Abstract
The investigation of thermal transformations of lignin samples have been carried out using temperature programmed desorption mass spectrometry method (TPD-MS). Main stages and products of lignin pyrolysis have been identified. The first stages (Tmax = 230 °C and Tmax = 300 °C) are attributed to thermal transformations of lignin peripheral polysaccharide fragments such as hemicellulose and cellulose respectively. The second stage (Tmax = 335 °C) is associated with desorption of lignin structural elements in the molecular forms as a result of depolymerization processes of polymeric blocks of lignin. The third stage (Tmax = 370 °C) correspond to a deeper decomposition of lignin and characterized by desorption of smaller structural fragments in molecular forms (m/z = 110, pyrocatechol). Pressure–temperature curves of pyrolysis of lignin samples have been analyzed.
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Acknowledgments
This publication is based on work supported by a grant UKC2-7072-KV-12 from the U.S. Civilian Research and Development Foundation (CRDF Global) with funding from the United States Department of State and by a grant M/299-2013 from the State Agency of Ukraine for Science, Innovation and Information.
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Palianytsia, B., Kulik, T., Dudik, O., Cherniavska, T., Tonkha, O. (2014). Study of the Thermal Decomposition of Some Components of Biomass by Desorption Mass Spectrometry. In: Oral, A., Bahsi, Z., Ozer, M. (eds) International Congress on Energy Efficiency and Energy Related Materials (ENEFM2013). Springer Proceedings in Physics, vol 155. Springer, Cham. https://doi.org/10.1007/978-3-319-05521-3_3
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