Abstract
Surfactants frequently self-assemble in water or in oil, into a large variety of structures, depending on the surfactant and on its concentration. The most common structures will be described in this chapter. Surfactants may also self-assemble in the presence of both oil and water, and structures such as microemulsions are encountered. Self-assembly also occurs in mixed solutions of surfactants and polymers or particles, in solutions of amphiphilic polymers or proteins and in dispersions of particles with functionalized surfaces. A recent survey can be found in the book edited by Nagarajan (2019). Because of their relevance to emulsions, microemulsions, and foams, this chapter will focus on surfactant-based systems and their main features. The common case of surfactant molecules with small polar head groups and hydrophobic carbon chains will be mostly considered. The topic is described in more detail in many books that the reader may consult, for instance, Tanford (1980), Israelachvili (1992), and Evans and Wennerström (1999).
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References
Abillon, O., Chatenay, D., Langevin, D., & Meunier, J. (1984). Light scattering study of a lower critical consolute point in a micellar system. Journal de Physique Lettres, 45(5), 223–231.
Alexander, S., Chaikin, P. M., Grant, P., Morales, G. J., Pincus, P., & Hone, D. (1984). Charge renormalization, osmotic-pressure, and bulk modulus of colloidal crystals – Theory. Journal of Chemical Physics, 80(11), 5776–5781. https://doi.org/10.1063/1.446600.
Almgren, M., Hansson, P., Mukhtar, E., & Vanstam, J. (1992). Aggregation of alkyltrimethylammonium surfactants in aqueous poly(styrenesulfonate) solutions. Langmuir, 8(10), 2405–2412. https://doi.org/10.1021/la00046a011.
Aniansson, E. A. G., Wall, S. N., Almgren, M., Hoffmann, H., Kielmann, I., Ulbricht, W., Zana, R., Lang, G., & Tondre, C. (1976). Theory of kinetics of micellar equilibria and quantitative interpretation of chemical relaxation studies of micellar solutions of ionic surfactants. Journal of Physical Chemistry, 80(9), 905–922.
Appell, J., Bassereau, P., Marignan, J., & Porte, G. (1990). Polymorphism in dilute surfactant solutions: A neutron scattering study. In Trends in colloid and interface science IV (pp. 13–18). Springer.
Arriaga, L. R., Drenckhan, W., Salonen, A., Rodrigues, J. A., Iniguez-Palomares, R., Rio, E., & Langevin, D. (2012a). On the long-term stability of foams stabilised by mixtures of nano-particles and oppositely charged short chain surfactants. Soft Matter, 8(43), 11085–11097. https://doi.org/10.1039/c2sm26461g.
Arriaga, L. R., Monroy, F., & Langevin, D. (2012b). The polymer glass transition in nanometric films. European Physics Letters, 98(3), 38007. https://doi.org/10.1209/0295-5075/98/38007.
Auvray, X., Petipas, C., Anthore, R., Rico, I., & Lattes, A. (1989). X-ray diffraction study of mesophases of cetyltrimethylammonium bromide in water, formamide, and glycerol. The Journal of Physical Chemistry, 93(21), 7458–7464.
Aveyard, R., Binks, B. P., & Fletcher, P. D. I. (1989). Interfacial-tensions and aggregate structure in C12E5 oil-water microemulsion systems. Langmuir, 5(5), 1210–1217. https://doi.org/10.1021/la00089a015.
Bernheim-Groswasser, A., Tlusty, T., Safran, S. A., & Talmon, Y. (1999). Direct observation of phase separation in microemulsion networks. Langmuir, 15(17), 5448–5453. https://doi.org/10.1021/la990301q.
Binks, B. P. (1993). Relationship between microemulsion phase behavior and macroemulsion type in systems containing nonionic surfactant. Langmuir, 9(1), 25–28.
Binks, B. P., Meunier, J., Abillon, O., & Langevin, D. (1989). Measurement of film rigidity and interfacial tensions in several ionic surfactant oil-water microemulsion systems. Langmuir, 5(2), 415–421.
Binks, B. P., Kellay, H., & Meunier, J. (1991). Effects of alkane chain length on the bending elasticity constant K of AOT monolayers at the planar oil-water interface. Europhysics Letters, 16(1), 53–58.
Binks, B. P., Kirkland, M., & Rodrigues, J. A. (2008). Origin of stabilisation of aqueous foams in nanoparticle-surfactant mixtures. Soft Matter, 4(12), 2373–2382. https://doi.org/10.1039/b811291f.
