers of Middle Ganga plain, Uttar Pradesh, India. Environmental Earth Sciences, 65(4): 1291-1308.
Ravenscroft, P., Brammer, H. and Richards, K. (2009). Arsenic pollution: A global synthesis. Wiley-Blackwell, United Kingdom.
Robert, L.C., Hug, S.J., Voegelin, A., Dittmar, J., Kertzschmar, R., Wehrli, B., Saha, G.C., Badruzzaman, A.B.M. and Ali, M.A. (2011). Arsenic Dynamics in Porewater of an Intermittently Irrigated Paddy Field in Bangladesh. Environmental Science and Technology, 45: 971-976. doi.org/10.1021/es102882q.
Seddique, A.A., Masuda, H., Mitamura, M., Shinoda, K., Yamanaka, T., Itai, T., Maruoka, T., Uesugi, K., Ahmed, K.M. and Biswas, D.K. (2008). Arsenic release from biotite into a Holocene groundwater aquifer in Bangladesh. Applied Geochemistry, 23: 2236-2248. doi:10.1016/j.apgeochem.2008.03.007.
Singh, I.B. (1996). Geological Evolution of Ganga Plain – An overview. Journal of the Palaeontological Society of India, 41: 99-137.
Singh, M., Kumar, S., Kumar, B., Singh, S. and Singh, I.B. (2013). Investigation on the hydrodynamics of Ganga Alluvial Plain using environmental isotopes: A case study of Gomati River Basin, northern India. Hydrogeology Journal, 21: 687-700. doi: 10.1007/s10040-013-0958-3.
Singh, M., Singh, A.K., Swati, Srivastava, N., Singh, S. and Chowdhary, A.K. (2010). Arsenic mobility in fluvial environment of the Ganga Plain, northern India. Environmental Earth Science, 59: 1703-1715. doi: 10.1007/s12665-009-0152-z.
Singh, M., Srivastava, A., Shinde, A.D., Acharya, R., Reddy, A.V.R. and Singh, I.B. (2012). Study of arsenic (As) mobilization in the Ganga Alluvial Plain using neutron activation analysis. Journal of Radioanalytical and Nuclear Chemistry, 294: 241-246. doi:10.1007/s10967-1592-y.
Smedley, P.L. and Kinniburgh, D.G. (2002). A review of the source, behavior and distribution of arsenic in natural waters. Applied Geochemistry, 17: 517-568. doi:10.1016/S0883-2927(02)00018-5.
Acknowledgements
Authors would like to thank Prof. Indra Bir Singh, University of Lucknow for constant encouragement and valuable discussions. This study was financially supported by the University Grants Commission (UGC), New Delhi under Rajiv Gandhi National Fellowship scheme to DKJ (No. 16-1731(SC)/2010 (SA-III), under Junior Research Fellowship to RK (No. 23154 Dt. 11/08/2010) and minor research project to SS (No. 8-29153)2011(MRP/NRCB). The Central Water Commission is gratefully acknowledged for providing discharge data of the Gomati river. Generous assistance by Vinay Singh during the field sampling work and by Nupur Srivastava in ICP-MS analysis is greatly appreciated. We thank Dr. Ratan Kar for comments and improvements in the early draft. We thank the anonymous reviewer for comments that substantially improved the paper.
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Jigyasu, D.K., Kuvar, R., Singh, S., Singh, S., Chowdhary, A.K., Singh, M. (2015). Seasonal Variations and Flux of Arsenic in Gomati River, Ganga Alluvial Plain, Northern India. In: Raju, N., Gossel, W., Ramanathan, A., Sudhakar, M. (eds) Management of Water, Energy and Bio-resources in the Era of Climate Change: Emerging Issues and Challenges. Springer, Cham. https://doi.org/10.1007/978-3-319-05969-3_8
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