Skip to main content

Electropolymerization of o-aminophenol on Different Electrode Materials and in Different Electrolyte Media: Formation of Poly(o-aminophenol) Film Electrodes

  • Chapter
  • First Online:
Poly(o-aminophenol) Film Electrodes

Part of the book series: Engineering Materials ((ENG.MAT.))

  • 466 Accesses

Abstract

Oxidation of o-aminophenol on different electrode materials (gold, platinum, carbon, indium-tin oxide, etc.) in aqueous medium was shown to form poly-o-aminophenol (POAP). Like aniline, o-AP can be polymerized electrochemically in acidic, neutral and alkaline solutions. However, while a conducting film is only formed in acidic media, POAP synthesized in neutral and alkaline media leads to a nonconducting film.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Barbero, C., Silber, J.J., Sereno, L.: Formation of a novel electroactive film by electropolymerization of orthoaminophenol. Study of its chemical structure and formation mechanism. Electropolymerization of analogous compounds. J. Electroanal. Chem. 263, 333 (1989)

    Article  CAS  Google Scholar 

  2. Salvagione, H.J., Arias, J., Garces, P., Morallon, E., Barbero, C., Vazquez, L.: Spectroelectrochemical study of the oxidation of aminophenols on platinum electrode in acid medium. J. Electroanal. Chem. 565, 375 (2004)

    Article  Google Scholar 

  3. Ortega, M.: Conducting potential range of poly(o-aminophenol). Thin Solid Films 371, 28 (2000)

    Article  CAS  Google Scholar 

  4. Ojani, R., Raoof, J.B., Fathi, S.: Poly(o-aminophenol) film prepared in the presence of sodium dodecyl sulphate: Aplication for nickel-ion dispersion and the elecctrocatalytic oxidation of methanol and ethylene glycol. Electrochim. Acta 54, 2190 (2009)

    Article  CAS  Google Scholar 

  5. Goncalves, D., Faria, R.C., Yonashiro, M., Bulhoes, L.O.S.: Electrochemical oxidation of o-aminophenol in aqueous medium: formation of film and soluble products. J. Electroanal. Chem. 487, 90 (2000)

    Article  CAS  Google Scholar 

  6. Yong, Y., Zugeng, L.: Effects of surface oxide species on the electropolymerization of o-aminophenol on pretreated glassy carbon electrodes. Synth. Met. 78, 111 (1996)

    Article  Google Scholar 

  7. Kunimura, S., Ohsaka, T., Oyama, N.: Preparation of thin polymeric films on electrode surfaces by electropolymerization of o-aminophenol. Macromolecules 21, 894 (1988)

    Article  CAS  Google Scholar 

  8. Zhang, A.Q., Cui, C.Q., Chen, Y.Z., Lee, J.Y.: Synthesis and electrochromic properties of poly-o-aminophenol. J. Electroanal. Chem. 373, 115 (1994)

    Article  CAS  Google Scholar 

  9. Zhang, A.Q., Cui, C.Q., Lee, J.Y.: Metal-polymer interactions in the Ag(I)|poly-o-aminophenol system. J. Electroanal. Chem. 413, 143 (1996)

    Article  Google Scholar 

  10. Zhang, A.Q., Chen, Y.Z., Tian, Z.W.: Metal|polymer interactions in the Cu(I)-poly(o-aminophenol) system. Acta Phys. Chem. China 9, 523 (1993)

    CAS  Google Scholar 

  11. Yano, J., Kawakami, H., Yamasaki, S., Kanno, Y.: Cation capturing ability and the potential response of a poly(o-aminophenol) film electrode to dissolved ferric ions. J. Electrochem. Soc. 148, E61 (2001)

    Article  CAS  Google Scholar 

  12. Jano, J., Kawakami, H., Yamasaki, S.: Potential response of poly(o-aminophenol) film electrode to dissolved ferric ion. Synth. Met. 102, 1335 (1999)

    Article  Google Scholar 

  13. Ul-Haq, A., Shah, A., Holze, R.: Poly(o-aminophenol) with two redox processes: A spectroelectrochemical study. J. Electroanal. Chem. 597, 95 (2006)

    Article  Google Scholar 

  14. Miras, M.C., Badano, A., Bruno, M.M., Barbero, C.: Nitric oxide electrochemical sensors based in hybrid films of conducting polymers and metal phtalocyanines. Portugaliae Electrochim. Acta 21, 235 (2003)

    Article  CAS  Google Scholar 

  15. Golabi, S.M., Nozad, A.: Electrocatalytic oxidation of methanol at lower potentials on glassy carbon electrode modified by platinum and platinum alloys incorporated in poly(o-aminophenol) films. Electroanalysis 15, 278 (2003)

    Article  CAS  Google Scholar 

  16. Guenbour, A., Kacemi, A., Benbachir, A., Aries, L.: Electropolymerization of 2-aminophenol. Electrochemical and spectroscopic studies. Progr. Org. Coatings 38, 121 (2000)

    Article  CAS  Google Scholar 

  17. Kursun, S., Ekinci, B.Z., Pasahan, A., Ekinci, E.: Preparation and properties of amperometric uric acid sensor based on poly(2-aminophenol). J. Appl. Polym. Sci. 120, 406 (2011)

    Article  CAS  Google Scholar 

  18. Tao, W., Pan, D., Liu, Y., Nie, L., Yao, S.: An amperometric glucose biosensor based on poly(o-aminophenol) and Prussian blue films at platinum electrodes. Anal. Biochem. 338, 332 (2005)