Briceño-Ahumada, Z., Drenckhan, W., & Langevin, D. (2016a). Coalescence in draining foams made of very small bubbles. Physical Review Letters, 116, 128302.
Briceño-Ahumada, Z., Maldonado, A., Imperor-Clerc, M., & Langevin, D. (2016b). On the stability of foams made with surfactant bilayer phases. Soft Matter, 12(5), 1459–1467.
Cabane, B., & Duplessix, R. (1982). Organization of surfactant micelles adsorbed on a polymer molecule in water: A neutron scattering study. Journal de Physique, 43(10), 1529–1542.
Cates, M. E., & Candau, S. J. (1990). Statics and dynamics of worm-like surfactant micelles. Journal of Physics-Condensed Matter, 2(33), 6869–6892.
Cazabat, A. M., Langevin, D., Meunier, J., & Pouchelon, A. (1982). Critical behavior in microemulsions. Advances in Colloid and Interface Science, 16, 175–199.
Cazabat, A. M., Chatenay, D., Langevin, D., & Meunier, J. (1983). Percolation and critical points in microemulsions. Faraday Discussions, 76(76), 291–303.
Chang, D. P., Barauskas, J., Dabkowska, A. P., Wadsater, M., Tiberg, F., & Nylander, T. (2015). Non-lamellar lipid liquid crystalline structures at interfaces. Advances in Colloid and Interface Science, 222, 135–147. https://doi.org/10.1016/j.cis.2014.11.003.
Chatellier, X., & Joanny, J. F. (1996). Adsorption of polyelectrolyte solutions on surfaces: A Debye-Huckel theory. Journal de Physique II, 6(12), 1669–1686. https://doi.org/10.1051/jp2:1996156.
Daillant, J., Bosio, L., Benattar, J., & Meunier, J. (1989). Capillary waves and bending elasticity of monolayers on water studied by x-ray reflectivity as a function of surface pressure. Europhysics Letters, 8(5), 453.
de Gennes, P. G. (1979). Scaling concepts in polymers physics. Ithaca: Cornell University Press.
de Gennes, P. G., & Prost, J. (1993). The physics of liquid crystals. Oxford: Clarendon Press.
de Gennes, P. G., & Taupin, C. (1982). Microemulsions and the flexibility of oil-water interfaces. Journal of Physical Chemistry, 86(13), 2294–2304.
Dechaine, G. P., & Gray, M. R. (2011). Membrane diffusion measurements do not detect exchange between asphaltene aggregates and solution phase. Energy & Fuels, 25, 509–523. https://doi.org/10.1021/ef101050a.
Dobrynin, A. V., & Rubinstein, M. (2005). Theory of polyelectrolytes in solutions and at surfaces. Progress in Polymer Science, 30(11), 1049–1118. https://doi.org/10.1016/j.progpolymsci.2005.07.006.
Dubois, M., Deme, B., Gulik-Krzywicki, T., Dedieu, J. C., Vautrin, C., Desert, S., Perez, E., & Zemb, T. (2001). Self-assembly of regular hollow icosahedra in salt-free catanionic solutions. Nature, 411(6838), 672–675.
Duwe, H., Kaes, J., & Sackmann, E. (1990). Bending elastic moduli of lipid bilayers: Modulation by solutes. Journal de Physique, 51(10), 945–961.
Eastoe, J., Dupont, A., & Steytler, D. C. (2003). Fluorinated surfactants in supercritical CO2. Current Opinion in Colloid & Interface Science, 8(3), 267–273. https://doi.org/10.1016/S1359-0294(03)00053-0.
Endo, H., Mihailescu, M., Monkenbusch, M., Allgaier, J., Gompper, G., Richter, D., Jakobs, B., Sottman, T., Strey, R., & Grillo, I. (2001). Effect of amphiphilic block copolymers on the structure and phase behavior of oil–water-surfactant mixtures. The Journal of Chemical Physics, 115(1), 580–600. https://doi.org/10.1063/1.1377881.
Evans, F., & Wennerström, W. (1999). The colloidal domain (2nd ed.). New York: Wiley.
Eyssautier, J., Levitz, P., Espinat, D., Jestin, J., Gummel, J., Grillo, I., & Barre, L. (2011). insight into asphaltene nanoaggregate structure inferred by small angle neutron and X-ray scattering. Journal of Physical Chemistry B, 115(21), 6827–6837. https://doi.org/10.1021/jp111468d.
