Abstract
Anode material expansion and cracking is a well-known issue with high-capacity, rechargeable lithium ion battery systems. Substantial strains develop within the anode during both the lithium ion infusion and removal processes. In this work, a custom configuration of the standard CR2032 coin cell battery is used to allow in-situ monitoring of in-plane strain development within the anode via digital image correlation. An anode thin films consisting of amorphous silicon deposited on a metal substrate is tested to determine the influence of film adhesion and battery cycling parameters on the strain-to-failure behavior.
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References
Nagaura T, Tozawa K (1990) Lithium ion rechargeable battery. Prog Batteries Solar Cells 9:209
Boukamp BA, Lesh GC, Huggins RA (1981) All-solid lithium electrodes with mixed-conductor matrix. J Electrochem Soc 128:725–729
Obrovac MN, Christensen L (2004) Structural changes in silicon anodes during lithium insertion/extraction. Electrochem Solid State Lett 7(5):A93–A96
Park CM, Kim JH, Kim H, Sohn HJ (2010) Li-alloy based anode materials for secondary batteries. Chem Soc Rev 39(8):3115–3141
Kasavajjula U, Wang CS, Appleby AJ (2007) Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells. J Power Sources 163(2):1003–1009
Li J, Lewis RB, Dahn JR (2007) Sodium carboxymethyl cellulose – a potential binder for Si negative electrodes for Li-ion batteries. Electrochem Solid State Lett 10(2):A17–A20
Fu LJ, Liu H, Li C, Wu YP, Rahm E, Holze R, Wu HQ (2006) Surface modifications of electrode materials for lithium ion batteries. Solid State Sci 8(2):113–128, February
Maranchi JP, Hepp AF, Kumta PN (2003) High capacity, reversible silicon thin-film anodes for lithium-ion batteries. Electrochem Solid State Lett 6(9):A198–A201
Chan CK, Peng HL, Liu G, McIlwrath K, Zhang XF, Huggins RA, Cui Y (2008) High-performance lithium battery anodes using silicon nanowires. Nat Nanotechnol 3(1):31–35
Kim H, Seo M, Park MH, Cho J (2010) A critical size of silicon nano-anodes for lithium rechargeable batteries. Angew Chem Int Edit 49(12):2146–2149
Xiao X, Liu P, Verbrugge MW, Haftbaradarab H (2010) Gao HImproved cycling stability of solicon thin film electrodes through patterning for high energy density lithium batteries. J Power Sources 196(3):1409–1416
Sethuraman VA, Chon MJ, Shimshak M, Srinivasan V, Guduru PR (2010) In situ measurements of stress evolution in silicon thin films during electrochemical lithiation and delithiation. J Power Sources 195:5062–5066
Sethuraman VA, Chon MJ, Shimshak M, Van Winkle N, Guduru PR (2010) In situ measurements of the biaxial modulus of Si anode for Li-ion batteries. Electrochem Commun 12:1614–1617
Qi Y, Harris SJ (2010) In situ observation of strains during lithiation of a graphite electrode. J Electrochem Soc 157(6):A741–A747
Sutton MA, Wolters WJ, Peters WH, Ranson WF, McNeill SRS (1983) Determination of displacements using an improved digital correlation method. Image Vis Comput 1(3):133–139, August
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© 2014 The Society for Experimental Mechanics, Inc.
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Chen, J., Berfield, T.A. (2014). In-Situ Characterization of Strain in Lithium Ion Battery Anodes. In: Tandon, G., Tekalur, S., Ralph, C., Sottos, N., Blaiszik, B. (eds) Experimental Mechanics of Composite, Hybrid, and Multifunctional Materials, Volume 6. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-319-00873-8_5
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DOI: https://doi.org/10.1007/978-3-319-00873-8_5
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