    Article  CAS  Google Scholar 

  19. Tao, W., Liu, Y., Pan, D., Nie, L., Yao, S.: Study of enhancement of catalytic activity for hemoglobin by quinhydrone in poly(o-aminophenol) film. Bioelectrochemistry 65, 51 (2004)

    Article  CAS  Google Scholar 

  20. Pan, D., Chen, J., Nie, L., Tao, W., Yao, S.: Amperometic glucose biosensor based on immobilization of glucose oxidase in electropolymerized o-aminophenol film at Prussian blue-modified platinum electrode. Electrochim. Acta 49, 795 (2004)

    Article  CAS  Google Scholar 

  21. Miland, E., Miranda Ordieres, A.J., Tunon Blanco, P., Smyth, M.R., Fagain, C.O.: Poly(o-aminophenol)-modified bienzyme carbon paste electrode for the detection of uric acid. Talanta 43, 785 (1996)

    Article  CAS  Google Scholar 

  22. Lobo Castañon, J., Miranda Ordieres, A.J., Tunon Blanco, P.: A bienzyme-poly-(o-phenylenediamine)-modified carbon paste electrode for the amperometric detection of L-lactate. Anal. Chim. Acta 346, 165 (1997)

    Article  Google Scholar 

  23. Lobo, M.J., Miranda, A.J., Lopez-Fonseca, J.M., Tunon, P.: Electrocatalytic detection of nicotinamide coenzymes by poly(o-aminophenol) and poly(o-phenylenediamine)-modified carbon paste electrodes. Anal. Chim. Acta 325, 33 (1996)

    Article  CAS  Google Scholar 

  24. Palys, B., Marzec, M., Rogalski, J.: Poly-o-aminophenol as a laccase mediator and influence of the enzyme on the polymer electrodeposition. Bioelectrochemistry 80, 43 (2010)

    Article  CAS  Google Scholar 

  25. Pan, D., Chen, J., Yao, S., Tao, W., Nie, L.: An amperometric glucose biosensor based on glucose oxidase immobilized in electropolymerized poly(o-aminophenol) and carbon nanotubes composite film on a gold electrode. Anal. Sci. Jpn. Soc. Anal. Chem. 21, 367 (2005)

    CAS  Google Scholar 

  26. Zhang, Z., Liu, H., Deng, J.: A glucose biosensor based on immobilization of glucose oxidase in electropolymerized o-aminophenol film on platinized glassy carbon electrode. Anal. Chem. 68, 1632 (1996)

    Article  CAS  Google Scholar 

  27. Li, J., Lin, X.: Glucose biosensor based on immobilization of glucose oxidase in poly(o-aminophenol) film on polypyrrole-Pt nanocomposite modified glassy carbon electrode. Biosens. Bioelectron. 22, 2898 (2007)

    Article  CAS  Google Scholar 

  28. Tucceri, R.I.: J. Specularity change of a thin gold film surface coated with poly(o-aminophenol) during the polymer redox conversion. The pH affect on the redox sites distribution at the metal||polymer interface. Electroanal. Chem. 543, 61 (2003)

    Article  CAS  Google Scholar 

  29. Ohsaka, T., Kunimura, S., Oyama, N.: Electrode kinetics of poly(o-aminophenol) film prepared by electro-oxidative polymerization of o-aminophenol and its electrochromic properties. Electrochim. Acta 33, 639 (1988)

    Article  CAS  Google Scholar 

  30. Salvagione, H.J., Arias-Padilla, J., Perez, J.M., Vazquez, J.L., Morallon, E., Miras, M.C., Barbero, C.:Study of the redox mechanism of poly(o-aminophenol) using in situ techniques: evidence of two redox processes. J. Electroanal. Chem. 576, 139 (2005)

    Article  Google Scholar 

  31. Tucceri, R.I., Barbero, C., Silber, J.J., Sereno, L., Posadas, D.: Spectroelectrochemical study of poly-o-aminophenol. Electrochim. Acta 42, 919 (1997)

    Article  CAS  Google Scholar 

  32. Chen, Y.Z., Zhang, A.Q., Tian, Z.W.: Poly(o-aminophenol) studied by X-ray Photoelectron Spectroscopy. Chem. J. Chin. 12, 519 (1991)

    CAS  Google Scholar 

  33. Barbero, C., Zerbino, J., Sereno, L., Posadas, D.: Optical properties of electropolymerized orthoaminophenol. Electrochim. Acta 32, 693 (1987)

    Article  CAS  Google Scholar 

  34. Jackowska, K., Bukowska, J., Kudelski, A.: Electro-oxidation of o-aminophenol studied by cyclic voltammetry and surface enhanced Raman scattering (SERS). J. Electroanal. Chem. 350, 177 (1993)

    Article  CAS  Google Scholar 

  35. Jackowska, K., Bukowska, J., Kudelski, A.: Poly-ortho-aminophenol modified electrodes. Structure and electrochemical properties. Polish J. Chem. 68, 141 (1994)

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ricardo Tucceri .

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Tucceri, R. (2013). Electropolymerization of o-aminophenol on Different Electrode Materials and in Different Electrolyte Media: Formation of Poly(o-aminophenol) Film Electrodes. In: Poly(o-aminophenol) Film Electrodes. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-02114-0_1

Download citation

Publish with us

Policies and ethics