Felgner, P. L., Gadek, T. R., Holm, M., Roman, R., Chan, H. W., Wenz, M., Northrop, J., Ringlod, G. M., & Danielsen, M. (1987). Lipofection: A highly efficient, lipid-mediated DNA-transfection procedure. Proceedings of the National Academy of Sciences, 84(21), 7413–7417.
Fletcher, P. D. I., & Horsup, D. I. (1992). Droplet dynamics in water-in-oil microemulsions and macroemulsions stabilized by nonionic surfactants – Correlation of measured rates with monolayer bending elasticity. Journal of the Chemical Society-Faraday Transactions, 88(6), 855–864. https://doi.org/10.1039/ft9928800855.
Goddard, E. D., & Ananthapadmanabhan, K. P. (1992). Interaction of surfactants with polymers and proteins. In J. C. T. Kwak (Ed.), Polymer-surfactant systems. Boca Raton: CRC Press.
Gompper, G., & Schick, M. (1990a). Correlation between structural and interfacial properties of amphiphilic systems. Physical Review Letters, 65(9), 1116–1119.
Gompper, G., & Schick, M. (1990b). Lattice model of microemulsions. Physical Review B, 41(13), 9148–9162.
Gradzielski, M., Hoffmann, H., & Langevin, D. (1995). Solubilization of decane into the ternary-system TDMAO/1-hexanol/water. Journal of Physical Chemistry, 99(33), 12612–12623. https://doi.org/10.1021/j100033a039.
Gradzielski, M., Langevin, D., & Farago, B. (1996a). Experimental investigation of the structure of nonionic microemulsions and their relation to the bending elasticity of the amphiphilic film. Physical Review E, 53(4), 3900–3919.
radzielski, M., Langevin, D., Sottmann, T., & Strey, R. (1996b). Small angle neutron scattering near the wetting transition: Discrimination of microemulsions from weakly structured mixtures. Journal of Chemical Physics, 104(10), 3782–3787.
Guering, P., Cazabat, A. M., & Paillette, M. (1986). Droplets clustering in microemulsions – An electric-birefringence study. Europhysics Letters, 2(12), 953–960.
Hellweg, T., & Langevin, D. (1998). Bending elasticity of the surfactant monolayer in droplet microemulsions: Determination by a combination of dynamic light scattering and neutron spin-echo spectroscopy. Physical Review E, 57(6), 6825–6834.
Hellweg, T., & Langevin, D. (1999). The dynamics in dodecane/C10E5/water microemulsions determined by time resolved scattering techniques. Physica A-Statistical Mechanics and Its Applications, 264(3–4), 370–387.
Hellweg, T., Brulet, A., & Sottmann, T. (2000). Dynamics in an oil-continuous droplet microemulsion as seen by quasielastic scattering techniques. Physical Chemistry Chemical Physics, 2(22), 5168–5174. https://doi.org/10.1039/b005088l.
Hoffmann, H., & Ulbricht, W. (1989). Transition of rodlike to globular micelles by the solubilisation of additives. Journal of Colloid and Interface Science, 129(2), 388–405.
Holmberg, K. (1994). Organic and bioorganic reactions in microemulsions. Advances in Colloid and Interface Science, 51, 137–174. https://doi.org/10.1016/0001-8686(94)80035-9.
Ilekti, P., Martin, T., Cabane, B., & Piculell, L. (1999). Effects of polyelectrolytes on the structures and interactions of surfactant aggregates. The Journal of Physical Chemistry B, 103(45), 9831–9840. https://doi.org/10.1021/jp991259a.
Israelachvili, J. (1992). Intermolecular and surface forces (2nd ed.). San Diego: Academic.
Israelachvili, J. N., Mitchell, D. J., & Ninham, B. W. (1976). Theory of self assembly of hydrocarbon amphiphiles into micelles and bilayers. Journal of the Chemical Society-Faraday Transactions II, 72, 1525–1568.
Jones, P., Wyn-Jones, E., & Tiddy, G. J. (1987). Kinetic and equilibrium studies associated with the aggregation of non-ionic surfactants in non-polar solvents. Journal of the Chemical Society, Faraday Transactions 1, 83(9), 2735–2749.
Kahlweit, M. (1982). Kinetics of formation of association colloids. Journal of Colloid and Interface Science, 90(1), 92–99.
