Abstract
Oxidation of o-aminophenol on different electrode materials (gold, platinum, carbon, indium-tin oxide, etc.) in aqueous medium was shown to form poly-o-aminophenol (POAP). Like aniline, o-AP can be polymerized electrochemically in acidic, neutral and alkaline solutions. However, while a conducting film is only formed in acidic media, POAP synthesized in neutral and alkaline media leads to a nonconducting film.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Barbero, C., Silber, J.J., Sereno, L.: Formation of a novel electroactive film by electropolymerization of orthoaminophenol. Study of its chemical structure and formation mechanism. Electropolymerization of analogous compounds. J. Electroanal. Chem. 263, 333 (1989)
Salvagione, H.J., Arias, J., Garces, P., Morallon, E., Barbero, C., Vazquez, L.: Spectroelectrochemical study of the oxidation of aminophenols on platinum electrode in acid medium. J. Electroanal. Chem. 565, 375 (2004)
Ortega, M.: Conducting potential range of poly(o-aminophenol). Thin Solid Films 371, 28 (2000)
Ojani, R., Raoof, J.B., Fathi, S.: Poly(o-aminophenol) film prepared in the presence of sodium dodecyl sulphate: Aplication for nickel-ion dispersion and the elecctrocatalytic oxidation of methanol and ethylene glycol. Electrochim. Acta 54, 2190 (2009)
Goncalves, D., Faria, R.C., Yonashiro, M., Bulhoes, L.O.S.: Electrochemical oxidation of o-aminophenol in aqueous medium: formation of film and soluble products. J. Electroanal. Chem. 487, 90 (2000)
Yong, Y., Zugeng, L.: Effects of surface oxide species on the electropolymerization of o-aminophenol on pretreated glassy carbon electrodes. Synth. Met. 78, 111 (1996)
Kunimura, S., Ohsaka, T., Oyama, N.: Preparation of thin polymeric films on electrode surfaces by electropolymerization of o-aminophenol. Macromolecules 21, 894 (1988)
Zhang, A.Q., Cui, C.Q., Chen, Y.Z., Lee, J.Y.: Synthesis and electrochromic properties of poly-o-aminophenol. J. Electroanal. Chem. 373, 115 (1994)
Zhang, A.Q., Cui, C.Q., Lee, J.Y.: Metal-polymer interactions in the Ag(I)|poly-o-aminophenol system. J. Electroanal. Chem. 413, 143 (1996)
Zhang, A.Q., Chen, Y.Z., Tian, Z.W.: Metal|polymer interactions in the Cu(I)-poly(o-aminophenol) system. Acta Phys. Chem. China 9, 523 (1993)
Yano, J., Kawakami, H., Yamasaki, S., Kanno, Y.: Cation capturing ability and the potential response of a poly(o-aminophenol) film electrode to dissolved ferric ions. J. Electrochem. Soc. 148, E61 (2001)
Jano, J., Kawakami, H., Yamasaki, S.: Potential response of poly(o-aminophenol) film electrode to dissolved ferric ion. Synth. Met. 102, 1335 (1999)
Ul-Haq, A., Shah, A., Holze, R.: Poly(o-aminophenol) with two redox processes: A spectroelectrochemical study. J. Electroanal. Chem. 597, 95 (2006)
Miras, M.C., Badano, A., Bruno, M.M., Barbero, C.: Nitric oxide electrochemical sensors based in hybrid films of conducting polymers and metal phtalocyanines. Portugaliae Electrochim. Acta 21, 235 (2003)
Golabi, S.M., Nozad, A.: Electrocatalytic oxidation of methanol at lower potentials on glassy carbon electrode modified by platinum and platinum alloys incorporated in poly(o-aminophenol) films. Electroanalysis 15, 278 (2003)
Guenbour, A., Kacemi, A., Benbachir, A., Aries, L.: Electropolymerization of 2-aminophenol. Electrochemical and spectroscopic studies. Progr. Org. Coatings 38, 121 (2000)
Kursun, S., Ekinci, B.Z., Pasahan, A., Ekinci, E.: Preparation and properties of amperometric uric acid sensor based on poly(2-aminophenol). J. Appl. Polym. Sci. 120, 406 (2011)
Tao, W., Pan, D., Liu, Y., Nie, L., Yao, S.: An amperometric glucose biosensor based on poly(o-aminophenol) and Prussian blue films at platinum electrodes. Anal. Biochem. 338, 332 (2005)
Tao, W., Liu, Y., Pan, D., Nie, L., Yao, S.: Study of enhancement of catalytic activity for hemoglobin by quinhydrone in poly(o-aminophenol) film. Bioelectrochemistry 65, 51 (2004)
