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Study of the Effect of Transition Metals on Titanium Dioxide Phase Transformation

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International Congress on Energy Efficiency and Energy Related Materials (ENEFM2013)

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 155))

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Abstract

MTiX samples with different atomic metal percentage were synthesised by sol-gel method and calcined at 400 °C under air. The anatase-rutile transformation in TiO2 in the presence of transition metals (Cr, V and Mn) was investigated. The kinetics of anatase-rutile transformations were determined by XRD over the temperature range 500–800 °C. It was found that the presence of V and Mn accelerate the transformation anatase-to-rutile. However, the anatase phase stability increases as the chromium content increases.

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References

  1. G. Cruciani, M.C. Dalconi, M. Dondi, C. Meneghini, F. Matteucci, A. Barzanti, G. Lorenzi, G. Baldi, J. Nanopart. Res. 13, 711–719 (2011)

    Article  Google Scholar 

  2. Y. Hu, H.L. Tsai, C.L. Huang, Mater. Sci. Eng. A 344, 209–214 (2003)

    Article  Google Scholar 

  3. H. Zhang, J.F. Banfield, J. Phys. Chem B 104, 3481–3487 (2000)

    Article  Google Scholar 

  4. K.R. Zhu, M.S. Zhang, J.M. Hong, Z. Yin, Mater. Sci. Eng. A 403, 87–93 (2005)

    Article  Google Scholar 

  5. Y. Djaoued, S. Badilescu, P.V. Ashrit, D. Bersani, P.P. Lottici, J. Robichaud, J. Sol-Gel, Sci. Technol 24, 255–264 (2002)

    Google Scholar 

  6. H.E. Chao, Y.U. Yun, H.U. Xingfang, A. Larbot, J. Eur. Ceram. Soc. 23, 1457–1464 (2003)

    Article  Google Scholar 

  7. R.B. Zhang, J. Non-Cryst. Solids 351(24–26), 2129–2132 (2005)

    Article  ADS  Google Scholar 

  8. S. Mahanty, S. Roy, S. Sen, J. Crys, Growth 261, 77–81 (2004)

    Article  Google Scholar 

  9. H. Zhang, J.F. Banfield, Chem. Mater. 17, 3421–3425 (2005)

    Article  Google Scholar 

  10. E. Setiawati, K. Kawano, J. Alloy, Compd 451, 293–296 (2008)

    Article  Google Scholar 

  11. Y. Hu, H.L. Tsai, C.L. Huang, Mater. Sci. Eng. A 344, 209–214 (2003)

    Article  Google Scholar 

  12. S. Rajesh Kumar, S.C. Pillai, U.S. Hareesh, P. Mukundan, K.G.K. Warrier, Mater. Lett. 43, 286–290 (2000)

    Article  Google Scholar 

  13. R. Arroyo, G. Cordoba, J. Padilla, V.H. Lara, Mater. Lett. 54, 397–402 (2002)

    Article  Google Scholar 

  14. D.J. Reidy, J.D. Holmes, C. Nagle, M.A. Morris, J. Mater. Chem. 15, 3494–3500 (2005)

    Article  Google Scholar 

  15. Z. Li, B. Hou, Y. Xu, D. Wu, Y. Sun, W. Hu, F. Deng, J. Solid, State. Chem 178, 1395–1405 (2005)

    Article  ADS  Google Scholar 

  16. A.F. Popa, L. Courtheoux, E. Gautron, S. Rossignol, C. Kappenstein, Eur. J. Inorg. Chem. 2005, 543–554 (2005)

    Article  Google Scholar 

  17. S. Pavasupree, Y. Suzuki, S. Pivsa-Art, S. Yoshikawa, J. Solid, State. Chem 178, 128–134 (2005)

    Article  ADS  Google Scholar 

  18. H.E. Chao, Y.U. Yun, H.U. Xingfang, A. Larbot, J. Eur. Ceram. Soc. 23, 1457–1464 (2003)

    Article  Google Scholar 

  19. R. Arroyo, G. Cordoba, J. Padilla, V.H. Lara, Mater. Lett. 54, 397–402 (2002)

    Article  Google Scholar 

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Correspondence to A. Bellifa .

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Bellifa, A., Choukchou-Braham, A., Kappenstein, C., Pirault-Roy, L. (2014). Study of the Effect of Transition Metals on Titanium Dioxide Phase Transformation. In: Oral, A., Bahsi, Z., Ozer, M. (eds) International Congress on Energy Efficiency and Energy Related Materials (ENEFM2013). Springer Proceedings in Physics, vol 155. Springer, Cham. https://doi.org/10.1007/978-3-319-05521-3_1

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