Kahlweit, M., Strey, R., & Firman, P. (1986). Search for tricritical points in ternary systems water-oil-nonionic amphiphile. Journal of Physical Chemistry, 90(4), 671–677.
Kaler, E. W., Herrington, K. L., Murthy, A. K., & Zasadzinski, J. A. N. (1992). Phase behaviour and structures of mixtures of anionic and cationic surfactants. Journal of Physical Chemistry, 96(16), 6698–6707.
Kosmella, S., & Koetz, J. (2012). Polymer-modified w/o microemulsions – With tunable droplet-droplet interactions. Current Opinion in Colloid & Interface Science, 17(5), 261–265. https://doi.org/10.1016/j.cocis.2012.06.004.
Kotlarchyk, M., Huang, J. S., & Chen, S. H. (1985). Structure of AOT reversed micelles determined by small-angle neutron scattering. The Journal of Physical Chemistry, 89(20), 4382–4386.
Kumar, A., Kushwaha, V., & Sharma, P. K. (2014). Pharmaceutical microemulsion: Formulation, characterization and drug deliveries across skin. International Journal of Drug Development and Research, 6, 1), 1–1),21.
Kunieda, H., & Shinoda, K. (1985). Evaluation of the hydrophile-lipophile balance (HLB) of nonionic surfactants. I. Multisurfactant systems. Journal of Colloid and Interface Science, 107(1), 107–121. https://doi.org/10.1016/0021-9797(85)90154-7.
Kwak, J. C. T. (Ed.). (1998). Polymer-surfactant systems (Vol. 77). New York/Basel: Marcel Dekker.
Lang, J., Jada, A., & Malliaris, A. (1988). Structure and dynamics of water-in-oil droplets stabilized by sodium bis (2-ethylhexyl) sulfosuccinate. The Journal of Physical Chemistry, 92(7), 1946–1953.
Langevin, D. (2009). Complexation of oppositely charged polyelectrolytes and surfactants in aqueous solutions. A review. Advances in Colloid and Interface Science, 147-48, 170–177. https://doi.org/10.1016/j.cis.2008.08.013.
Lattes, A., & Rico, I. (1989). Aggregation in formamide solution: Reactivity and structure of non-aqueous microemulsions. Colloids and Surfaces, 35(2), 221–235.
Leitao, H., Somoza, A. M., daGama, M. M. T., Sottmann, T., & Strey, R. (1996). Scaling of the interfacial tension of microemulsions: A phenomenological description. Journal of Chemical Physics, 105(7), 2875–2883. https://doi.org/10.1063/1.472149.
Lin, Y.-J., Perrard, A., Biswal, S. L., Hill, R. M., & Trabelsi, S. (2018). Microfluidic investigation of asphaltenes-stabilized water-in-oil emulsions. Energy & Fuels, 32(4), 4903–4910.
Lu, J. R., Purcell, I. P., Lee, E. M., Simister, E. A., Thomas, R. K., Rennie, A. R., & Penfold, J. (1995). The composition and structure of sodium dodecyl-sulfate dodecanol mixtures adsorbed at the air-water-interface – A neutron reflection study. Journal of Colloid and Interface Science, 174(2), 441–455. https://doi.org/10.1006/jcis.1995.1412.
McLoughlin, D., Delsanti, M., Tribet, C., & Langevin, D. (2005). DNA bundle formation induced by cationic surfactants. Europhysics Letters, 69(3), 461–467. https://doi.org/10.1209/epl/i2004-10367-2.
McManus, J. J., Rädler, J. O., & Dawson, K. A. (2004). Observation of a rectangular columnar phase in a DNA−calcium−zwitterionic lipid complex. Journal of the American Chemical Society, 126(49), 15966–15967. https://doi.org/10.1021/ja046105+.
Meunier, J. (1992). Light reflectivity and ellipsometry. In D. Langevin (Ed.), Light scattering by liquid surfaces and complementary techniques (pp. 333–364). New York: Dekker, M.
Meunier, J., & Langevin, D. (1982). Optical reflectivity of a diffuse interface. Journal de Physique Lettres, 43(6), L185–L191.
Mihailescu, M., Monkenbusch, M., Endo, H., Allgaier, J., Gompper, G., Stellbrink, J., Richeter, D., Jakobs, B., Sottman, T., & Farago, B. (2001). Dynamics of bicontinuous microemulsion phases with and without amphiphilic block-copolymers. Journal of Chemical Physics, 115(20), 9563–9577. https://doi.org/10.1063/1.1413509.