Pan, D., Chen, J., Nie, L., Tao, W., Yao, S.: Amperometic glucose biosensor based on immobilization of glucose oxidase in electropolymerized o-aminophenol film at Prussian blue-modified platinum electrode. Electrochim. Acta 49, 795 (2004)
Miland, E., Miranda Ordieres, A.J., Tunon Blanco, P., Smyth, M.R., Fagain, C.O.: Poly(o-aminophenol)-modified bienzyme carbon paste electrode for the detection of uric acid. Talanta 43, 785 (1996)
Lobo Castañon, J., Miranda Ordieres, A.J., Tunon Blanco, P.: A bienzyme-poly-(o-phenylenediamine)-modified carbon paste electrode for the amperometric detection of L-lactate. Anal. Chim. Acta 346, 165 (1997)
Lobo, M.J., Miranda, A.J., Lopez-Fonseca, J.M., Tunon, P.: Electrocatalytic detection of nicotinamide coenzymes by poly(o-aminophenol) and poly(o-phenylenediamine)-modified carbon paste electrodes. Anal. Chim. Acta 325, 33 (1996)
Palys, B., Marzec, M., Rogalski, J.: Poly-o-aminophenol as a laccase mediator and influence of the enzyme on the polymer electrodeposition. Bioelectrochemistry 80, 43 (2010)
Pan, D., Chen, J., Yao, S., Tao, W., Nie, L.: An amperometric glucose biosensor based on glucose oxidase immobilized in electropolymerized poly(o-aminophenol) and carbon nanotubes composite film on a gold electrode. Anal. Sci. Jpn. Soc. Anal. Chem. 21, 367 (2005)
Zhang, Z., Liu, H., Deng, J.: A glucose biosensor based on immobilization of glucose oxidase in electropolymerized o-aminophenol film on platinized glassy carbon electrode. Anal. Chem. 68, 1632 (1996)
Li, J., Lin, X.: Glucose biosensor based on immobilization of glucose oxidase in poly(o-aminophenol) film on polypyrrole-Pt nanocomposite modified glassy carbon electrode. Biosens. Bioelectron. 22, 2898 (2007)
Tucceri, R.I.: J. Specularity change of a thin gold film surface coated with poly(o-aminophenol) during the polymer redox conversion. The pH affect on the redox sites distribution at the metal||polymer interface. Electroanal. Chem. 543, 61 (2003)
Ohsaka, T., Kunimura, S., Oyama, N.: Electrode kinetics of poly(o-aminophenol) film prepared by electro-oxidative polymerization of o-aminophenol and its electrochromic properties. Electrochim. Acta 33, 639 (1988)
Salvagione, H.J., Arias-Padilla, J., Perez, J.M., Vazquez, J.L., Morallon, E., Miras, M.C., Barbero, C.:Study of the redox mechanism of poly(o-aminophenol) using in situ techniques: evidence of two redox processes. J. Electroanal. Chem. 576, 139 (2005)
Tucceri, R.I., Barbero, C., Silber, J.J., Sereno, L., Posadas, D.: Spectroelectrochemical study of poly-o-aminophenol. Electrochim. Acta 42, 919 (1997)
Chen, Y.Z., Zhang, A.Q., Tian, Z.W.: Poly(o-aminophenol) studied by X-ray Photoelectron Spectroscopy. Chem. J. Chin. 12, 519 (1991)
Barbero, C., Zerbino, J., Sereno, L., Posadas, D.: Optical properties of electropolymerized orthoaminophenol. Electrochim. Acta 32, 693 (1987)
Jackowska, K., Bukowska, J., Kudelski, A.: Electro-oxidation of o-aminophenol studied by cyclic voltammetry and surface enhanced Raman scattering (SERS). J. Electroanal. Chem. 350, 177 (1993)
Jackowska, K., Bukowska, J., Kudelski, A.: Poly-ortho-aminophenol modified electrodes. Structure and electrochemical properties. Polish J. Chem. 68, 141 (1994)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2013 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Tucceri, R. (2013). Electropolymerization of o-aminophenol on Different Electrode Materials and in Different Electrolyte Media: Formation of Poly(o-aminophenol) Film Electrodes. In: Poly(o-aminophenol) Film Electrodes. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-02114-0_1
Download citation
DOI: https://doi.org/10.1007/978-3-319-02114-0_1
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-02113-3
Online ISBN: 978-3-319-02114-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)