Moldover, M. R. (1985). Interfacial-tension of fluids near critical-points and 2-scale-factor universality. Physical Review A, 31(2), 1022–1033. https://doi.org/10.1103/PhysRevA.31.1022.
Mullins, O. C. (2010). The modified yen model. Energy & Fuels, 24, 2179–2207. https://doi.org/10.1021/ef900975e.
Nagarajan, R. (Ed.). (2019). Self assembly. From surfactants to nanoparticles. New York: Wiley.
Nazar, M. F., Shah, S. S., & Khosa, M. A. (2011). Microemulsions in enhanced oil recovery: A review. Petroleum Science and Technology, 29(13), 1353–1365. https://doi.org/10.1080/10916460903502514.
Patist, A., Kanicky, J. R., Shukla, P. K., & Shah, D. O. (2002). Importance of micellar kinetics in relation to technological processes. Journal of Colloid and Interface Science, 245(1), 1–15. https://doi.org/10.1006/jcis.2001.7955.
Peliti, L., & Leibler, S. (1985). Effects of thermal fluctuations on systems with small surface tension. Physical Review Letters, 54(15), 1690–1693.
Piculell, L., & Lindman, B. (1992). Association and segregation in aqueous polymer/polymer, polymer/surfactant, and surfactant/surfactant mixtures: similarities and differences. Advances in Colloid and Interface Science, 41, 149–178. https://doi.org/10.1016/0001-8686(92)80011-L.
Pileni, M. P. (1997). Nanosized Particles Made in Colloidal Assemblies. Langmuir, 13(13), 3266–3276. https://doi.org/10.1021/la960319q.
Porte, G., Appell, J., Bassereau, P., & Marignan, J. (1989). L-alpha to L3 – A topology driven transition in phases of infinite fluid membranes. Journal de Physique, 50(11), 1335–1347.
Pouchelon, A., Chatenay, D., Meunier, J., & Langevin, D. (1981). Origin of low interfacial-tensions in systems involving micro-emulsion phases. Journal of Colloid and Interface Science, 82(2), 418–422. https://doi.org/10.1016/0021-9797(81)90383-0.
Prince, L. M. (Ed.). (1977). Microemulsions. New York: Academic.
Quemada, D., & Langevin, D. (1985). Rheological modeling of microemulsions. [Article]. Journal de Mécanique Theorique et Appliquée, 201–237.
Ramadan, M. S., Evans, D. F., & Lumry, R. (1983). Why micelles form in water and hydrazine. A reexamination of the origins of hydrophobicity. The Journal of Physical Chemistry, 87(22), 4538–4543.
Riess, J. G. (2002). Fluorous micro- and nanophases with a biomedical perspective. Tetrahedron, 58(20), 4113–4131. https://doi.org/10.1016/s0040-4020(02)00262-4.
Rubinstein, M., & Colby, R. H. (2003). Polymer physics. New York: Oxford University Press.
Safinya, C., Sirota, E., Roux, D., & Smith, G. (1989). Universality in interacting membranes: The effect of cosurfactants on the interfacial rigidity. Physical Review Letters, 62(10), 1134.
Safran, S. A. (1994). Fluctuating interfaces and the structure of microemulsions. In W. M. Gelbart, A. Ben-Shaul, & D. Roux (Eds.), Micelles, membranes, microemulsions and monolayers (pp. 427–484). New York: Springer.
Safran, S. A., Turkevich, L. A., & Pincus, P. (1984). Cylindrical microemulsions – A polymer-like phase. Journal de Physique Lettres, 45(2), L69–L74.
Salager, J. L., Marquez, L., Pena, A. A., Rondon, M., Silva, F., & Tyrode, E. (2000). Current phenomenological know-how and modeling of emulsion inversion. Industrial & Engineering Chemistry Research, 39(8), 2665–2676. https://doi.org/10.1021/ie990778x.
Salager, J.-L., Antón, R. E., Andérez, J. M., & Aubry, J.-M. (2001). Formulation des micro-émulsions par la méthode HLD. In Techniques de l’Ingénieur(J2 157) (pp. 1–20).
Schurtenberger, P., Magid, L., King, S., & Lindner, P. (1991). Cylindrical structure and flexibility of polymerlike lecithin reverse micelles. The Journal of Physical Chemistry, 95(11), 4173–4176.
Schwuger, M. J., Stickdorn, K., & Schomacker, R. (1995). Microemulsions in technical processes. Chemical Reviews, 95(4), 849–864. https://doi.org/10.1021/cr00036a003.
Skouri, M., Marignan, J., Appell, J., & Porte, G. (1991). Fluid membranes in the semirigid regime – Scale-invariance. Journal de Physique II, 1(9), 1121–1132.
Sottmann, T., & Strey, R. (1997). Ultralow interfacial tensions in water–n-alkane–surfactant systems. The Journal of Chemical Physics, 106(20), 8606–8615.
Strey, R. (1994). Microemulsion microstructure and interfacial curvature. Colloid and Polymer Science, 272(8), 1005–1019.
Stubenrauch, C., & Gießelmann, F. (2016). Gelled complex fluids: Combining unique structures with mechanical stability. Angewandte Chemie International Edition, 55(10), 3268–3275.
Stubenrauch, C., Tessendorf, R., Strey, R., Lynch, I., & Dawson, K. A. (2007). Gelled polymerizable microemulsions. 1. Phase behavior. Langmuir, 23(14), 7730–7737.
Talmon, Y., & Prager, S. (1978). Statistical thermodynamics of phase equilibria in microemulsions. Journal of Chemical Physics, 69, 2984–2992.
Tanford, C. (1980). The hydrophobic effect (2nd ed.). New York: Wiley.
Teubner, M., & Strey, R. (1987). Origin of the scattering peak in microemulsions. Journal of Chemical Physics, 87(5), 3195–3200.
Tresset, G., Cheong, W. C. D., Tan, Y. L. S., Boulaire, J., & Lam, Y. M. (2007). Phospholipid-based artificial viruses assembled by multivalent cations. Biophysical Journal, 93(2), 637–644. https://doi.org/10.1529/biophysj.107.104448.
Walde, P., Cosentino, K., Engel, H., & Stano, P. (2010). Giant vesicles: Preparations and applications. ChemBioChem, 11(7), 848–865.
Wang, Z.-G., & Safran, S. A. (1990). Equilibrium emulsification of polymer blends by diblock copolymers. Journal de Physique, 51(2), 185–200.
Watarai, H. (1997). Microemulsions in separation sciences. Journal of Chromatography A, 780(1–2), 93–102. https://doi.org/10.1016/s0021-9673(97)00444-5.
Widom, B. (1986). Lattice model of microemulsions. Journal of Chemical Physics, 84(12), 6943–6954.
Winsor, P. A. (1954). Solvent properties of amphiphilic compounds. London: Butterworth.
Zana, R. (2002). Dimeric and oligomeric surfactants. Behavior at interfaces and in aqueous solution: A review. Advances in Colloid and Interface Science, 97(1–3), 205–253.
Zana, R., & Lang, J. (1987). Chemical relaxation methods. In R. Zana (Ed.), Surfactant solutions (Vol. 22, pp. 405–452). New York/Basel: Dekker, M.
Zemb, T. N. (1997). The DOC model of microemulsions: Microstructure, scattering, conductivity and phase limits imposed by sterical constraints. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 129, 435–454. https://doi.org/10.1016/s0927-7757(97)00061-7.
Zemb, T. N., Hyde, S. T., Derian, P. J., Barnes, I. S., & Ninham, B. W. (1987). Microstructure from X-ray scattering – The disordered open connected model of microemulsions. Journal of Physical Chemistry, 91(14), 3814–3820.
Zemb, T., Dubois, M., Deme, B., & Gulik-Krzywicki, T. (1999). Self-assembly of flat nanodiscs in salt-free catanionic surfactant solutions. Science, 283(5403), 816–819.
Zilman, A. G., & Granek, R. (1999). Undulation instability of lamellar phases under shear: A mechanism for onion formation? European Physical Journal B, 11(4), 593–608. https://doi.org/10.1007/s100510051187.
Zohuriaan-Mehr, M. J., & Kabiri, K. (2008). Superabsorbent polymer materials: A review. Iranian Polymer Journal, 17(6), 451–477.
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Langevin, D. (2020). Self-Assembly in Bulk. In: Emulsions, Microemulsions and Foams. Soft and Biological Matter. Springer, Cham. https://doi.org/10.1007/978-3-030-55681-5_3
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